부틸리튬
n-Butyl lithium
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기본 정보
- CAS
109-72-8- 표준 SMILES
[CH2-]CCC.[Li+]- InChIKey
DLEDOFVPSDKWEF-UHFFFAOYSA-N- 분자식
- C4H9Li
- 평균 분자량
- 64.1 g/mol
개요
Butyllithium is an alkyllithium compound.
이름 및 식별자
- 우선 이름
- n-Butyl lithium
- IUPAC
- lithium butane
- 현지명
- 부틸리튬
- 영어명
- n-Butyllithium
- 분자식
- C4H9Li
- 분자량
- 64.06
이름 및 동의어
lithium;butanen-Butyl lithiumC4H9LiLiBun-butyllitiumMFCD00009414BuLibutyilithiumbutyllitiumUNII-09W9A6B8ZCbutyl-lithiumn-butyllithiurn
이름 더 보기
부틸리튬뷰틸리튬n-부틸 리튬N-BULIBUTYLLITHIUMLithiumn-butylButyllithium solutionn-ButyllithiuM(BULI)ButyllithiuminhexaneMn-BuLi, Lithium-1-butaniden-Butyllithium, 1.6M solution in hexanesbutyl-lithiu
n-butyllithumn-Buyllithiumn- butyllithiumn-butyl-lithiumnButLi1-butyllithiumn-buty lithiumn-butyl lithum
데이터베이스 식별자
- CAS
109-72-8- PubChem CID
- 61028
- ChEBI
CHEBI:51469- UNII
- 09W9A6B8ZC
- Nikkaji
- J370K
물성
구조 계산 물성보충 중
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 1
- 회전 가능 결합 수
- 1
- 무거운 원자 수
- 5
- 형식 전하
- 0
- 복잡도
- 7.6
물리화학적 성질
- 녹는점
- -95 °C · -95 °C
- 끓는 점
- 80 °C · 80 °C
- 밀도
- 0.68 g/mL · 0.68 g/mL at 20 °C
- 증기압
- 163 hPa · 163 hPa ( 20 °C)
- 인화점
- 10 °F · 10 °F
- 저장 조건
- 2 · 2-8°C
- 용해도
- 디에틸 에테르 및 시클로헥산과 혼합 가능.
- 물리적 상태
- 액체
- 색상
- 노란색
- Specific Gravity
- 0.695 · 0.695
- 냄새
- 용매의 냄새
- 폭발한계
- 1.2 · 1.2-7.8% (v/v)
- 수용성
- 격렬한 반응
- BRN
- 1209227 · 1209227
- InChI
- 1S/C4H9.Li/c1-3-4-2;/h1,3-4H2,2H3;
- InChIKey
- MZRVEZGGRBJDDB-UHFFFAOYSA-N
- SMILES
- [Li]CCCC
- LogP
- 1.25 · 1.25-2.31
- NIST
- Butyl lithium(109-72-8)
- EPA
- Lithium, butyl- (109-72-8)
화학적 성질
n-Butyllithium is a colorless crystalline solid or clear yellow solution. Due to its high reactivity and extreme solubility, even in its impurities, it is commonly thought to be a viscous liquid.
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
유해성 정보
CSL Reaction Information
CSL00127
Perfluorethyllithium + Phosphorus Trichloride,Phosphorus + N-BUTYLLITHIUM + CHLOROPENTAFLUOROETHANE
Avoid temperatures below -90 C
Substitution
Several times in our laboratory, we have experienced a violent decomposition of the ethereal C2F5Cl/n-BuLi solution after the addition of just a few drops of (R)nPCl3=n. In each of these cases, the metal-halogen exchange temperature was maintained below -90 C. We believe that this problem is due to a buildup of starting reagents at low temperatures.
C&EN
안전 데이터
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- UN 3399 4.3/PG 1
- 독성
- There is little toxicity data available for the butyllithiums; for data on ether and hydrocarbon solvents, see the appropriate LCSSs.
- HS 번호
- 29319090
- risk_code
- 14/15-17-34-48/20-51/53-62-65-67-63-35-11-15-50/53-66
- hazard_code
- F,C,N
- safety_code
- 6-9-16-26-36/37/39-45-61-62-6A-46-43B-43-60-33-29-5
- 포장분류
- I
- 위험 등급
- 4.3
- 기존화학 물질
- KE-04320
- F 고인화성물질
- 3-10
- 자연 발화 온도
- 240°C
- Hazard Classifications
- Aquatic Chronic 2Asp. Tox. 1Eye Dam. 1Flam. Liq. 2Pyr. Liq. 1Skin Corr. 1BSTOT SE 3Water-react 1
- 스토리지 클래스
- 4.2 - Pyrophoric and self-heating hazardous materials
화학 및 산업
응용 분야
용도n-Butyllithium is used as a polymerization initiator in the production of elastomers like polybutadiene and styrene- butadiene- styrene. As a strong base, it is utilized in the synthesis of organic compounds. It undergoes thermal decomposition to prepare 1-butene.
제조 방법
Industrially, n-butyllithium is produced by the reaction of n-butyl chloride with lithium metal dispersion in various hydrocarbon solvents. Hexane is the most commonly used solvent. Up to one-half of the lithium is replaced with sodium in order to lower the cost of the butyllithium and increase the reactivity of the dispersion. The reaction is carried out below the boiling point of the solvent.The laboratory procedure is essentially the same except that pentane and diethyl ether are two of the more popular solvents. The preparation runs smoothly in ether at lower temperatures but the product must either be used immediately or kept refrigerated due to the rapid cleavage of ether by n-butyllithium.
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