루테늄(III) 염화물
루테늄(III)염화물 · 루테늄(III)염화물(RUTHENIUM(III)CHLORIDE) · RUCl3 · RUTHENIUM TRICHLORIDE · RUTHENIUM CHLORIDE · RUTHENIUM(III) CHLORIDE ANHYDROUS · Ruthenic chloride · Ruthenium(III) chL
식별자 및 물리적 특성
| CAS No. | 10049-08-8 |
|---|---|
| 분자식 | Cl3Ru |
| 평균 분자량 | 207.4 g/mol |
| 단동위원소 질량 | 206.81090734 g/mol |
| SMILES | [Cl][Ru]([Cl])[Cl] |
| InChIKey | YBCAZPLXEGKKFM-UHFFFAOYSA-K |
| PubChem CID | 61850 |
| EC No. | 233-167-5 |
| DTXSID | DTXSID101014308 |
| 현지명 | 루테늄(III) 염화물 |
화학 및 물리적 성질
| 극성 표면적 | 0 |
|---|---|
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 0 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 4 |
| 형식 전하 | 0 |
| 복잡도 | 8 |
| 물질 분류 | Metals -> Metals, Inorganic Compounds |
| SpringerMaterials Properties | crystal structure |
| 밀도 | 3.11 @25 °C3.11 g/mL at 25 °C (lit.) |
| Physical Description | alpha form: Black lustrous solidbeta form: Dark brown solid[Merck Index] Black hygroscopic crystals with a pungent odor[Alfa Aesar MSDS] |
| 녹는점 | 500 °C |
| 저장 조건 | Keep in dark place,Inert atmosphere,Room temperature |
| 용해도 | insoluble in H2Oslightly soluble in ethanol |
| 물리적 상태 | 분말 또는 결정 |
| 색상 | 검은색 |
| pH | 1-2 |
| 용해도 | 불용성 |
| Merck | 14,8302 |
| 안정성 | 안정적인. 아연과 호환되지 않습니다. 습기로부터 보호하십시오. |
| 주요 응용 | PEM 연료 전지균일 촉매재료 합성 전구체 |
| InChI | InChI=1S/3ClH.Ru/h3*1H/q+3/p-3 |
| InChIKey | YBCAZPLXEGKKFM-UHFFFAOYSA-K |
| SMILES | [Ru](Cl)(Cl)Cl |
| EPA | Ruthenium chloride (RuCl3) (10049-08-8) |
안전 및 규제
| GHS 분류 | DangerH290 (18.5%): May be corrosive to metals [Warning Corrosive to Metals]P234, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 205 reports by companies from 18 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 규제 정보 | Chemical: Ruthenium chloride (RuCl3)Ruthenium chloride (RuCl3): Does not have an individual approval but may be used under an appropriate group standardRuthenium (III) chloride: Does not have an individual approval but may be used under an appropriate group standard |
| 기타 안전 정보 | IMAP assessments - Ruthenium chloride (RuCl3): Human health tier I assessment |
| 유해성 요약 | Intraperitoneal LD50 (rat) = 360 mg/kg[RTECS] Causes burnsInhalation may cause corrosive injuries to upper respiratory tract and lungs[Alfa Aesar MSDS] |
| Hazard Classes and Categories | Met. Corr. 1 (18.5%) |
| Protective Action Criteria (PAC) | 2.2 [mg/m3]24 [mg/m3]140 [mg/m3] |
| 유해 작용 | Dermatotoxin - Skin burns. |
| 수질 위해 등급(WGK) | 2 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | VM2650000 |
| 운송 번호(UN) | UN 3260 8/PG 2 |
| 관세 코드 | 28439000 |
| 위험 문구(R) | 34-52/53-22 |
| 위험 표시 | C |
| 안전 문구(S) | 26-36/37/39-45-61 |
| 포장분류 | III |
용도
용도
Ruthenium(III) chloride is widely used as a starting material of ruthenium complexes. It acts as a catalyst used in the oxidative cyclization of 1,7-dienes to oxepane diols. It is used in the hydroxylation of tertiary hydrocarbons in combination of periodate or bromate. It is involved as a catalyst in the synthesis of 2,3-pyridinedicarboxylic acid-13C3, 15N, where the unlabelled analog is an inhibitor of glucose synthesis.
제조 및 합성 방법
생산 방법
RuCl3, is made by direct chlorination of the metal at 700 °C (1,292 °F). Two allotropic forms result. The trihydrate is made by evaporating an HCl solution of ruthenium (III) hydroxide to dryness or reducing ruthenium (VIII) oxide in a HCl solution.