기본 정보
- CAS
7783-53-1- 표준 SMILES
[F][Mn]([F])[F]- InChIKey
SRVINXWCFNHIQZ-UHFFFAOYSA-K- 분자식
- F3Mn
- 평균 분자량
- 111.9333 g/mol
- 단동위원소 질량
- 111.933253
개요
Manganese trifluoride is a fluoride of manganese. Manganese is a naturally occurring metal with the symbol Mn and the atomic number 25. It does not occur naturally in its pure form, but is found in many types of rocks in combination with other substances such as oxygen, sulfur, or chlorine. Manganese occurs naturally in most foods and small amounts are needed to stay healthy, as manganese ions act as cofactors for a number of enzymes. (L228, L229)
이름 및 식별자
- 우선 이름
- Manganese trifluoride
- IUPAC
- trifluoromanganese
- 영어명
- Manganese(III) fluoride
- 분자식
- F3Mn
- 분자량
- 111.93
이름 및 동의어
Manganese trifluorideManganese(III) fluoridetrifluoromanganeseManganese fluoride (MnF3)manganic fluorideUNII-VHG84D268XVHG84D268XDTXSID50893904EINECS 232-006-6RefChem:155599DTXCID801323942232-006-6
이름 더 보기
Manganese(Ⅲ) Fluoridemanganesefluoride(mnf3)Manganese fluoride (III)Manganese(III)fluoride99%Manganese(III)fluoride,98%
MANGANESE TRIFLUORIDE [MI]MANGANESE(3+) FLUORIDEMnF3manganese(3+) trifluoridemanganese(3+) ion trifluorideSCHEMBL1773075AKOS025310462CS-0111493
데이터베이스 식별자
- CAS
7783-53-1- PubChem CID
- 522682
- DTXSID
DTXSID50893904- EC Number
- 232-006-6
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 3
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 4
- 형식 전하
- 0
- 복잡도
- 8
실험 및 물리화학적 성질
Chemical ClassesMetals -> Manganese Compounds, Inorganic
Physical DescriptionRed solid; [Merck Index]
물리화학적 성질
- 녹는점
- 600 ℃ · decomposes at >600℃ [KIR81]
- 밀도
- 3.54 g/mL · 3.54 g/mL at 25 °C(lit.)
- 용해도
- 2 O · reacts with H2O
- 물리적 상태
- 가루
- 색상
- 빨간색
- Specific Gravity
- 3.54 · 3.54
- 수용성
- 유기 용매에 불용성. 물에 의해 가수분해됨.
- Merck
- 14 · 14,5741
- 안정성
- 안정적인. 강한 산화제와 호환되지 않습니다. 습기로부터 보호하십시오. 가연성 물질과 접촉하면 화재가 발생할 수 있습니다.
- 주요 응용
- 배터리 전구체촉매재료 합성 전구체
- InChI
- 1S/3FH.Mn/h3*1H;/q;;;+3/p-3
- InChIKey
- SRVINXWCFNHIQZ-UHFFFAOYSA-K
- SMILES
- F[Mn](F)F
- EPA
- Manganese fluoride (MnF3) (7783-53-1)
화학적 성질
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Danger
H272 (88.6%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]
P210, P220, P261, P264, P264+P265, P270, P271, P280, P301+P316, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 44 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Hazards SummaryToxic material; [Hawley] See Manganese and linked occupational diseases.
Hazard Classes and CategoriesOx. Sol. 2 (88.6%)
안전 및 보호
Exposure Control and Personal Protection
Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)
0.2 [mg/m3], as Mn (inhalable fraction), 0.02 mg/m3, as Mn (respirable fraction) [1 mg/m3, as F, inhalable fraction][German Research Foundation (DFG)]
Minimum Risk LevelChronic Inhalation: 0.0003 mg/m3 (L134)
Threshold Limit Values (TLV)0.02 [mg/m3], as Mn (respirable fraction), 0.1 mg/m3, as Mn (inhalable fraction) (2.5 mg/m3, as F)
Permissible Exposure Limit (PEL)2.5 [mg/m3]Ceiling(OSHA)=5 mg/m3, as Mn
독성 정보
화학 및 산업
약리 정보
Metabolism/Metabolites
Manganese is absorbed mainly via ingestion, but can also be inhaled. It binds to alpha-2-macroglobulin, albumin, or transferrin in the plasma and is distributed to the brain and all other mammalian tissues, though it tends to accumulate more in the liver, pancreas, and kidney. Manganese is capable of existing in a number of oxidation states and is believed to undergo changes in oxidation state within the body. Manganese oxidation state can influence tissue toxicokinetic behavior, and possibly toxicity. Manganese is excreted primarily in the faeces. (L228)
용도 및 제조
UsesUsed as a fluorinating agent of organic compounds; [Merck Index]
General Manufacturing InformationManganese fluoride (MnF3): ACTIVE
응용 분야
용도Fluorinating agent in organic chemistry.
일반 설명Manganese(III) fluoride (also known as manganese trifluoride), MnF3, is a red/purplish solid useful for converting hydrocarbons into fluorocarbons, that is, it is a fluorination agent. It forms a hydrate and numerous derivatives. MnF3 can be produced by reacting a solution of MnF2 in hydrogen fluoride with fluorine.
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