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황산 칼륨

Potassium bisulfate

HCID 516920
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기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
7646-93-7
표준 SMILES
O=S(=O)([O-])O.[K+]
InChIKey
CHKVPAROMQMJNQ-UHFFFAOYSA-M
분자식
HKO4S
평균 분자량
136.17 g/mol
단동위원소 질량
135.92326117

이름 및 식별자

우선 이름
Potassium bisulfate
IUPAC
potassium hydrogen sulfate
현지명
황산 칼륨
영어명
Potassium bisulfate
분자식
HKO4S
분자량
136.16884

이름 및 동의어

Potassium bisulfatePotassium hydrogen sulfate7646-93-7Sal enixumSulfuric acid, monopotassium saltCaswell No. 682CMonopotassium hydrogen sulfatePotassium hydrosulfate (KHSO4)Potassium hydrogen sulfate, solidEINECS 231-594-1UN2509EPA Pesticide Chemical Code 005605
이름 더 보기
황산칼륨황산칼륨(POTASSIUMHYDROGENSULFATE)황산수소칼륨(VI)KHSO4POTASSIUM BISULPHATEPOTASSIUM HYDROGEN SULPHATEKaliumhydrogensulfatPOTASSIUM HYDROGEN SULPHATE puresalenixumPotassium bisuLmonopotassiumsulfate
NSC 409996UNII-1J1K03241FAI3-044591J1K03241FINS NO.515(II)DTXSID8047715POTASSIUM BISULFATE [MI]INS-515(II)

데이터베이스 식별자

CAS
7646-93-7
PubChem CID
516920
DTXSID
DTXSID8047715
UNII
1J1K03241F
EC Number
231-594-1
Nikkaji
J43.947I

물성

구조 계산 물성보충 중

극성 표면적
85.8 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
4
회전 가능 결합 수
0
무거운 원자 수
6
형식 전하
0
복잡도
93

실험 및 물리화학적 성질

Density · 2건

2.2 g/cm³

2.24 @25 °C

Solubility · 2건

Freely soluble in water, insoluble in ethanol

Solubility in water, g/100ml: 49 (very good)

Decomposition195-214 °C
Physical Description · 5건

Potassium hydrogen sulfate is a colorless crystalline solid with a sulfur odor. It may cause illness from ingestion. If heated to high temperatures it may emit toxic fumes. It is used to make fertilizers and wine.

Large Crystals; Other Solid; Dry Powder; Large Crystals

White deliquescent crystals, pieces or granules

White deliquescent solid; [Merck Index] Colorless to white hygroscopic solid; [ICSC]

COLOURLESS-TO-WHITE HYGROSCOPIC CRYSTALS OR CRYSTALLINE POWDER.

물리화학적 성질

녹는점
214 °C · 214 °C(lit.)
끓는 점
93 · decomposes [STR93]
밀도
2.32 g/mL · 2.32 g/mL at 25 °C(lit.)
저장 조건
5 °C · Store at +5°C to +30°C.
용해도
2 O: · H2O: 1 M at 20 °C, 투명, 무색
물리적 상태
고체
색상

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H314: Causes severe skin burns and eye damage [Danger Skin corrosion/irritation];H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P319, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Danger

유해성 정보

Regulatory Information · 6건

Chemical: Sulfuric acid, monopotassium salt

Regulation (EC) No 1333/2008 (amended)

Sulfuric acid, potassium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, potassium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 12-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/23635;Status: Active Update: 07-12-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/22889

Potassium hydrogen sulphate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelCorrosive
Fire Hazards · 3건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:;Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Corrosives in contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. For electric vehicles or equipment, ERG Guide 147 (lithium ion or sodium ion batteries) or ERG Guide 138 (sodium batteries) should also be consulted. (ERG, 2024)

화학 및 산업

용도 및 제조

UsesUsed as a flux (ores and siliceous compounds) and cathartic; [Merck Index] Used to make fertilizers and wine; [CAMEO]
U.S. Production2023: 250,000 - <400,000 lb;2022: 550,000 - <700,000 lb;2021: 1,000,000 - <2,500,000 lb;2020: 4,000,000 - <5,500,000 lb
Consumer UsesSoil amendments (fertilizers)
Industry UsesSoil amendments (fertilizers)
Household ProductsInformation on 3 consumer products that contain Potassium hydrogensulphate in the following categories is provided:;• Commercial / Institutional;• Landscaping/Yard
Use ClassificationFood additives
General Manufacturing Information · 2건

Agriculture, Forestry, Fishing and Hunting

Sulfuric acid, potassium salt (1:1): ACTIVE

응용 분야

일반 설명Potassium hydrogen sulfate is a colorless crystalline solid with a sulfur odor. It may cause illness from ingestion. If heated to high temperatures it may emit toxic fumes. It is used as flux in analysis of ores and siliceous Compounds.

제조 방법

Potassium bisulfate is typically made by heating potassium sulfate (K2SO4) with sulfuric acid. The acid provides the hydrogen needed to convert the salt (K2SO4) to the corresponding acid salt (KHSO4).

상·하류 제품 정보

상류 원료

피루브 산, 나트륨 염

관련 반응

1,094건
반응 기록 만들기
HRID 869 반응식
HRID 869반응물로uspto-grants-1998_03
HRID 3788 반응식
HRID 3788반응물로uspto-grants-1988_02
HRID 6869 반응식
HRID 6869반응물로uspto-grants-2006_08
HRID 6871 반응식
HRID 6871반응물로uspto-grants-2006_08
HRID 8528 반응식
HRID 8528반응물로uspto-grants-2006_08
HRID 8837 반응식
HRID 8837반응물로uspto-grants-2006_08
HRID 13183 반응식
HRID 13183반응물로uspto-grants-2010_06
HRID 19582 반응식
HRID 19582용매로uspto-grants-2010_06
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화합물 노트

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이 페이지에서기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
더보기
새 노트새 반응견적 요청하기
하얀색
Specific Gravity
2.322 · 2.322
수소이온지수(pH)
1 · 1 (50g/l, H2O, 20℃)
수용성
녹는
Merck
14 · 14,7613
안정성
안정적인. 수분에 민감합니다.
InChI
1S/K.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+1;/p-1
InChIKey
CHKVPAROMQMJNQ-UHFFFAOYSA-M
SMILES
[K+].OS([O-])(=O)=O
EPA
Potassium bisulfate (7646-93-7)
화학적 성질 · 1건

Potassium bisulfate, also known as potassium hydrogen sulfate and potassium acid sulfate, KHS04 is water soluble, white deliquescent crystals,which melt at 214°C. Potassium bisulfate dissolved in water undergoes ionization to form K+, H+, SO42-. It is used in wine making, fertilizer manufacture, and as a flux and food preservative.

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.;· Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.).;· Corrosives in contact with metals may evolve flammable hydrogen gas.;· Containers may explode when heated.;· For electric vehicles or equipment, GUIDE 147 (lithium ion or sodium ion batteries) or GUIDE 138 (sodium batteries) should also be consulted.

Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

Health Hazards · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:;TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental contamination. (ERG, 2024)

· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.;· Contact with molten substance may cause severe burns to skin and eyes.;· Avoid any skin contact.;· Fire may produce irritating, corrosive and/or toxic gases.;· Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental contamination.

Hazards SummaryReacts with water; A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; [ICSC] Causes burns; May cause respiratory irritation; [Aldrich MSDS]
DOT ID and Guide2509 154
Reactive GroupSalts, Acidic
EC ClassificationSymbol: C; R: 34-37; S: (1/2)-26-36/37/39-45
UN ClassificationUN Hazard Class: 8; UN Pack Group: II
Reactivity Profile · 1건

Acidic salts, such as POTASSIUM HYDROGEN SULFATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Chemical DangersDecomposes on heating. This produces toxic fumes. Reacts with alcohols and water. The solution in water is a medium strong acid. Attacks many metals. This produces flammable/explosive gas (hydrogen - see ICSC 0001).
Packaging and LabellingUnbreakable packaging. Put breakable packaging into closed unbreakable container.

안전 및 보호

Fire Fighting · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:;SMALL FIRE: Dry chemical, CO2 or water spray.;LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal.;FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. (ERG, 2024)

In case of fire in the surroundings, use appropriate extinguishing media.

First Aid Measures · 4건

Fresh air, rest. Seek medical attention if you feel unwell.

First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer for medical attention if skin irritation occurs.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Do NOT induce vomiting. Refer immediately for medical attention.

Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.;· Keep unauthorized personnel away.;· Stay upwind, uphill and/or upstream.;· Ventilate closed spaces before entering, but only if properly trained and equipped.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.;· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.;· Stop leak if you can do it without risk.;· Prevent entry into waterways, sewers, basements or confined areas.;· Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.;· DO NOT GET WATER INSIDE CONTAINERS.

First Aid · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:;Refer to the "General First Aid" section. Specific First Aid: For corrosives, in case of contact, immediately flush skin or eyes with running water for at least 30 minutes. Additional flushing may be required. (ERG, 2024)

General First Aid:;· Call 911 or emergency medical service.;· Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.;· Move victim to fresh air if it can be done safely.;· Administer oxygen if breathing is difficult.;· If victim is not breathing:;-- DO NOT perform mouth-to-mouth resuscitation; the victim may have ingested or inhaled the substance.;-- If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).;-- If no pulse detected or no respiratory medical device available, provide continuous compressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.;· Remove and isolate contaminated clothing and shoes.;· For minor skin contact, avoid spreading material on unaffected skin.;· In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.;· For severe burns, immediate medical attention is required.;· Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.;· Keep victim calm and warm.;· Keep victim under observation.;· For further assistance, contact your local Poison Control Center.;· Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.;Specific First Aid:;· For corrosives, in case of contact, immediately flush skin or eyes with running water for at least 30 minutes. Additional flushing may be required.

Safe StorageDry. Separated from strong bases, alcohols, metals and food and feedstuffs.
Exposure Control and Personal Protection · 1건

· Wear positive pressure self-contained breathing apparatus (SCBA).;· Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.;· Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

Nonfire Spill Response · 1건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:;ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2024)

Spillage DisposalPersonal protection: chemical protection suit and particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting.
Isolation and Evacuation · 2건

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:;IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.;SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.;FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)

Immediate precautionary measure;· Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.;Spill;· For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.;· For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind direction, as necessary.;Fire;· If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

Eye PreventionWear face shield or eye protection in combination with breathing protection.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.
Skin PreventionProtective gloves. Protective clothing.

독성 정보

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesThe substance can be absorbed into the body by inhalation of dust and by ingestion.
Signs and Symptoms · 4건

Cough. Sore throat.

Redness. Pain. Skin burns.

Redness. Pain. Severe deep burns.

Sore throat. Abdominal pain. Burning sensation. Shock or collapse.

규제 정보

Regulatory Information · 6건

Chemical: Sulfuric acid, monopotassium salt

Regulation (EC) No 1333/2008 (amended)

Sulfuric acid, potassium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, potassium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 12-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/23635;Status: Active Update: 07-12-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/22889

Potassium hydrogen sulphate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

안전 데이터

wgk
1
tsca
TSCA listed
rtecs
TS7200000
ridadr
UN 2509
독성
LD50 orally in Rabbit: 2340 mg/kg
HS 번호
2833 29 80
risk_code
34-37
hazard_code
C
safety_code
26-36/37/39-45
포장분류
II
위험 등급
8
기존화학 물질
KE-32642
F 고인화성물질
3
Hazard Classifications
Eye Dam. 1Skin Corr. 1BSTOT SE 3
스토리지 클래스
8B - Non-combustible corrosive hazardous materials
황산칼륨
황산

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