기본 정보
- CAS
10241-05-1- 표준 SMILES
[Cl][Mo]([Cl])([Cl])([Cl])[Cl]- InChIKey
GICWIDZXWJGTCI-UHFFFAOYSA-I- 분자식
- Cl5Mo
- 평균 분자량
- 273.2 g/mol
- 단동위원소 질량
- 272.7496716
개요
Molybdenum pentachloride is a green-black odorless solid. It is toxic by ingestion and an irritant to skin. It may react with water to produce corrosive hydrochloric acid and toxic fumes.
이름 및 식별자
- 우선 이름
- Molybdenum pentachloride
- IUPAC
- pentachloromolybdenum
- 현지명
- 몰리브덴 오염화물
- 영어명
- MOLYBDENUM(V) CHLORIDE
- 분자식
- Cl5Mo
- 분자량
- 273.2
이름 및 동의어
Molybdenum(V) chlorideMolybdenum pentachloride10241-05-1PentachloromolybdenumMoCl5BB0UFP2VO5CHEBI:30635RefChem:159384DTXCID1032721233-575-3DTXSID0065012MOLYBDENUM CHLORIDE (MoCl5)
이름 더 보기
몰리브덴오염화물오염화몰리브덴오염화몰리브덴MOLYBDENUM CHLORIDEybdenum(V) chLMOLYBDENUMCHLORIDE(V)MOLYBDENUM(+5)CHLORIDEmolybdenumchloride(mocl5)Molybdenum(V)pentachloride
MFCD00003467EINECS 233-575-3UNII-BB0UFP2VO5UN2508pentachloridomolybdenum[MoCl5]SCHEMBL454117Molybdenum(V) chloride, 95%
데이터베이스 식별자
- CAS
10241-05-1- PubChem CID
- 61497
- DTXSID
DTXSID0065012- ChEBI
CHEBI:30635- EC Number
- 233-575-3
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 0
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 6
- 형식 전하
- 0
- 복잡도
- 37.1
실험 및 물리화학적 성질
Chemical Classes
Metals -> Metals, Inorganic Compounds
Corrosives
Density2.93 @25 °C
Boiling Point268 °C @760 [mm Hg]
Physical Description
Molybdenum pentachloride is a green-black odorless solid. It is toxic by ingestion and an irritant to skin. It may react with water to produce corrosive hydrochloric acid and toxic fumes.
Green-black solid; Dark-red as liquid or vapor; Hygroscopic; Reacts with water and air; [Hawley] Black crystalline solid with a pungent odor; Reacts with water; [MSDSonline]
물리화학적 성질
- 녹는점
- 194 °C · 194 °C (lit.)
- 끓는 점
- 268 °C · 268 °C (lit.)
- 밀도
- 2.928 g/mL · 2.928 g/mL at 25 °C (lit.)
- 증기압
- 1.75 mm · 1.75 mm Hg ( 25 °C)
- 용해도
- 건조 에테르, 건조 알코올, 유기 용매 및 염소화 용매에 용해됩니다.
- 물리적 상태
- 가루
- 색상
- 흰색에서 회색으로
- Specific Gravity
- 2.928 · 2.928
- 수용성
- 93 · 건조 에테르 및 건조 알코올, 기타 유기 용매에 용해됨 [HAW93]
- 안정성
- 안정적이지만 습기와 공기에 민감합니다. 물과 접촉하면 독성 가스가 방출됩니다. 물, 강한 산화제와 호환되지 않습니다.
- InChI
- InChI=1S/5ClH.Mo/h5*1H;/q;;;;;+5/p-5
- InChIKey
- GICWIDZXWJGTCI-UHFFFAOYSA-I
- SMILES
- [Mo](Cl)(Cl)(Cl)(Cl)Cl
- EPA
- Molybdenum chloride (MoCl5) (10241-05-1)
화학적 성질
Green-black solid, dark red as liquid orvapor.Hygroscopic,reacting with water and air. Soluble in dry ether,dry alcohol, and other organic solvents.
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Danger
H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 71 reports by companies from 6 notifications to the ECHA C&L Inventory.
유해성 정보
Regulatory Information
Chemical: Molybdenum chloride (MoCl5)
Molybdenum (V) chloride: Does not have an individual approval but may be used under an appropriate group standard
The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelCorrosive
Fire Hazards
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
· Combustible material: may burn but does not ignite readily.
Health Hazards
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.
Hazards Summary
An irritant; [Hawley] May react with water evolving hydrochloric acid; A skin irritant; [CAMEO] Corrosive to skin and eyes; [eChemPortal: ERMA] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Molybdenum.
DOT ID and Guide2508 156
Reactive GroupHalogenating Agents
Reactivity AlertsWater-Reactive
Reactivity Profile
MOLYBDENUM PENTACHLORIDE is a corrosive, hygroscopic solid, on contact with water or steam it decomposes to form hydrochloric acid. When heated to decomposition it emits toxic fumes of molybdenum chlorides and metallic molybdenum [Lewis, 3rd ed., 1993, p. 892]. Explodes on contact with finely divided sodium [Berry D. H., Chem. Eng. News, 1989, 67(47), p. 2]. Reaction with finely divided sodium sulfide is violent, may lead to autoignition [Kaner, R. B., Nature, 1991, 349, p. 510].
DOT Hazard Classification
Molybdenum pentachloride
UN2508
Class 8 Corrosive material (49 eCFR § 173.136)
PG III: the degree of danger presented by the material is minor
Air and Water ReactionsMolybdenum pentachloride may react with water to produce corrosive hydrochloric acid and toxic fumes.
Hazard Classes and Categories
Skin Corr. 1B (100%)
Corrosives, Reactive agents - 2nd degree
안전 및 보호
Fire FightingExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
General First Aid:
Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Isolation and Evacuation
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Immediate precautionary measure
Threshold Limit Values (TLV)0.5 [mg/m3], as Mo, respirable fraction
Permissible Exposure Limit (PEL)5.0 [mg/m3], as Mo
Protective Action Criteria (PAC)
1.8 [ppm]
22 [ppm]
100 [ppm]
Personal Protective Equipment (PPE)Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Emergency Response Planning Guidelines· Note: Most foams will react with the material and release corrosive/toxic gases.
독성 정보
Adverse EffectsDermatotoxin - Skin burns.
안전 데이터
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- QA4690000
- ridadr
- UN 2508
- HS 번호
- 28273985
- risk_code
- 29-34-48/20/22-40
- hazard_code
- C
- safety_code
- 26-36/37/39-43-45
- 포장분류
- III
- 위험 등급
- 8
- 기존화학 물질
- KE-25451
- F 고인화성물질
- 1-3-10
- Hazard Classifications
- Carc. 2Eye Dam. 1Skin Corr. 1B
- 스토리지 클래스
- 8A - Combustible corrosive hazardous materials
화학 및 산업
용도 및 제조
Uses
Used as a chlorination catalyst and intermediate; Also used in molybdenum coatings, fire-retardant resins, and brazing/soldering fluxes; [Hawley]
Brazing [Category: Heat or Machine]
General Manufacturing InformationMolybdenum chloride (MoCl5): ACTIVE
응용 분야
용도Chlorination catalyst, vapor-deposited molyb-denum coatings, component of fire-retardant resins,brazing and soldering flux, intermediate fororganometallic compounds, e.g., molybdenum hex-acarbonyl.
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하류 제품
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