홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /화합물

Sodium Picramate

HCID 5362461
새 노트새 반응견적 요청하기
인쇄 미리보기
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
831-52-7
표준 SMILES
Nc1cc([N+](=O)[O-])cc([N+](=O)[O-])c1[O-].[Na+]
InChIKey
UENNEPPWFZYINW-UHFFFAOYSA-M
분자식
C6H4N3O5.Na
평균 분자량
221.1 g/mol
단동위원소 질량
221.00486452

개요

Sodium picramate appears as a yellow solid. Toxic by inhalation and skin absorption. Primary hazard is fire with either a minor blast or projection hazard or both, but no mass explosion hazard. May explode under prolonged exposure to heat.

이름 및 식별자

우선 이름
Sodium Picramate
IUPAC
sodium 2-amino-4,6-dinitrophenolate

이름 및 동의어

Sodium picramate831-52-7Phenol, 2-amino-4,6-dinitro-, monosodium salt2-Amino-4,6-dinitrophenol monosodium saltEINECS 212-603-8UNII-4988SZV57R2-Amino-4,6-dinitrophenol, sodium salt4988SZV57RDTXSID2061193Phenol, 2-amino-4,6-dinitro-, sodium saltEC 212-603-8Phenol, 2-amino-4,6-dinitro-, sodium salt (1:1)
이름 더 보기
SODIUM PICRAMATE, (WET, WITH >= 20% WATER)SODIUM PICRAMATE, [WET, WITH >= 20% WATER]SODIUM PICRAMINATERefChem:184081SODIUM PICRAMATE [INCI]DTXCID5048346PICRAMIC ACID, SODIUM DERIV.SODIUM PICRAMATE, WETTED WITH NOT LESS THAN 20% WATER

데이터베이스 식별자

CAS
831-52-7
PubChem CID
5362461
DTXSID
DTXSID2061193
UNII
4988SZV57R
EC Number
212-603-8、688-508-4

물성

구조 계산 물성

극성 표면적
141 Ų
수소 결합 공여자 수
1
수소 결합 수용자 수
6
회전 가능 결합 수
0
무거운 원자 수
15
형식 전하
0
복잡도
247

실험 및 물리화학적 성질

Chemical ClassesFlammable agents - 3rd degree
Cosmetics · 2건

Cosmetic ingredients (Sodium Picramate) -> CIR (Cosmetic Ingredient Review)

Hair dyeing

Physical Description · 3건

Sodium picramate appears as a yellow solid. Toxic by inhalation and skin absorption. Primary hazard is fire with either a minor blast or projection hazard or both, but no mass explosion hazard. May explode under prolonged exposure to heat.

Sodium picramate, wetted with not less than 20% water appears as a slurry of dark red crystals. Highly explosive. Burns vigorously when dry. May explode if in large quantities. Burns when wet, but difficult to ignite. Produces toxic oxides of nitrogen during combustion.

CBI

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 15.8% (12 of 76) of reports.

Danger

H301 (26.3%): Toxic if swallowed [Danger Acute toxicity, oral]

P261, P264, P270, P271, P272, P273, P280, P301+P316, P301+P317, P302+P352, P304+P340, P317, P321, P330, P333+P317, P362+P364, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 76 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

유해성 정보

Regulatory Information · 5건

Chemical: Phenol, 2-amino-4,6-dinitro-, monosodium salt

Phenol, 2-amino-4,6-dinitro-, sodium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phenol, 2-amino-4,6-dinitro-, sodium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Sodium 2-amino-4,6-dinitrophenoxide (EC: 212-603-8)

Phenol, 2-amino-4,6-dinitro-, monosodium salt, (wetted): HSNO Approval: HSR001299 Approved with controls

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Picramic acid and sodium picramate: Human health tier II assessment
DOT Label · 2건

Explosive 1.3C Flammable Solid

Flammable Solid

Fire Hazards · 3건

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:

· Flammable/combustible material.

화학 및 산업

용도 및 제조

UsesCIR ingredient: Sodium Picramate
U.S. Production2023: <50,000 lb
Industry UsesEnergy Releasers (explosives, motive propellant)
Use ClassificationCosmetics -> Hair dyeing
General Manufacturing Information · 2건

Explosives Manufacturing

Phenol, 2-amino-4,6-dinitro-, sodium salt (1:1): ACTIVE

관련 반응

0건
반응 기록 만들기

현재 필터 조건에 해당하는 반응 기록이 없습니다.

화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
더보기
새 노트새 반응견적 요청하기
Health Hazards · 3건

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:

· Some are toxic and may be fatal if inhaled, ingested or absorbed through skin. Specifically, Dinitrophenol, wetted (UN1320); Dinitrophenolates, wetted (UN1321), Sodium dinitro-o-cresolate, wetted (UN1348); and Barium azide, wetted (UN1571) are known to be toxic.

DOT ID and Guide1349 113
Reactive Group · 2건

Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic

Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic

Reactivity Alerts · 2건

Highly Flammable

Highly Flammable

Reactivity Profile · 2건

SODIUM PICRAMATE can react vigorously with reducing agents, including hydrides, sulfides and nitrides, leading to a detonation. Emits toxic fumes when heated to decomposition.

Aromatic nitro compounds, such as SODIUM PICRAMATE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups. Flammable/combustible material. May be ignited by heat, sparks or flames. DRIED OUT material may explode if exposed to heat, flame, friction or shock; Treat as an explosive.

DOT Hazard Classification · 6건

Sodium picramate, dry or wetted with less than 20 percent water, by mass

UN0235

Div 1.3 Explosives (with predominately a fire hazard) (49 eCFR § 173.50)

Sodium picramate, wetted with not less than 20 percent water, by mass

UN1349

Div 4.1 Flammable solid (49 eCFR § 173.124)

Air and Water Reactions · 2건

Flammable. Water soluble

Highly flammable. Soluble in water.

Hazard Classes and Categories · 5건

Acute Tox. 3 (26.3%)

Flam. Sol. 2 (100%)

Acute toxicity (ingestion) - category 3

Explosives - Division 1.3

Flammable agents - 3rd degree, Reactive agents - 3rd degree

안전 및 보호

Fire Fighting · 2건

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:

Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 3건

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill Response · 2건

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:

Isolation and Evacuation · 3건

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:

Immediate precautionary measure

Personal Protective Equipment (PPE) · 2건

Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]:

Excerpt from ERG Guide 113 [Flammable Materials (Wet / Desensitized Explosive)]:

Emergency Response Planning GuidelinesCARGO Fire

독성 정보

Toxicity SummarySafe in the present practices of use and concentration. Ingredient, concentration, and use information are available in documents discoverable at https://cir-reports.cir-safety.org