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아코발트 아세트산, 테트라수화물

Cobalt(II) acetate tetrahydrate

HCID 61372
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기본 정보이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
6147-53-1
표준 SMILES
CC(=O)[O-].CC(=O)[O-].O.O.O.O.[Co+2]
InChIKey
ZBYYWKJVSFHYJL-UHFFFAOYSA-L
분자식
C4H6CoO4.4H2O
평균 분자량
249.08 g/mol
단동위원소 질량
249.00206241

이름 및 식별자

우선 이름
Cobalt(II) acetate tetrahydrate
IUPAC
cobalt(2+);diacetate;tetrahydrate
현지명
아코발트 아세트산, 테트라수화물
영어명
Cobalt(II) acetate tetrahydrate
분자식
C4H14CoO8
분자량
249.08

이름 및 동의어

Cobalt(II) acetate tetrahydrate6147-53-1Cobaltous acetate tetrahydrateCCRIS 9441UNII-7648Z91O1NAcetic acid, cobalt(2+) salt, tetrahydrate7648Z91O1NDTXSID80210423BIS(ACETATO)TETRAAQUOCOBALTCOBALTOUS ACETATE TETRAHYDRATE [MI]Cobalt (II) diacetateRefChem:127234
이름 더 보기
아세트산,코발트(2+)염,테트라수화물코발트아세테이트테트라하이드레이트코발트(2+)아세트산테트라수화물코발트(II)아세트산테트라수화물아코발트아세트산,테트라수화물코발트디아세트산테트라수화물코발트(II)아세테이트테트라하이드레이트아코발트아세트산,테트라수화물(COBALTOUSACETATE,TETRAHYDRATE)Cobalt diacetateACETIC ACID COBALT (II) SALT TETRAHYDRATECOBALT ACETATCobaltAcetateAroctankobaltnatyANTI-MOUSE LAMP-1ANTI-MOUSE CD107ACobalt acetate, GRCobalt tetrahydrate
Acetic acid, cobalt(+2) saltCobaltous diacetate tetrahydrateCobaltous acetate (tetrahydrate)DTXCID80132914612-153-6Cobalt(II) diacetateCobalt acetate tetrahydrateCobalt diacetate tetrahydrate

데이터베이스 식별자

CAS
6147-53-1
PubChem CID
61372
DTXSID
DTXSID80210423
UNII
7648Z91O1N
EC Number
612-153-6

물성

구조 계산 물성

극성 표면적
84.3 Ų
수소 결합 공여자 수
4
수소 결합 수용자 수
8
회전 가능 결합 수
0
무거운 원자 수
13
형식 전하
0
복잡도
25.5

실험 및 물리화학적 성질

Chemical ClassesMetals -> Organic Acids, Metal Salts
Density1.7 g/cm³
SolubilitySolubility in water, g/100ml at 25 °C: (very good)
Melting Point140 °C
Physical Description · 3건

Dry Powder

Intense red solid; [Merck Index] Violet crystals, soluble in water; [MSDSonline] Delliquescent; [Ullmann]

RED CRYSTALS.

물리화학적 성질

녹는점
140 °C · 140 °C
밀도
1 · 1,71 g/cm3
굴절률
1.542 · 1.542
저장 조건
5 °C · Store at +5°C to +30°C.
용해도
348 g/L · 348g/L
물리적 상태
고체
색상
빨간색
Specific Gravity
1.71 · 1.71
냄새
아세트산 냄새
수소이온지수(pH)
7.2 · 7.2 (50g/l, H2O, 20℃)
수용성
380 g/L · 380g/L(20℃)

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]

P203, P233, P260, P261, P271, P272, P273, P280, P284, P302+P352, P304+P340, P318, P321, P333+P317, P342+P316, P362+P364, P391, P403, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 2209 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H350: May cause cancer [Danger Carcinogenicity]

유해성 정보

Regulatory Information · 4건

Chemical: Acetic acid, cobalt(2+) salt, tetrahydrate

Regulation (EC) No 1831/2003 (amended)

Acetic acid, cobalt(2+) salt, hydrate (2:1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Acetic acid, cobalt(2+) salt, hydrate (2:1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Cobalt (II) acetate tetrahydrate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Soluble cobalt (II) and salts: Human health tier II assessment
Fire HazardsNot combustible. Gives off irritating or toxic fumes (or gases) in a fire.
Hazards SummaryA skin, eye, and respiratory tract irritant; May cause skin sensitization; [ICSC] Harmful if swallowed; May cause skin and respiratory tract sensitization; [MSDSonline] See Cobalt.
Chemical DangersDecomposes on heating. This produces irritating fumes. Reacts with strong oxidants. This generates fire and explosion hazard.

화학 및 산업

용도 및 제조

Uses · 2건

Used in sympathetic inks, feed additives, catalysts, foam stabilizers, driers for coatings, and anodizing; [Hawley]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

U.S. Production2023: <50,000 lb
Industry UsesCatalyst
General Manufacturing InformationPlastics Material and Resin Manufacturing
응용 분야 · 2건

용도Cobalt(II) acetate tetrahydrate is used to prepare complexes for examination of the properties of metals with unusual coordination geometries. used as a catalyst for oxidation and esterification. used as an industrial catalyst to harden paints and varnishes, an active catalyst for oxidation and esterification reactions.

일반 설명Cobalt(II) acetate tetrahydrate has an octahedral structure, the central cobalt orbit is coordinated by four water molecules and two acetate ligands. Cobalt(II) acetate tetrahydrate becomes anhydrous by 140oC.

상·하류 제품 정보

상류 원료

코발트(II) 아세테이트Metal cobalt

하류 제품

코발트TPP(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II)5,10,15,20-Tetrakis-(4-aminophenyl)-porphyrin-Co-(II)

관련 반응

109건
반응 기록 만들기
HRID 18851 반응식
HRID 18851촉매로uspto-grants-2010_06
HRID 18852 반응식
HRID 18852촉매로uspto-grants-2010_06
HRID 18853 반응식
HRID 18853촉매로uspto-grants-2010_06
HRID 18856 반응식
HRID 18856촉매로uspto-grants-2010_06
HRID 18857 반응식
HRID 18857촉매로uspto-grants-2010_06
HRID 18858 반응식
HRID 18858촉매로uspto-grants-2010_06
HRID 18859 반응식
HRID 18859촉매로uspto-grants-2010_06
HRID 18860 반응식
HRID 18860촉매로uspto-grants-2010_06
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화합물 노트

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더보기
새 노트새 반응견적 요청하기
Merck
14 · 14,2433
BRN
3731397 · 3731397
안정성
안정적인. 습기, 열을 피하십시오.
InChI
1S/2C2H4O2.Co.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2
InChIKey
ZBYYWKJVSFHYJL-UHFFFAOYSA-L
SMILES
[H]O[H].[H]O[H].[H]O[H].[H]O[H].CC(=O)O[Co]OC(C)=O
EPA
Cobalt acetate tetrahydrate (6147-53-1)

화학적 성질

Reddish violet deliequecent crystals.

Packaging and Labelling
Do not transport with food and feedstuffs.
Hazard Classes and Categories · 4건

Skin Sens. 1 (100%)

Acute toxicity - category 4

Acute toxicity (Oral) - Category 4

Carcinogenicity - Category 1B

안전 및 보호

Fire FightingIn case of fire in the surroundings, use appropriate extinguishing media.
First Aid Measures · 4건

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower. Seek medical attention if you feel unwell.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .

Safe StorageSeparated from strong oxidants. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.
Exposure Control and Personal ProtectionBiological Exposure Indices (BEI) [ACGIH] - Cobalt in urine = 15 ug/L; sample at end of shift at end of workweek;
Spillage Disposal · 1건

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Then store and dispose of according to local regulations.

Eye PreventionWear safety goggles or eye protection in combination with breathing protection.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.
Skin PreventionProtective gloves. Protective clothing.
Exposure PreventionPREVENT DISPERSION OF DUST! AVOID ALL CONTACT!
Ingestion PreventionDo not eat, drink, or smoke during work. Wash hands before eating.
Inhalation PreventionUse local exhaust or breathing protection.
Threshold Limit Values (TLV)0.02 [mg/m3], as Co

독성 정보

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Exposure RoutesThe substance can be absorbed into the body by inhalation and by ingestion.
Signs and Symptoms · 4건

Cough. Shortness of breath. Sore throat.

Redness.

Redness. Pain.

Abdominal pain. Nausea. Vomiting.

ICSC Environmental DataBioaccumulation of this chemical may occur in seafood.

안전 데이터

wgk
2
tsca
No
rtecs
AG3325000
ridadr
3077
HS 번호
29152300
risk_code
22-38-40-43-53-50/53-42/43-36/37/38-20/21/22-68-60-49
hazard_code
Xn,N,T
safety_code
36/37-61-45-29-24-22-37/39-36/37/39-26-60-53
포장분류
III
위험 등급
9
Hazard Classifications
Acute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Carc. 1B InhalationEye Irrit. 2Muta. 2Repr. 1BResp. Sens. 1Skin Sens. 1
스토리지 클래스
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects