기본 정보
- 표준 SMILES
CCO[Si](C)(C)OCC- InChIKey
YYLGKUPAFFKGRQ-UHFFFAOYSA-N- 분자식
- C6H16O2Si
- 평균 분자량
- 148.28 g/mol
- 단동위원소 질량
- 148.09195628
개요
Dimethyldiethoxysilane appears as a colorless liquid. Less dense than water and insoluble in water. Vapors heavier than air.
이름 및 식별자
- 우선 이름
- Diethoxydimethylsilane
- IUPAC
- diethoxy(dimethyl)silane
- 현지명
- 다이에톡시다이메틸실레인
- 영어명
- Diethoxydimethylsilane
- 분자식
- C6H16O2Si
- 분자량
- 148.28
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
78-62-6- PubChem CID
- 62322
- DTXSID
DTXSID6052538- ChEMBL
CHEMBL3561087- UNII
- I3931J3ZJ2
- EC Number
- 201-127-6
- Nikkaji
- J36.477K
물성
구조 계산 물성
- 극성 표면적
- 18.5 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 2
- 회전 가능 결합 수
- 4
- 무거운 원자 수
- 9
- 형식 전하
- 0
- 복잡도
- 65.5
실험 및 물리화학적 성질
Physical Description
Dimethyldiethoxysilane appears as a colorless liquid. Less dense than water and insoluble in water. Vapors heavier than air.
Liquid
물리화학적 성질
- 녹는점
- -97 °C · -97°C
- 끓는 점
- 114 °C · 114 °C (lit.)
- 밀도
- 0.865 g/mL · 0.865 g/mL at 25 °C (lit.)
- 증기압
- 7 · 7-7910Pa at 20-25℃
- 굴절률
- 20 · n20/D 1.381(lit.)
- 인화점
- 53 °F · 53 °F
- 저장 조건
- Flammables area
- 물리적 상태
- 액체
- Specific Gravity
- 0.939 · 0.939
- 색상
- 25 · 25(APHA)
- 수용성
- 분해될 수 있음
- BRN
- 1736110 · 1736110
- Dielectric constant
- 3.22 · 3.2200000000000002
- InChI
- 1S/C6H16O2Si/c1-5-7-9(3,4)8-6-2/h5-6H2,1-4H3
- InChIKey
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N
- SMILES
- CCO[Si](C)(C)OCC
- LogP
- -0.4 · -0.4-3 at 25℃
- NIST
- Silane, diethoxydimethyl-(78-62-6)
- EPA
- Silane, diethoxydimethyl- (78-62-6)
화학적 성질
Colorless clear liquid
안전 및 규제
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 2% (5 of 245) of reports.
Danger
H225 (98%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 245 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
유해성 정보
Regulatory Information
Chemical: Silane, diethoxydimethyl-
Silane, diethoxydimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silane, diethoxydimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 23-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/24954
Diethoxydimethylsilane: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
Fire Hazards
Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Health Hazards
Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
· Inhalation or contact with material may irritate or burn skin and eyes.
Reactivity Profile
These substances undergo chemical reactions only under relatively severe circumstances or in the presence of an effective catalyst that promotes reaction. They are resistant to ignition, although they may become flammable at very high temperatures. They will be resistant to oxidation/reduction, except in the most severe conditions. These materials may be nontoxic.
DOT Hazard Classification
Dimethyldiethoxysilane
UN2380
Class 3 Flammable and combustible liquid (49 eCFR § 173.120)
PG II: the degree of danger presented by the material is medium
Hazard Classes and Categories
Flam. Liq. 2 (98%)
Flammable liquids - Category 2
Flammable agents - 3rd degree
안전 및 보호
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
General First Aid:
Isolation and Evacuation
Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Immediate precautionary measure
Protective Action Criteria (PAC)
17 [mg/m3]
190 [mg/m3]
1100 [mg/m3]
안전 데이터
- wgk
- 2
- tsca
- TSCA listed
- rtecs
- VV3590000
- ridadr
- UN 2380
- 독성
- LD50 oral in rat: 9280mg/kg
- HS 번호
- 29319090
- risk_code
- 11-36/38-20
- hazard_code
- F,Xi,Xn
- safety_code
- 26-36-16
- 포장분류
- II
- 위험 등급
- 3
- 기존화학 물질
- 2005-3-3180
- Hazard Classifications
- Flam. Liq. 2Repr. 2
- 스토리지 클래스
- 3 - Flammable liquids
화학 및 산업
용도 및 제조
General Manufacturing Information
All Other Basic Inorganic Chemical Manufacturing
Silane, diethoxydimethyl-: ACTIVE
응용 분야
용도Diethoxydimethylsilane may be used to modify epoxy resin6 and the surfaces of pure silica and Pd/SiO2 hydrogen gas sensors. Surface modification results in enhanced gas sensing properties of the sensors. It may be used as a precursor for the synthesis of ultrafine SiC powder. Diethoxydimethylsilane is an intermediate silane useful for blocking hydroxyl and amino groups in organic synthesis reactions. This silylating step allows subsequent reactions to be carried out which would be adversely affected by the presence of active hydrogen in the hydroxyl or amine groups. Following the reaction step, hydroxyl or amine groups blocked with diethoxydimethylsilane may be recovered by a hydrolysis procedure. It is also used for preparing hydrophobic and release materials as well as enhancing flow of powders. Studies report its use as a precursor for ORMOSIL (Organically modified SILicates) and thin a-SiOxCyHz films.
일반 설명A colorless liquid. Flash point 75°F. Less dense than water and insoluble in water. Vapors heavier than air.
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