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칼륨 헥사플루오로규산염

Potassium hexafluorosilicate

HCID 61851
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
16871-90-2
표준 SMILES
F[Si-2](F)(F)(F)(F)F.[K+].[K+]
InChIKey
UUHPPUWEDCVPCO-UHFFFAOYSA-N
분자식
F6Si.2K
평균 분자량
220.272 g/mol
단동위원소 질량
219.8947585

개요

Potassium fluorosilicate appears as a white, odorless crystalline powder. Denser than water. Contact may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

이름 및 식별자

우선 이름
Potassium hexafluorosilicate
IUPAC
dipotassium;hexafluorosilicon(2-)
현지명
칼륨 헥사플루오로규산염
영어명
Potassium fluorosilicate
분자식
F6K2Si
분자량
220.27

이름 및 동의어

Potassium hexafluorosilicate16871-90-2Potassium fluosilicatePotassium silicofluorideDipotassium hexafluorosilicate2610W49XYDDipotassium hexafluorosilicate(2-)EINECS 240-896-2UN2655UNII-2610W49XYDSilicate(2-), hexafluoro-, potassium (1:2)DTXSID10884939
이름 더 보기
규불화칼륨불화규소산칼륨실리코플루오린화칼륨(실리코플루오르화칼륨)칼륨헥사플루오로규산염불화규산칼륨포타슘플루오로실리케이트칼륨헥사플루오로규산염포타슘 실리코플루오라이드다이포타슘 헥사플루오로실리케이트다이포타슘 헥사플루오로실리케이트(2-)디포타슘헥사플루오로실리케이트실리코플루오르화 포타슘포타슘 플루오로실리케이트포타슘 플루오로실리케이트 (K2SiF6)포타슘 플루오실리케이트플루오로규산칼륨헥사플루오로규산 포타슘헥사플루오로규산(2-), 다이포타슘헥사플루오로규산(2-), 포타슘 (1:2)헥사플루오로규산칼륨dipotassiumhexafluorosilicate(2-)Potassium fluosilicapotassiumfluosilicate

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
7
회전 가능 결합 수
0
무거운 원자 수
9
형식 전하
0
복잡도
62.7

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Inorganic Compounds
CosmeticsAntiplaque; Oral care
Density · 2건

Relative density (water = 1): 2.3

2.27 @25 °C

SolubilitySolubility in water, g/100ml at 20 °C: 0.18 (poor)
Physical Description · 4건

Potassium fluorosilicate appears as a white, odorless crystalline powder. Denser than water. Contact may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

Dry Powder

White solid; [Merck Index] White powder; [Alfa Aesar MSDS]

WHITE CRYSTALS OR FINE POWDER.

물리화학적 성질

녹는점
°Cd ec.)
끓는 점
dec
밀도
2.665 g/mL · 2.665 g/mL at 25 °C(lit.)
증기압
0.01 Pa · 0.01Pa
굴절률
1.3991 · 1.3991
용해도
insoluble in ethanol
물리적 상태
가루
Specific Gravity
2.665 · 2.665

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

P261, P262, P264, P270, P271, P280, P301+P316, P302+P352, P304+P340, P316, P321, P330, P361+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for 9.2% (11 of 119) of reports.

Danger

H301 (90.8%): Toxic if swallowed [Danger Acute toxicity, oral]

유해성 정보

Regulatory Information · 5건

Chemical: Silicate(2-), hexafluoro-, dipotassium

Silicate(2-), hexafluoro-, potassium (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicate(2-), hexafluoro-, potassium (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Dipotassium hexafluorosilicate (EC: 240-896-2)

Potassium hexafluorosilicate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Hexafluorosilicate salts: Human health tier II assessment
DOT LabelPoison
Fire Hazards · 2건

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

Health HazardsExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Hazards Summary

화학 및 산업

용도 및 제조

Uses · 3건

Used to make opalescent glass, in porcelain enamels, insecticides, and aluminum metallurgy; [Merck Index]

Aluminum Producing [Category: Industry]

Ceramics making [Category: Hobbies]

U.S. Production2023: 407,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesAbrasives
Use ClassificationCosmetics -> Antiplaque; Oral care
General Manufacturing Information · 2건

Not Known or Reasonably Ascertainable

Silicate(2-), hexafluoro-, potassium (1:2): ACTIVE

응용 분야

용도In the manufacture of opalescent glass, in porcelain enamels, in insecticides. Also used in aluminum metallurgy.

일반 설명A white, odorless crystalline powder. Denser than water. Contact may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

상·하류 제품 정보

상류 원료

플루오로규산탄산 칼륨염화칼륨

하류 제품

제일인산칼륨

공급사100 곳

관련 반응

0건
반응 기록 만들기

현재 필터 조건에 해당하는 반응 기록이 없습니다.

화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
Kaliumhexafluorsilikat
potassium flurosilicate
POTASSIUM FLUOROSILICATE
POTASSIUM SILICAFLUORIDE
Potasssium Silicofluoride
POTASSIUM HEXAFLUOROSILICATE [MI]SILICATE, HEXAFLUORO-, DIPOTASSIUMEC 240-896-2RefChem:175487FLUOSILICATE DE POTASSIUMDipotassium hexafluorosilicate(2)FLUOROSILICATE DE POTASSIUMSILICOFLUORURE DE POTASSIUM

데이터베이스 식별자

CAS
16871-90-2
PubChem CID
61851
DTXSID
DTXSID10884939
UNII
2610W49XYD
EC Number
240-896-2
색상
하얀색
냄새
Odorless
수용성
물에 약간 용해됩니다.
Merck
14 · 14,7638
화장품 원료 기능
구강 관리안티플라크
InChI
1S/F6Si.2K/c1-7(2,3,4,5)6;;/q-2;2*+1
InChIKey
UUHPPUWEDCVPCO-UHFFFAOYSA-N
SMILES
[K+].[K+].F[Si--](F)(F)(F)(F)F
LogP
0.001 · 0.001
EPA
Silicate(2-), hexafluoro-, dipotassium (16871-90-2)

화학적 성질

White, odorless, crystalline powder. D 3.0. Slightly soluble in water; soluble in hydrochlo- ric acid.

· 1건

Causes flaccid paralysis, ataxia, and muscle contraction in oral lethal-dose studies of mice and rats; [RTECS] Hydrolyzed by hot water producing potassium fluoride, hydrogen fluoride, and silicic acid; A severe irritant; [Merck Index] A skin, eye, and respiratory tract irritant; May have effects on calcium metabolism; Chronic exposure may cause fluorosis; [ICSC] Forms hydrofluoric acid when dissolved in water; An irritant; Toxic by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS] See Sodium hexafluorosilicate.

Reactive GroupSalts, Basic
EC ClassificationSymbol: T; R: 23/24/25; S: (1/2)-26-45; Note: A
UN ClassificationUN Hazard Class: 6.1; UN Pack Group: III
Reactivity Profile · 1건

Solutions of potassium fluorosilicate may contain some hydrofluoric acid, which can cause severe chemical burns and is one of the few materials that can etch glass. Unlike other halide ions, fluoride is quite reactive, acting as a weak base and participating in some unique reactions. In particular, fluorides react strongly with compounds containing calcium, magnesium, or silicon ions, which means that solutions containing soluble fluorides are corrosive to both living tissue and glass.

Chemical DangersDecomposes on heating. This produces toxic and corrosive fumes including fluorine. Reacts with acids. This produces corrosive hydrogen fluoride (see ICSC 0283).
Packaging and LabellingDo not transport with food and feedstuffs.

안전 및 보호

Fire Fighting · 2건

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

In case of fire in the surroundings, use appropriate extinguishing media.

First Aid Measures · 4건

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.

First AidExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Safe StorageSeparated from acids and food and feedstuffs.
Exposure Control and Personal Protection · 2건

Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Spillage Disposal · 1건

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.

Isolation and EvacuationExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Eye PreventionWear safety goggles or eye protection in combination with breathing protection if powder.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed.
Skin PreventionProtective gloves. Protective clothing.
Exposure PreventionPREVENT DISPERSION OF DUST!

독성 정보

Exposure RoutesThe substance can be absorbed into the body by ingestion.
Signs and Symptoms · 4건

Burning sensation. Cough. Sore throat. See Ingestion.

Redness. Pain.

Redness. Pain. Blurred vision.

Abdominal cramps. Burning sensation. Nausea. Vomiting. Weakness. Convulsions. Shock or collapse.

안전 데이터

wgk
2
tsca
TSCA listed
rtecs
VV8400000
ridadr
UN 2655
HS 번호
2826908090
risk_code
23/24/25
hazard_code
T,Xi
safety_code
26-45
포장분류
III
위험 등급
6.1
기존화학 물질
KE-12160
F 고인화성물질
21
위험 참고 사항
Irritant
Hazard Classifications
Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 3 Oral
스토리지 클래스
6.1D - Non-combustible acute toxic Cat.3toxic hazardous materials or hazardous materials causing chronic effects
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 플루오로규산과 그 염류 및 그 중 하나를 1% 이상 함유한 혼합물
유해화학물질 필터링
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