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펜타플루오린화 염소(펜타플루오르화 염소)

Chlorine pentafluoride

HCID 61654
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
구조도 없음

기본 정보

CAS
13637-63-3
InChIKey
KNSWNNXPAWSACI-UHFFFAOYSA-N
분자식
ClF5
평균 분자량
130.44 g/mol

개요

Chlorine pentafluoride appears as a colorless gas with a sweet odor. Toxic by inhalation and an irritant to skin, eyes and mucus membranes. Corrosive. Heavier than air. Under prolonged exposure to fire or intense heat the containers may violently rupture or rocket. Used as an oxidizer in propellants.

이름 및 식별자

우선 이름
Chlorine pentafluoride
IUPAC
pentafluoro-λ5-chlorane
현지명
펜타플루오린화 염소(펜타플루오르화 염소)
영어명
CHLORINE PENTAFLUORIDE
분자식
ClF5
분자량
130.45

이름 및 동의어

CHLORINE PENTAFLUORIDE13637-63-3Chlorine fluoride (ClF5)O4RJ1HW01HDTXSID90894056RefChem:125328DTXCID901324098237-123-6pentafluoro-lambda5-chloraneEINECS 237-123-6UN2548UNII-O4RJ1HW01H
이름 더 보기
펜타플루오르화염소펜타플루오린화염소(펜타플루오르화염소)펜타플루오린화염소(펜타플루오르화염소)(CHLORINEPENTAFLUORIDE)염소오불화물ClF5chlorinefluoride(clf5)Chlorinepentafluoride99%Chlorine pentafluoride 99%pentafluoro-λ5-chlorane
Pentafluoro-lambda~5~-chloraneKNSWNNXPAWSACI-UHFFFAOYSA-NSBB085767DB-243239Chlorine pentafluoride [UN2548] [Poison gas]Q419447

데이터베이스 식별자

CAS
13637-63-3
PubChem CID
61654
DTXSID
DTXSID90894056
UNII
O4RJ1HW01H
EC Number
237-123-6
Nikkaji
J74.677K

물성

구조 계산 물성

XLogP
3.6
극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
5
회전 가능 결합 수
0
무거운 원자 수
6
형식 전하
0
복잡도
37.1

실험 및 물리화학적 성질

Chemical Classes · 2건

Toxic Gases & Vapors -> Oxidizers

Corrosives

Density5.332 g/L
Boiling Point-13.1 °C @760 [mm Hg]
Melting Point-103 °C
Physical Description · 2건

Chlorine pentafluoride appears as a colorless gas with a sweet odor. Toxic by inhalation and an irritant to skin, eyes and mucus membranes. Corrosive. Heavier than air. Under prolonged exposure to fire or intense heat the containers may violently rupture or rocket. Used as an oxidizer in propellants.

Colorless gas with a sweet odor; [CAMEO]

물리화학적 성질

녹는점
-103 °C · -103°C
끓는 점
-13 · -13,1°C
밀도
1.774 · 1.774 (estimate)
물리적 상태
무색 가스
색상
무색의
EPA
Chlorine fluoride (ClF5) (13637-63-3)

화학적 성질

colorless gas; critical temp 142.6°C; enthalpy of vaporization 22.21 kJ/mol; specific conductivity 1.25×109 ohm· cm [KIR78]

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 4건

Danger

H270 (100%): May cause or intensify fire; oxidizer [Danger Oxidizing gases]

P220, P244, P260, P264, P271, P280, P284, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P320, P321, P363, P370+P376, P403, P403+P233, P405, P410+P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 111 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazards IdentificationToxic/poison by inhalation (TIH/PIH)
Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
DOT LabelPoison Gas Oxidizer Corrosive
Fire Hazards · 2건

Excerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:

· Substance does not burn but will support combustion.

Health Hazards · 2건

Excerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:

· TOXIC and/or CORROSIVE; may be fatal if inhaled or absorbed through skin.

Hazards SummaryReacts with water or moisture in the air to form hydrofluoric acid and chloride gas; Contact with liquefied gas can cause burns or frostbite; May be fatal if inhaled or absorbed through skin; [CAMEO]
DOT ID and Guide2548 124
Reactive Group

화학 및 산업

용도 및 제조

UsesUsed as a propellant; [CAMEO]
응용 분야 · 2건

용도Chlorine pentafluoride does not have anysignificant commercial application. It is usedas a fluorinating and oxidizing agent.

일반 설명A colorless gas with a sweet odor. Toxic by inhalation and an irritant to skin, eyes and mucus membranes. Corrosive. Heavier than air. Under prolonged exposure to fire or intense heat the containers may violently rupture or rocket. Used as an oxidizer in propellants.

관련 반응

0건
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현재 필터 조건에 해당하는 반응 기록이 없습니다.

화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
Oxidizing Agents, Strong
Reactivity AlertsStrong Oxidizing Agent
Reactivity Profile · 1건

CHLORINE PENTAFLUORIDE is a strong oxidizing agent. Nonflammable, but likely to react vigorously on contact with combustible materials. Reacts violently with lithium, calcium. Emits highly toxic fluoride and chloride fumes when heated to decomposition. Extremely vigorous reaction with water, steam, even ice [Pilipovich D. et al., Inorg. Chem., 1967, 6, p. 1918]. Very vigorous reaction with anhydrous nitric acid even at -100 °C [Christie, K. O., Inorg. Chem. 1992, 11, p. 1220].

DOT Hazard Classification · 4건

Chlorine pentafluoride

UN2548

Div 2.3 Poisonous gas (49 eCFR § 173.115)

Div 2.3 Poisonous gas (49 eCFR § 173.115)

Air and Water Reactions · 1건

Reacts with water or moisture in the air to produce corrosive hydrofluoric acid and toxic chlorine gas. Interaction with ice at -100 °C, or with water vapor above 0 °C is extremely vigorous (Christe, K.O. Inorg. Chem. 1972 11, 1220). Hydrochloric acid fumes might also be generated upon reaction with water.

안전 및 보호

Fire FightingExcerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:
Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Do not touch or walk through spilled material.

First Aid · 2건

Excerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:

General First Aid:

Exposure Control and Personal Protection · 3건

· Wear positive pressure self-contained breathing apparatus (SCBA).

TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].

1.0 [mg/m3], as F, inhalable fraction[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:
Isolation and Evacuation · 4건

Excerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:

Immediate precautionary measure

Small spill:

Small spill:

Threshold Limit Values (TLV)2.5 [mg/m3], as F
Permissible Exposure Limit (PEL)2.5 [mg/m3], as F
Protective Action Criteria (PAC) · 3건

0.015 [ppm]

0.17 [ppm]

8.0 [ppm]

Personal Protective Equipment (PPE)Excerpt from ERG Guide 124 [Gases - Toxic and/or Corrosive - Oxidizing]:
Emergency Response Planning GuidelinesCAUTION: These materials do not burn but will support combustion. Some will react violently with water.
Immediately Dangerous to Life or Health (IDLH) · 2건

1.7 ppm [From IDLH Table: Chlorine Pentafluoride] (NIOSH, 2024)

9.05 [mg/m3]

독성 정보

Adverse EffectsDermatotoxin - Skin burns.
Toxicity DataLC50 (rat) = 122 ppm/1H

규제 정보

DHS Chemicals of Interest (COI) · 4건

Chlorine pentafluoride

4.07

15

Weapons of Mass Effect chemical material that, if stolen or diverted, can be converted into weapons using simple chemistry, equipment, or techniques.

안전 데이터

IDLA
1.7 ppm
ridadr
UN 2548
HS 번호
2812199000
hazard_code
O
safety_code
17-36/37/39
위험 등급
2.3
위험 참고 사항
Oxidising agent