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헥사불화규산 마그네슘

Magnesium hexafluorosilicate

HCID 61861
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
16949-65-8
표준 SMILES
F[Si-2](F)(F)(F)(F)F.[Mg+2]
InChIKey
INWUJAAIUAAHJA-UHFFFAOYSA-N
분자식
F6Si.Mg
평균 분자량
166.38 g/mol
단동위원소 질량
165.95238755

개요

Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

이름 및 식별자

우선 이름
Magnesium hexafluorosilicate
IUPAC
magnesium hexafluorosilicon(2-)
현지명
헥사불화규산 마그네슘
영어명
Magnesium fluosilicate
분자식
F6MgSi
분자량
166.38

이름 및 동의어

Magnesium hexafluorosilicateMagnesium fluorosilicateCaswell No. 532Fluosilicate de magnesiumHexafluorosilicate(2-) magnesium (1:1)Silicate(2-), hexafluoro-, magnesium (1:1)EPA Pesticide Chemical Code 075304Fluosilicate de magnesium [French]EINECS 241-022-2UN2853UNII-H37V80D2JSMagnesium hexafluorosilicate(2)
이름 더 보기
마그네슘헥사플루오로규산염헥사불화규산마그네슘규불화마그네슘마그네슘플루오로실리케이트마그네슘헥사플루오로규산염(MAGNESIUMHEXAFLUOROSILICATE)마그네슘 플루오로실리케이트마그네슘 플루오규산마그네슘 헥사플루오로규산 (MgSiF6)마그네슘 헥사플루오로실리케이트(2-)실리케이트(2-), 헥사플루오로-, 마그네슘실리코플루오르화 마그네슘실리코플루오르화 마그네슘 (MgSiF6)플루오로규산 마그네슘플루오실리크산, 마그네슘 염헥사플루오로규소산 (2-) 마그네슘 (1:1)Magnesium fluorosiliMAGNESIUM FLUOSILICATEMAGNESIUM SILICOFLUORIDEMagnesiumhexafluorsilikatMAGNESIUMHEXAFLUOSILICATEfluosilicicacidmagnesiumsaltMAGNESIUM SILICOFLUORIDE 98%
FLUOROSILICATO DE MAGNESIODTXSID70884950hexafluorosilicate, magnesium saltMAGNESIUM HEXAFLUOROSILICATE [MI]MAGNESIUM SILICOFLUORIDE, (SOLID)EC 241-022-2MAGNESIUM SILICOFLUORIDE, [SOLID]RefChem:155211

데이터베이스 식별자

CAS
16949-65-8、18972-56-0
PubChem CID
61861
DTXSID
DTXSID70884950
UNII
H37V80D2JS
EC Number
241-022-2、606-187-0

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
7
회전 가능 결합 수
0
무거운 원자 수
8
형식 전하
0
복잡도
62.7

실험 및 물리화학적 성질

Chemical ClassesMineral Dusts -> Other Mineral Dusts
CosmeticsAntiplaque; Oral care
Physical Description · 3건

Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

Dry Powder

Solid; [CAMEO] White powder; [Gelest MSDS]

물리화학적 성질

녹는점
120 °C · 120°C
끓는 점
120 °C · >120°C
밀도
1.788 · 1.788
증기압
0.001 Pa · 0.001Pa at 25℃
물리적 상태
가루
Specific Gravity
1.788 · 1.788
수용성
498.4 g/L · 498.4g/L at 18.3℃
화장품 원료 기능
안티플라크구강 관리
InChI
InChI=1S/F6Si.Mg.6H2O/c1-7(2,3,4,5)6;;;;;;;/h;;6*1H2/q-2;+2;;;;;;
InChIKey
ZYDDCPHMRLLEEV-UHFFFAOYSA-N
SMILES
[Si-2](F)(F)(F)(F)(F)F.O.O.O.O.O.O.[Mg+2]

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

P264, P270, P301+P316, P321, P330, P405, and P501 (click each P-code to see the statement)

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P316, P304+P340, P305+P354+P338, P317, P321, P330, P405, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 5건

Chemical: Silicate(2-), hexafluoro-, magnesium (1:1)

Silicate(2-), hexafluoro-, magnesium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicate(2-), hexafluoro-, magnesium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Magnesium hexafluorosilicate (EC: 241-022-2)

Magnesium hexafluorosilicate: Does not have an individual approval but may be used under an appropriate group standard

Magnesium fluorosilicate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Magnesium hexafluorosilicates: Human health tier II assessment
DOT LabelPoison
Fire Hazards · 2건

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards · 2건

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.

화학 및 산업

용도 및 제조

Uses · 2건

Used for mothproofing textiles; [Merck Index] Used to make other chemicals; [CAMEO]

Textiles (Printing, Dyeing, or Finishing) [Category: Industry]

U.S. Production2023: 88,184 lb
Consumer UsesBinder
Industry UsesBinder
Use ClassificationCosmetics -> Antiplaque; Oral care
General Manufacturing Information · 2건

Non-metallic Mineral Product Manufacturing (includes clay, glass, cement, concrete, lime, gypsum, and other non-metallic mineral product manufacturing)

Silicate(2-), hexafluoro-, magnesium (1:1): ACTIVE

응용 분야

일반 설명Crystalline solid. Decomposes at 120°C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

상·하류 제품 정보

상류 원료

수산화마그네슘Magnesite플루오로규산불산산화마그네슘해사

관련 반응

0건
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화합물 노트

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LogP
0 at · 0 at 25℃
EPA
Magnesium fluosilicate (16949-65-8)
Hazards Summary · 1건

Toxic by ingestion; May cause serious eye injury [Classifications by the EC] Not a skin irritant in rabbits (80% aqueous solution); Hematological and clinical chemistry changes, adverse dental effects, mineralization in bone tissue, interstitial nephritis, hyperkeratosis of the stomach, increased relative liver and kidney weights, and increased relative testes and adrenal weights in males observed in 4-week oral study of rats at 3,000 ppm dietary (approximately 300 mg/kg/day); [IUCLID] An eye irritant; Corrosive to mucous membranes; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause osteofluorosis; [Gelest MSDS] See Magnesium. See Fluorosilicic acid. See Calcium hexafluorosilicate.

DOT ID and Guide2853 151
Reactive GroupSalts, Basic
Reactivity Profile · 1건

MAGNESIUM FLUOROSILICATE gives basic aqueous solutions. Reacts with acids. Does not usually react as either oxidizing agents or reducing agents. It can react slowly with water to generate hydrofluoric acid, which can cause severe chemical burns and is one of the few materials that can etch glass.

DOT Hazard Classification · 4건

Magnesium fluorosilicate

UN2853

Div 6.1 Poisonous materials (49 eCFR § 173.132)

PG III: the degree of danger presented by the material is minor

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 5건

Acute Tox. 3 (100%)

Acute toxicity (ingestion) - category 3

Acute toxicity (Oral) - Category 3

Acute toxicity (Oral) - Category 3

Acute Tox. 3 *

안전 및 보호

Fire FightingExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

First Aid · 2건

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

General First Aid:

Exposure Control and Personal Protection · 3건

· Wear positive pressure self-contained breathing apparatus (SCBA).

Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Isolation and Evacuation · 2건

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

Immediate precautionary measure

Threshold Limit Values (TLV)2.5 [mg/m3], as F
Permissible Exposure Limit (PEL)2.5 [mg/m3], as F
Personal Protective Equipment (PPE)Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Emergency Response Planning GuidelinesSmall Fire
Immediately Dangerous to Life or Health (IDLH)250.0 [mg/m3], as F

독성 정보

Adverse EffectsDermatotoxin - Skin burns.
Toxicity DataLC50 (rat) = 3,600 mg/m3/4hr

안전 데이터

tsca
TSCA listed
ridadr
UN 2853
독성
LD in guinea pigs (mg/kg): 200 orally, 400 s.c. (Waldbott)
risk_code
25
hazard_code
T
safety_code
24/25-45
포장분류
III
위험 등급
6.1
기존화학 물질
KE-22747
함량 및 규제정보
물질구분: 유독물질; 혼합물(제품)함량정보: 플루오로규산과 그 염류 및 그 중 하나를 1% 이상 함유한 혼합물
유해화학물질 필터링
97-1-376