과요드산 칼륨

Potassiummetaperiodate,과요오드산(HIO4),칼륨염 · 과요드산칼륨 · 칼륨과요오드산 · 칼륨과요오드산(POTASSIUMPERIODATE) · 칼륨 퍼아이오데이트 · 칼륨주기율 · POTASSIUM METAPERIODATE · ACS， 99.8%-100.3%

https://huagongshe.com/ko/chemical/516896

식별자 및 물리적 특성

CAS No.	7790-21-8
분자식	I.K.O4
평균 분자량	230 g/mol
단동위원소 질량	229.84783816 g/mol
SMILES	[K+].[O-][I+3]([O-])([O-])[O-]
InChIKey	WZIUPTUZHCSBAA-UHFFFAOYSA-N
PubChem CID	516896
EC No.	232-196-0
DTXSID	DTXSID90894076
현지명	과요드산 칼륨

화학 및 물리적 성질

극성 표면적	74.3
수소 결합 공여자 수	0
수소 결합 수용자 수	4
회전 가능 결합 수	0
무거운 원자 수	6
형식 전하	0
복잡도	118
물질 분류	Other Classes -> Halogens, Inorganic Compounds
밀도	3.618 @ 15°C
Physical Description	Colorless or white solid[Hawley] Colorless odorless powder[MSDSonline]
녹는점	582 °C
끓는 점	explodes [HAW93]
증기 밀도	7.9 (vs air)
저장 조건	2-8°C
용해도	H2O: 0.01 M at 20 °C, 투명, 무색
물리적 상태	분말/고체
색상	흰색에서 황백색까지
비중	3.618
pH	pH (5g/l, 25℃) : 4.5～5.5
냄새	냄새 없는
용해도	0.42g/100mL(20℃)
Merck	14,7654
안정성	안정적인. 강산화제 - 가연성 물질과 접촉하면 화재가 발생할 수 있습니다. 유기 물질, 가연성 물질, 강력한 환원제, 금속 분말과 혼합할 수 없습니다.
InChI	1S/HIO4.K/c2-1(3,4)5/h(H,2,3,4,5)/q+1/p-1
InChIKey	FJVZDOGVDJCCCR-UHFFFAOYSA-M
SMILES	[K+].[O-]I(=O)(=O)=O
EPA	Periodic acid (HIO4), potassium salt (7790-21-8)

화학적 성질

colourless crystals or white crystalline powder

안전 및 규제

GHS 분류	DangerH272 (96.4%): May intensify fireoxidizer [Danger Oxidizing liquidsOxidizing solids]P210, P220, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 56 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H302: Harmful if swallowed [Warning Acute toxicity, oral]
규제 정보	Chemical: Periodic acid (HIO4), potassium saltPeriodic acid, potassium salt: HSNO Approval: HSR001341 Approved with controls
기타 안전 정보	IMAP assessments - Periodic acid and its salts: Human health tier II assessment
유해성 요약	A strong skin, eye, and mucous membrane irritant[Merck Index] May cause fire on contact with organic substancesA strong oxidizing agent and irritant[Hawley] A skin and eye irritant[eChemPortal: ERMA] An oxidizing agentMay cause fire on contact with combustible materialAn irritant[MSDSonline] See Metaperiodic acid.
Hazard Classes and Categories	Ox. Sol. 2 (96.4%)Acute toxicity (ingestion) - category 4
Protective Action Criteria (PAC)	1.2 [mg/m3]13 [mg/m3]79 [mg/m3]
수질 위해 등급(WGK)	3
TSCA 등재 상태	TSCA listed
운송 번호(UN)	UN 1479 5.1/PG 2
관세 코드	28299000
위험 문구(R)	8-36/37/38
위험 표시	O,Xi
안전 문구(S)	17-26-36-37/39

용도

For the colorimetric determination of Mn (oxidizes manganese compounds to permanganates), as oxidizing agentPotassium periodate is used as an oxidizing agent in organic synthesis and an analytical reagent for the determination of potassium and cerium. It is also used in colorimetric estimation of manganese. It reacts with ammonium cerium(IV) nitrate to prepare tris[trinitratocerium(IV)] paraperiodate which finds application as an oxidant.

일반 설명

Potassium (meta)periodate exhibits strong oxidizing properties in acidic medium.

제조 및 합성 방법

제조 방법

Potassium periodate can be prepared by oxidation of potassium iodate with a powerful oxidizing agent such as potassium permanganate, chlorine or bromine in basic solution:IO3ˉ+ Cl2+ 2OHˉ→IO4ˉ+ 2Clˉ+ H2OAlso, the salt may be prepared by electrolysis.

생산 방법

Potassium periodate, KlO4, white solid, formed by electrolysis of potassium iodate under proper conditions.