Dimethylphosphinic chloride

HCID 517954

노트 반응

부분 구조 검색 유사 구조 찾기

기본 정보

CAS: 1111-92-8
표준 SMILES: CP(C)(=O)Cl
InChIKey: CVNMBKFJYRAHPO-UHFFFAOYSA-N
분자식: C2H6ClOP
평균 분자량: 112.49 g/mol
단동위원소 질량: 111.98447912

이름 및 식별자

우선 이름: Dimethylphosphinic chloride
IUPAC: [chloro(methyl)phosphoryl]methane
영어명: DIMETHYLPHOSPHINIC CHLORIDE
분자식: C2H6ClOP
분자량: 112.5

이름 및 동의어

Dimethylphosphinic chloride1111-92-8Phosphinic chloride, dimethyl-EINECS 214-187-3DTXSID40149503RefChem:588592DTXCID2071994214-187-3[chloro(methyl)phosphoryl]methaneMFCD00002078dimethylphosphinoyl chlorideC2H6ClOP

이름 더 보기

Chlorodimethylphosphine oxideDiMethylphosphinic chloride 97%Dimethylphosphinic acidchlorideDimethylphosphinic chloride, 97+%3-Pyridinecarboxylicacid,6-(1H-imidazol-2-yl)-Phosphinic chloride, dimethyl- (6CI,7CI,8CI,9CI)

Me2P(O)Cldimethylphosphinoylchloridedimethylphosphinyl chlorideDimethylphosphin1c chloridedimethyl phosphinyl chlorideSCHEMBL213567Dimethylphosphinic chloride, 97%AKOS015916086

데이터베이스 식별자

CAS: 1111-92-8
PubChem CID: 517954
DTXSID: DTXSID40149503
EC Number: 214-187-3
Nikkaji: J217.229A

물성

구조 계산 물성

XLogP: 0.2
극성 표면적: 17.1 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 0
무거운 원자 수: 5
형식 전하: 0
복잡도: 64

실험 및 물리화학적 성질

SpringerMaterials Properties31P nuclear magnetic resonance spectrum

물리화학적 성질

녹는점: 65 · 65-71 °C(lit.)
끓는 점: 204 °C · 204 °C(lit.)
밀도: 1.158 · 1.158±0.06 g/cm3(Predicted)
인화점: 204 °C · 204°C
저장 조건: Refrigerator, under inert atmosphere
용해도: 클로로포름(소량으로 용해), 메탄올(약간 용해됨)
물리적 상태: 수정 같은
색상: 흰색에서 황백색까지
안정성: 수분에 민감한
InChI: 1S/C2H6ClOP/c1-5(2,3)4/h1-2H3
InChIKey: CVNMBKFJYRAHPO-UHFFFAOYSA-N
SMILES: CP(C)(Cl)=O

화학적 성질

yellow to pink to tan crystals or crystalline

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesSkin Corr. 1 (100%)

안전 데이터

wgk: 3
ridadr: UN 3261 8/PG 2
risk_code: 34
hazard_code: C
safety_code: 26-27-28-36/37/39-45
포장분류: II
위험 등급: 8
Hazard Classifications: Skin Corr. 1B
스토리지 클래스: 8A - Combustible corrosive hazardous materials

화학 및 산업

응용 분야

용도Dimethylphosphinic chloride is used in the protection of amino acids in peptide synthesis. It initiates the luminescence of ABI-NH2. It is utilized in the reactivity of organophosphate-based nerve gases such as sarin gas.

일반 설명Kinetics of pyridinolyses of dimethylphosphinic chloride in acetonitrile was studied. Kinetics and mechanism of the reaction of dimethyl phosphinic chloride with anilines in acetonitrile was studied.