2-(트리메틸실릴)티아졸

2-Trimethylsilylthiazole

HCID 588453CAS 79265-30-8
부분 구조 검색유사 구조 찾기

기본 정보

표준 SMILES
C[Si](C)(C)c1nccs1
InChIKey
VJCHUDDPWPQOLH-UHFFFAOYSA-N
분자식
C6H11NSSi
평균 분자량
157.31 g/mol
단동위원소 질량
157.03814688

이름 및 식별자

우선 이름
2-Trimethylsilylthiazole
IUPAC
trimethyl(1,3-thiazol-2-yl)silane
현지명
2-(트리메틸실릴)티아졸
영어명
2-(Trimethylsilyl)thiazole
분자식
C6H11NSSi
분자량
157.31

이름 및 동의어

2-TrimethylsilylthiazoleThiazole, 2-(trimethylsilyl)-RefChem:4838412-(Trimethylsilyl)thiazole79265-30-82-(Trimethylsilyl)-1,3-thiazoletrimethyl(1,3-thiazol-2-yl)silaneMFCD000662742-TRIMETHYLSILANYLTHIAZOLE2-trimethylsilyl thiazole2-trimethylsilyl-thiazole2-trimethylsilanyl-thiazole
이름 더 보기
2-(트리메틸실릴)티아졸2-(트라이메틸실릴)싸이아졸2-TSTDondoniDondoni reagent2-（trimethyl)thiazole2-TRIMETHYLSILYTHIAZOLE2-THIAZOLYTRIMETHYLSILANE2-Thiazolyltrimethylsilanetrimethyl(2-thiazolyl)silane
s20279AKOS015840024AC-5111AS-2184IOXILAN(400MG)trimethyl(thiazol-2-yl)silane2-TrimethylsilAMY5357

데이터베이스 식별자

CAS
79265-30-8
PubChem CID
588453
DTXSID
DTXSID00343242
EC Number
627-932-6
Nikkaji
J261.103A

물성

구조 계산 물성

극성 표면적
41.1 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
1
무거운 원자 수
9

실험 및 물리화학적 성질

SpringerMaterials PropertiesChemical shift

물리화학적 성질

끓는 점
56 · 56-57 °C10 mm Hg(lit.)
밀도
0.985 g/mL · 0.985 g/mL at 25 °C(lit.)
굴절률
20 · n20/D 1.497(lit.)
인화점
135 °F · 135 °F
저장 조건
2 · Inert atmosphere,2-8°C
용해도
THF: 매우 용해성(lit.)

화학적 성질

Colorless to light yellow liqui

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 2.2% (1 of 46) of reports.

Warning

H226 (10.9%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information2-TRIMETHYLSILYLTHIAZOLE: Does not have an individual approval but may be used under an appropriate group standard
Hazard Classes and CategoriesFlam. Liq. 3 (10.9%)

안전 데이터

wgk
3
ridadr
1993
HS 번호
29341000
risk_code
36/37/38
hazard_code
Xi
safety_code
23-24/25-26

화학 및 산업

응용 분야 · 1건

용도2-(Trimethylsilyl)thiazole is used as formyl anion equivalent; effective one-carbon homologating reagent of alkoxy aldehydes, amino aldehydes, and dialdoses.It takes part in the reactions of Homologation of Aldehydes, Metalation and Reactivity with Electrophiles, Cross-coupling Reactions, etc.

제조 방법

Although 2-(trimethylsilyl)thiazole (1) is commercially available, it can be easily prepared on a multigram scale from 2-bromothiazole, n-butyllithium, and chlorotrimethylsilane as shown in eq 1.

상·하류 제품 정보

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]

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