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디아민 디클로로파라듐

Palladium, diamminedichloro-

HCID 61732
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
13782-33-7
표준 SMILES
N.N.[Cl][Pd][Cl]
InChIKey
WIEZTXFTOIBIOC-UHFFFAOYSA-L
분자식
Cl2H6N2Pd
평균 분자량
211.38 g/mol
단동위원소 질량
209.89428

개요

cis-Diamminedichloro-palladium(II) is a chemical compound of palladium. Palladium is a chemical element with the chemical symbol Pd and an atomic number of 46. It is found as a free metal alloyed with gold and other platinum group metals and in the rare minerals cooperite and polarite. (L794)

이름 및 식별자

우선 이름
Palladium, diamminedichloro-
IUPAC
azane;dichloropalladium
현지명
디아민 디클로로파라듐
영어명
Diamminedichloropalladium
분자식
Cl2H6N2Pd
분자량
211.38

이름 및 동의어

RefChem:858352238-269-314323-43-4ChloropalladosamineDiammine palladium (II) chlorideDiamminedichloropalladium (II)DiamminodichloropalladiumPalladium (II) diammine dichloridePalladium diammine dichloridePalladium, diamminedichloro-13782-33-7Diamminedichloropalladium
이름 더 보기
디아민디클로로파라듐50%PdTRANS-DIAMMITranspalladinTRANSPALLADIUMDiaMMine dichloropalDichlorodiaminopalladiumdichlorodiaminepalladiumPALLADIUM DICHLORODIAMINEPALLADIUM AMMINE CHLORIDE
trans-Diamminedichloropalladium(II)Diammine dichloropalladiumazane;dichloropalladiumtrans-Diammine dichloropalladiumtrans-Dichlorodiammine palladium (II)trans-Dichlorodiammine palladium(II)Palladium, diamminedichloro-, (SP-4-1)- (9CI)Diammine dichloropalladium ( cento)

데이터베이스 식별자

CAS
13782-33-7、14323-43-4、15684-18-1

물성

구조 계산 물성

극성 표면적
2 Ų
수소 결합 공여자 수
2
수소 결합 수용자 수
2
회전 가능 결합 수
0
무거운 원자 수
5
형식 전하
0
복잡도
2.8

실험 및 물리화학적 성질

Physical DescriptionWet Solid

물리화학적 성질

밀도
2.5 g/mL · 2.5 g/mL at 25 °C(lit.)
저장 조건
2 · under inert gas (nitrogen or Argon) at 2-8°C
물리적 상태
가루
색상
노란색
InChI
InChI=1S/2ClH.2H2N.Pd/h2*1H;2*1H2;/q;;2*-1;+4/p-2
InChIKey
LXSVNTRDMUGFLL-UHFFFAOYSA-L
SMILES
[Pd+2](N)(N)([Cl-])[Cl-]
EPA
Palladium, diamminedichloro-, (SP-4-1)- (13782-33-7)

화학적 성질

yellow powder(s) [STR93]

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H302+H332 (34%): Harmful if swallowed or if inhaled [Warning Acute toxicity, oral; acute toxicity, inhalation]

P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P304+P340, P305+P354+P338, P317, P330, P391, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 215 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H301 (95.1%): Toxic if swallowed [Danger Acute toxicity, oral]

유해성 정보

Regulatory Information · 3건

Chemical: Palladium, diamminedichloro-

Palladium, diamminedichloro- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Palladium, diamminedichloro- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Diamminedichloropalladium (EC: 238-269-3)

Other Safety InformationIMAP assessments - Palladium, diamminedichloro-: Environment tier I assessment
Hazard Classes and Categories · 2건

Acute Tox. 3 (95.1%)

Acute Tox. 4 (98.1%)

독성 정보

Treatment · 2건

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

화학 및 산업

약리 정보

Metabolism/Metabolites · 2건

Palladium may be absorbed through oral, dermal, and inhalation exposure. Once in the body it distributes to the kidney, liver, spleen, lymph nodes, adrenal gland, lung and bone. Palladium's ability to form complexes allows it the bind to amino acids, proteins, DNA, and other macromolecules. Palladium and its metabolites are excreted in the urine and faeces. (A21)

Palladium may be absorbed through oral, dermal, and inhalation exposure. Once in the body it distributes to the kidney, liver, spleen, lymph nodes, adrenal gland, lung and bone. Palladium's ability to form complexes allows it the bind to amino acids, proteins, DNA, and other macromolecules. Palladium and its metabolites are excreted in the urine and faeces. (A21)

용도 및 제조

U.S. Production2023: 75,000 - <500,000 lb
Industry UsesIntermediate
General Manufacturing Information · 2건

Other (requires additional information)

Palladium, diamminedichloro-: ACTIVE

응용 분야 · 1건

용도Diamminedichloropalladium (also known as trans-Diamminedichloropalladium(II), TDPD) is a chiral analytical reagent that can be used as an internal standard for determining cisplatin-derived platinum in human plasma ultrafiltrate. In addition, trace elements Cu, Ni, and Zn in TDPD and diamminedinitropalladium can be determined by flame atomic absorption spectroscopy.

공급사100 곳

北京华美互利生物化工010-56205725 · [email protected]
上海阿拉丁生化科技股份有限公司

관련 반응

0건
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화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
PubChem CID
61732
EC Number
237-437-3、238-269-3

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 2건

Contact with palladium may cause palladium sensitivity and allergy. Animal studies have shown that palladium may damage the liver and kidney. (L798)

Contact with palladium may cause palladium sensitivity and allergy. Animal studies have shown that palladium may damage the liver and kidney. (L798)

Toxicity Summary · 2건

Due to their ability to form strong complexes with both inorganic and organic ligands, palladium ions can disturb cellular equilibria, replace other essential ions, and interact with functional groups of macromolecules, such as proteins or DNA. Palladium complexes binding to DNA and RNA leads to strand breakage. Palladium ions are able to inhibit most major cellular functions, including DNA and RNA synthesis. Palladium compounds have been shown to bind to and inhibit various enzymes, including creatine kinase and prolyl hydroxylase. (L798)

Due to their ability to form strong complexes with both inorganic and organic ligands, palladium ions can disturb cellular equilibria, replace other essential ions, and interact with functional groups of macromolecules, such as proteins or DNA. Palladium complexes binding to DNA and RNA leads to strand breakage. Palladium ions are able to inhibit most major cellular functions, including DNA and RNA synthesis. Palladium compounds have been shown to bind to and inhibit various enzymes, including creatine kinase and prolyl hydroxylase. (L798)

Signs and Symptoms · 2건

Skin contact with palladium may cause contact dermatitis, erythema, and oedema. (L798)

Skin contact with palladium may cause contact dermatitis, erythema, and oedema. (L798)

Carcinogen Classification · 2건

No indication of carcinogenicity to humans (not listed by IARC).

No indication of carcinogenicity to humans (not listed by IARC).

안전 데이터

wgk
3
HS 번호
2843909000
risk_code
23/24/25-36/37/38
hazard_code
T
safety_code
22-26-36/37/39-45
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