HRID 1299688촉매로High-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
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기본 정보
- CAS
13991-08-7- 표준 SMILES
c1ccc(P(c2ccccc2)c2ccccc2P(c2ccccc2)c2ccccc2)cc1- InChIKey
NFRYVRNCDXULEX-UHFFFAOYSA-N- 분자식
- C30H24P2
- 평균 분자량
- 446.5 g/mol
- 단동위원소 질량
- 446.13532403
개요
structure in first source
이름 및 식별자
- 우선 이름
- 1,2-Bis(diphenylphosphino)benzene
- IUPAC
- (2-diphenylphosphanylphenyl)-diphenylphosphane
- 영어명
- 1,2-Bis(diphenylphosphino)benzene
- 분자식
- C30H24P2
- 분자량
- 446.47
이름 및 동의어
1,2-Bis(diphenylphosphino)benzene13991-08-7DTXSID60333306RefChem:71736DTXCID30284396681-134-2dppBzMFCD00014081o-Bis(diphenylphosphino)benzeneo-Phenylenebis(diphenylphosphine)Phosphine, 1,1'-(1,2-phenylene)bis[1,1-diphenyl-(2-diphenylphosphanylphenyl)-diphenylphosphane
이름 더 보기
dppbedppbendppbenzJACS-13991-08-71,2-Diphenylphosphine-benzene
[2-(diphenylphosphanyl)phenyl]diphenylphosphaneSCHEMBL150139o-Phenylenebis[diphenylphosphine]SY038943EN300-7396611[2-(Diphenylphosphino)phenyl](diphenyl)phosphine #Phosphine, phenylenebis[diphenyl-1,2-Bis(diphenylphosphanyl)benzene
데이터베이스 식별자
- CAS
13991-08-7- PubChem CID
- 498379
- DTXSID
DTXSID60333306- EC Number
- 681-134-2
- Nikkaji
- J726.283C
물성
구조 계산 물성보충 중
- XLogP
- 7.3
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 6
- 무거운 원자 수
- 32
- 형식 전하
- 0
- 복잡도
- 439
물리화학적 성질
- 녹는점
- 183 · 183-188 °C (lit.)
- 끓는 점
- 546.9 · 546.9±33.0 °C(Predicted)
- 저장 조건
- Inert atmosphere,Room Temperature
- 물리적 상태
- 미세 결정성 분말
- 색상
- 하얀색
- 수용성
- 물에 불용성.
- InChI
- InChI=1S/C30H24P2/c1-5-15-25(16-6-1)31(26-17-7-2-8-18-26)29-23-13-14-24-30(29)32(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-24H
- InChIKey
- NFRYVRNCDXULEX-UHFFFAOYSA-N
- SMILES
- P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1
화학적 성질
white to light yellow crystal powde
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 16.7% (1 of 6) of reports.
Warning
H315 (83.3%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 6 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Hazard Classes and CategoriesSkin Irrit. 2 (83.3%)
안전 데이터
- wgk
- 3
- tsca
- No
- HS 번호
- 29319090
- risk_code
- 36/37/38
- safety_code
- 24/25
- 스토리지 클래스
- 11 - Combustible Solids
화학 및 산업
응용 분야
용도1,2-Bis(diphenylphosphino)benzene (DPPB) can be used:As a chelating ligand in the synthesis of luminescent copper(I) halide complexes.In the synthesis of copper-1,2-bis(diphenylphosphino)benzene catalyst which is used for the β-boration of α, β-unsaturated amide.As an alternative to TMEDA for the selective cleavage of sp3 C-X bond in fluoroaromatic coupling reactions catalyzed by iron.As a ligand in the synthesis of alkenylboronates from acetylenic esters.To synthesize copper-diphosphine complexes which are used as homogeneous catalysts for N-formylation of a wide range of amines.
공급사100 곳
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖南韵邦生物科技股份有限公司0731-88532326 13319508186 · [email protected]
山东春雨精细化工有限责任公司13561220159 · [email protected]
上海炎泽化工有限公司15345144255 19975051755 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]
上海遐瑞医药科技有限公司+86-021-61551413 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
韶远科技（上海）有限公司4000665055 · [email protected]
관련 반응
473건
HRID 1299689촉매로High-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
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