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Cuprous potassium cyanide

HCID 61666
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
13682-73-0
표준 SMILES
[C-]#N.[C-]#N.[Cu+].[K+]
InChIKey
IVDPWEKOUUEEBD-UHFFFAOYSA-N
분자식
KCu(CN)2
평균 분자량
154.68 g/mol
단동위원소 질량
153.899452

개요

Potassium cuprocyanide appears as a white crystalline solid. Denser than water. Contact may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion and inhalation.

이름 및 식별자

우선 이름
Cuprous potassium cyanide
IUPAC
potassium;copper(1+);dicyanide

이름 및 동의어

Cuprous potassium cyanidePotassium dicyanocupratePotassium copper(I) cyanideCopper(I) potassium cyanidePotassium cuprocyanidePotassium dicyanocuprate(1-)Cuprate(1-), dicyano-, potassiumEINECS 237-192-2J77YMP09YDCuprate(1-), bis(cyano-kappaC)-, potassiumDTXSID901014552Cuprate(1-), bis(cyano-kappaC)-, potassium (1:1)
이름 더 보기
Potassiocuprous cyanideCuprate(1-), bis(cyano-C)-, potassiumRefChem:580053Potassium dicyanocuprate(1)Cuprate(1), dicyano, potassiumDTXCID701473148Cuprate(1), bis(cyanokappaC), potassiumBis(cyanokappaC)cuprate(1) potassium (1:1)

데이터베이스 식별자

CAS
13682-73-0
PubChem CID
61666
DTXSID
DTXSID901014552
EC Number
237-192-2

물성

구조 계산 물성

극성 표면적
47.6 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
4
회전 가능 결합 수
0
무거운 원자 수
6
형식 전하
0
복잡도
31.6

실험 및 물리화학적 성질

Chemical ClassesToxic Gases & Vapors -> Cyanides
Physical Description · 3건

Potassium cuprocyanide appears as a white crystalline solid. Denser than water. Contact may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion and inhalation.

Other Solid

White solid; Contains at least 26% copper and 1-3% free KCN; [Hawley] Reddish, lustrous, odorless solid; Inslouble in water; [MP Biomedicals MSDS]

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H300 (100%): Fatal if swallowed [Danger Acute toxicity, oral]

P260, P262, P264, P270, P271, P273, P280, P284, P301+P316, P302+P352, P304+P340, P316, P320, P321, P330, P361+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

Danger

H316: Causes mild skin irritation [Warning Skin corrosion/irritation]

유해성 정보

Regulatory Information · 1건

Cuprate(1-), bis(cyano-.kappa.C)-, potassium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cuprate(1-), bis(cyano-.kappa.C)-, potassium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

DOT LabelPoison
Fire Hazards · 2건

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards · 2건

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

Hazards Summary · 1건

Acute copper poisoning after ingestion can cause liver injury, methemoglobinemia, and hemolytic anemia. Acute renal failure may result, secondary to massive hemoglobinuria. [Goldfrank, p. 1259] An irritant; [MP Biomedicals MSDS] See Copper and CYANIDES.

화학 및 산업

용도 및 제조

Uses · 2건

Used in cyanide copper plating baths; [Hawley] Used in electroplating of copper and brass; [Merck Index]

Electroplating [Category: Plate]

U.S. Production2023: 11,000 lb
Industry UsesPlating agent
General Manufacturing Information · 2건

Fabricated Metal Product Manufacturing

Cuprate(1-), bis(cyano-.kappa.C)-, potassium (1:1): ACTIVE

관련 반응

0건
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화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
DOT ID and Guide
1679 157
Reactive GroupCyanides, Inorganic
Reactivity Profile · 1건

POTASSIUM CUPROCYANIDE is an inorganic cyanide. Members of this class that contain heavy metals tend to explosive instability, most of them are capable of violent oxidation under certain condition; fusion of metal cyanides with metal chlorates, perchlorates, nitrates or nitrites can cause violent explosions [Bretherick 1979. p. 101].

DOT Hazard Classification · 6건

Potassium cuprocyanide

Severe marine pollutant

Potassium cuprocyanide

UN1679

Div 6.1 Poisonous materials (49 eCFR § 173.132)

PG II: the degree of danger presented by the material is medium

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 2건

Acute Tox. 2 (100%)

Skin corrosion/irritation - Category 3

안전 및 보호

Fire FightingExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

General First Aid:

Exposure Control and Personal Protection · 2건

· Wear positive pressure self-contained breathing apparatus (SCBA).

2.0 [mg/m3], inhalable fraction, as CN (0.01 mg/m3, respirable fraction-Cu inorganic cmpds)[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
Isolation and Evacuation · 2건

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

Immediate precautionary measure

Permissible Exposure Limit (PEL)5.0 [mg/m3], as CN
Personal Protective Equipment (PPE)Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
Emergency Response Planning Guidelines· Note: Some foams will react with the material and release corrosive/toxic gases.
Immediately Dangerous to Life or Health (IDLH)25.0 [mg/m3], as CN

독성 정보

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.