Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
나트륨 오르토바나드산염
나트륨오르토바나드산염 · 나트륨오르토바나드산염(SODIUMORTHOVANADATE) · SODIUM VANADATE · Sodium orthavanadium · Sodium Orthovanadate(Ⅴ) · sodiumvanadate(v)(na3vo4) · trisodium tetraoxovanadate · DECAVANDATE
식별자 및 물리적 특성
| CAS No. | 13721-39-6 |
|---|---|
| 분자식 | Na3-V-O4 |
| 평균 분자량 | 183.908 g/mol |
| 단동위원소 질량 | 183.89292582 g/mol |
| SMILES | [Na+].[Na+].[Na+].[O]=[V]([O-])([O-])[O-] |
| InChIKey | IHIXIJGXTJIKRB-UHFFFAOYSA-N |
| PubChem CID | 61671 |
| ChEBI | CHEBI:35607 |
| EC No. | 237-287-9 |
| DTXSID | DTXSID2037269 |
| 현지명 | 나트륨 오르토바나드산염 |
화학 및 물리적 성질
| 극성 표면적 | 86.3 |
|---|---|
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 4 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 8 |
| 형식 전하 | 0 |
| 복잡도 | 36.8 |
| 물질 분류 | Metals -> Metals, Inorganic Compounds |
| Physical Description | White odorless granules[Alfa Aesar MSDS] |
| 녹는점 | 850-866 °C(lit.) |
| 저장 조건 | Sealed in dry,Room Temperature |
| 용해도 | H2O: 용해성 |
| 물리적 상태 | 고체 |
| 색상 | 회백색 |
| 생물학적 소스 | synthetic (organic) |
| 용해도 | 녹는 |
| 안정성 | 안정적인. 강한 산화제와 호환되지 않습니다. |
| InChI | InChI=1S/3Na.4O.V |
| InChIKey | HQHUIUQMQXUPHI-UHFFFAOYSA-N |
| SMILES | [V](=O)(O[Na])(O[Na])O[Na] |
| EPA | Sodium vanadium oxide (Na3VO4) (13721-39-6) |
화학적 성질
It forms colourless hexagonal columnar crystals that are soluble in water but insoluble in ethanol.
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 1.7% (1 of 59) of reports.WarningH302 (98.3%): Harmful if swallowed [Warning Acute toxicity, oral]P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 59 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 규제 정보 | Chemical: Vanadate (VO43-), trisodium, (T-4)-Trisodium orthovanadate: Does not have an individual approval but may be used under an appropriate group standard |
| 유해성 요약 | Causes convulsions in subcutaneous lethal-dose studies[RTECS] A skin and strong eye irritantHarmful by ingestion and inhalationReproductive effects observed in experimental animals[Alfa Aesar MSDS] See Sodium metavanadate. |
| Hazard Classes and Categories | Acute Tox. 4 (98.3%) |
| Minimum Risk Level | Acute Inhalation: 0.0002 mg/m3 (L134) Intermediate Oral: 0.003 mg/kg/day (L134) |
| Protective Action Criteria (PAC) | 0.092 [mg/m3]1.0 [mg/m3]65 [mg/m3] |
| Treatment | EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration. |
| 건강 영향 | Breathing high levels of vanadium affects the lungs, throat, and eyes. Ingestion of vanadium may cause kidney and liver damage, birth defects, or death. (L837) |
| 노출 경로 | Oral (L837)inhalation (L837)dermal (L837) |
| 독성 요약 | Vanadium damages alveolar macrophages by decreasing the macrophage membrane integrity, thus impairing the cells' phagocytotic ability and viability. The pentavalent form of vanadium, vanadate, is a potent inhibitor of the Ca+-ATPase and Na+,K+-ATPase of plasma membranes, which decreases intracellular ATP concentration. Vanadium is also believed to induce the production of reactive oxygen species. This may damage DNA and also cause oxidative stress, which can damage the reproductive system. Vanadium also inhibits protein tyrosine phosphatases, producing insulin-like effects. (L837, A247, A248, A249, A250, A251) |
| Signs and Symptoms | Inhalation of vanadium causes lung irritation, coughing, wheezing, chest pain, runny nose, and a sore throat. (L837) |
| Carcinogen Classification | No indication of carcinogenicity to humans (not listed by IARC). |
| 수질 위해 등급(WGK) | 3 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | YW1120000 |
| 운송 번호(UN) | UN3285 |
| 관세 코드 | 28419030 |
| 위험 문구(R) | 20/21/22 |
| 위험 표시 | Xn |
| 안전 문구(S) | 22-36 |
| 포장분류 | III |
| 위험 등급 | 6.1Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralEye Irrit. 2Skin Irrit. 2 |
| 기존화학 물질 | KE-34917 |
| 저장 분류 | 13 - Non Combustible Solids |
제조 및 합성 방법
제조 방법
Sodium orthovanadate is produced by dissolving vanadium(V) oxide in a solution of sodium hydroxide: V2O5 + 6 NaOH → 2 Na3VO4 + 3 H2OThe salt features tetrahedral VO3-4 anion centers linked to octahedral Na+ cation sites.