기본 정보
- CAS
10026-06-9- 표준 SMILES
O.O.O.O.O.[Cl][Sn]([Cl])([Cl])[Cl]- InChIKey
KHMOASUYFVRATF-UHFFFAOYSA-J- 분자식
- Cl4Sn.5H2O
- 평균 분자량
- 350.6 g/mol
- 단동위원소 질량
- 349.83042884
개요
Stannic chloride pentahydrate is a white colored solid. It is soluble in water. It is toxic by ingestion, inhalation and skin absorption. It is used to make perfumes and dyes.
이름 및 식별자
- 우선 이름
- Stannic chloride pentahydrate
- IUPAC
- tetrachlorostannane;pentahydrate
- 현지명
- 염화제이석 5수
- 영어명
- Tin(IV) chloride
- 분자식
- Cl4H2OSn
- 분자량
- 278.53
이름 및 동의어
Tin(IV) chloride pentahydrateStannic chloride pentahydrateStannane, tetrachloro-, pentahydrateTetrachlorostannane pentahydrateUN2440Stannic chloride, pentahydrateDTXSID6074413TIN TETRACHLORIDE, (HYDRATED)TIN TETRACHLORIDE, [HYDRATED]Tin chloride (SnCl4), pentahydrateRefChem:888978DTXCID0032493
이름 더 보기
염화제이석5수염화주석(IV)주석염화물,펜타수화물주석염화물,펜타수화물(STANNICCHLORIDE,PENTAHYDRATE)주석의 염화물, 오수화물TIN(IV) CHLORIDETin(IV) chloride hydrateOlovo Stanicoride pentahydrate4-(289-Butyl)phenolStannic chloride hydSTANNIC CHLORIDE 5H2O
Stannane, tetrachloro, pentahydrateTIN TETRACHLORIDE, PENTAHYDRATESTANNIC TETRACHLORIDE PENTAHYDRATE600-048-810026-06-9Tin chloride pentahydratetin (IV) chloride pentahydratetetrachlorostannane;pentahydrate
데이터베이스 식별자
- CAS
10026-06-9- PubChem CID
- 61442
- DTXSID
DTXSID6074413- EC Number
- 600-048-8
물성
구조 계산 물성
- 극성 표면적
- 5 Ų
- 수소 결합 공여자 수
- 5
- 수소 결합 수용자 수
- 5
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 10
- 형식 전하
- 0
- 복잡도
- 19.1
실험 및 물리화학적 성질
Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical Description
Stannic chloride pentahydrate is a white colored solid. It is soluble in water. It is toxic by ingestion, inhalation and skin absorption. It is used to make perfumes and dyes.
White or slightly yellow solid with a mild odor of hydrogen chloride; [Merck Index]
물리화학적 성질
- 녹는점
- 56 °C · 56 °C
- 밀도
- 2.04 · 2.040
- 용해도
- 2 O; · very soluble in H2O; soluble in ethanol
- 물리적 상태
- 덩어리
- 색상
- 연노랑
- 수용성
- 녹는
- 비열
- 0.59 J/ · Cp(liquid): 0.59 J/(g·K); Cp(gas): 0.35 J/(g·K), at 25℃
- Merck
- 14 · 14,8774
- 안정성
- 안정적이지만 습기나 물과 접촉하면 분해될 수 있습니다. 강산과 호환되지 않습니다.
- InChI
- InChI=1S/4ClH.H2O.Sn/h4*1H;1H2;/q;;;;;+4/p-4
- InChIKey
- KHMOASUYFVRATF-UHFFFAOYSA-J
- SMILES
- [Sn](Cl)(Cl)(Cl)Cl.O
- EPA
- Stannane, tetrachloro-, pentahydrate (10026-06-9)
화학적 성질
White solid. Soluble in water or alcohol.
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Danger
H314 (98%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P261, P264, P264+P265, P271, P273, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 50 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Regulatory Information
Chemical: Stannane, tetrachloro-, pentahydrate
Tin (IV) chloride, pentahydrate: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelCorrosive
Fire Hazards
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Health Hazards
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.
Hazards Summary
Intravenous LD50 (mouse) = 32 mg/kg; [RTECS] Corrosive; [Merck Index] Reacts with water evolving hydrochloric acid; Toxic by ingestion, inhalation, and skin absorption; [CAMEO] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS] See Stannic chloride.
DOT ID and Guide2440 154
Reactive GroupAcids, Strong Non-oxidizing
Reactivity AlertsWater-Reactive
Reactivity ProfileSTANNIC CHLORIDE readily hydrolyzes to form hydrochloric acid in aqueous solution or moist air. Combination of stannic chloride with turpentine is strongly exothermic, and may lead to ignition [Mellor, 1941, Vol. 7, 446].
DOT Hazard Classification
Stannic chloride pentahydrate
UN2440
Class 8 Corrosive material (49 eCFR § 173.136)
PG III: the degree of danger presented by the material is minor
Air and Water ReactionsSoluble in water. Reacts with water to form Hydrochloric Acid in dense white fumes [Merck 11th ed. 1989].
Hazard Classes and CategoriesSkin Corr. 1B (98%)
안전 및 보호
Fire FightingExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
General First Aid:
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Isolation and Evacuation
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Immediate precautionary measure
Threshold Limit Values (TLV)2.0 [mg/m3], as Sn
Permissible Exposure Limit (PEL)2.0 [mg/m3], as Sn
Personal Protective Equipment (PPE)Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Emergency Response Planning GuidelinesSmall Fire
독성 정보
Adverse EffectsDermatotoxin - Skin burns.
안전 데이터
- wgk
- 3
- rtecs
- XP8870000
- ridadr
- UN 2440
- HS 번호
- 28273990
- risk_code
- 34-52/53
- hazard_code
- C
- safety_code
- 26-36/37/39-45-7/8-61
- 포장분류
- III
- 위험 등급
- 8
- Hazard Classifications
- Aquatic Chronic 3Skin Corr. 1B
- 스토리지 클래스
- 8A - Combustible corrosive hazardous materials
- 함량 및 규제정보
- 물질구분: 유독물질; 혼합물(제품)함량정보: 무기주석 염류 및 이를 25% 이상 함유한 혼합물
- 유해화학물질 필터링
- 97-1-93
화학 및 산업
용도 및 제조
Uses
Used as a stabilizer for colors and perfumes in soap, in fabric dyeing (mordant), weighting silk, tinning vessels, and coating ceramics; [Merck Index] Used to make dyes and perfumes; [CAMEO]
Textiles (Printing, Dyeing, or Finishing) [Category: Industry]
Ceramics making [Category: Hobbies]
응용 분야
용도Substitute for anhydrous stannic chloride where the presence of water is not objectionable
일반 설명Stannic chloride pentahydrate is a white colored solid. Stannic chloride pentahydrate is soluble in water. Stannic chloride pentahydrate is toxic by ingestion, inhalation and skin absorption. Stannic chloride pentahydrate is used to make perfumes and dyes.
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