Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dichloro(1,3-dimesityl-2-imidazolidinylidene)(5-(dimethylsulfamoyl)-2-isopropoxybenzylidene)ruthenium
ZHAN CATALYST-1B · Zhan catalyst · 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(iso-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methylene ruthenium(II) dichloride · Dichloride Zhan catalyst 1B · TB-1840 · CATALYST -1B · Dichloro(1,3-dimesityl-2-imidazolidinylidene)[5-(dimethylsulfamoyl)-2-isopropoxybenzylidene]ruthenium · (1,3-Dimesitylimidazolidin-2-ylidene)[5-(N,N-dimethylsulfamoyl)-2-isopropoxybenzylidene]ruthenium(VI) Chloride
식별자 및 물리적 특성
| CAS No. | 918870-76-5 |
|---|---|
| 분자식 | C33H43Cl2N3O3RuS |
| 평균 분자량 | 733.8 g/mol |
| 단동위원소 질량 | 733.144559 g/mol |
| SMILES | Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)[C]2=[Ru]([Cl])([Cl])=[CH]c2cc(S(=O)(=O)N(C)C)ccc2OC(C)C)c(C)c1 |
| InChIKey | OXLURKCRXVAJQS-UHFFFAOYSA-L |
| PubChem CID | 59856477 |
| EC No. | 813-485-6 |
화학 및 물리적 성질
| 극성 표면적 | 61.5 |
|---|---|
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 6 |
| 회전 가능 결합 수 | 7 |
| 무거운 원자 수 | 43 |
| 형식 전하 | 0 |
| 복잡도 | 1,130 |
| 저장 조건 | 2-8°C, stored under nitrogen |
| 물리적 상태 | 고체 |
| 색상 | 녹색 |
| InChIKey | JIZPWEVWTYCVNK-UHFFFAOYSA-L |
| SMILES | [Cl-][Ru+6]1(=[C-2]C2=CC(S(=O)(=O)N(C)C)=CC=C2O1C(C)C)(=[C-2]1N(C2C(=CC(C)=CC=2C)C)CCN1C1C(=CC(C)=CC=1C)C)[Cl-] |
안전 및 규제
| GHS 분류 | WarningH302 (50%): Harmful if swallowed [Warning Acute toxicity, oral]P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 2 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Hazard Classes and Categories | Acute Tox. 4 (50%) |
| 수질 위해 등급(WGK) | 3 |
| 위험 문구(R) | 36/37/38 |
| 위험 표시 | Xi |
| 안전 문구(S) | 26 |
| 저장 분류 | 13 - Non Combustible Solids |
용도
용도
Zhan Catalyst-1B (Hoveyda-Grubbs type catalyst) can be used:In the preparation of hybrid olefin metathesis catalysts, with increased catalytic activity via immobilization on molecular seives. supportsAs a catalyst in the synthesis of divergent dendrimerIn ring-closure metathesis (RCM) reaction.