다이에톡시다이메틸실레인

Diethoxydimethylsilane

HCID 62322CAS 78-62-6

기본 정보

표준 SMILES
CCO[Si](C)(C)OCC
InChIKey
YYLGKUPAFFKGRQ-UHFFFAOYSA-N
분자식
C6H16O2Si
평균 분자량
148.28 g/mol
단동위원소 질량
148.09195628

개요

Dimethyldiethoxysilane appears as a colorless liquid. Less dense than water and insoluble in water. Vapors heavier than air.

이름 및 식별자

우선 이름
Diethoxydimethylsilane
IUPAC
diethoxy(dimethyl)silane
현지명
다이에톡시다이메틸실레인
영어명
Diethoxydimethylsilane
분자식
C6H16O2Si
분자량
148.28

이름 및 동의어

DiethoxydimethylsilaneDimethyldiethoxysilaneDiethoxy(dimethyl)silaneSilane, diethoxydimethyl-Dimethyl-diethoxysilanDimethyl-diethoxysilan [Czech]CCRIS 1321dimethyl diethoxy silaneDTXSID6052538EINECS 201-127-6NSC 77085UNII-I3931J3ZJ2
이름 더 보기
다이메틸디에톡시실란다이에톡시다이메틸실레인DMDESdirthoxydimethylsilanekbe22DiethoxydimethyLDimethyldisilanolDiethoxydimethylsi
BRN 1736110I3931J3ZJ2NSC-77085EXP-49SILANE,DIETHOXY,DIMETHYLDTXCID70311114-04-00-04101 (Beilstein Handbook Reference)CD5600

데이터베이스 식별자

CAS
78-62-6
PubChem CID
62322
DTXSID
DTXSID6052538
ChEMBL
CHEMBL3561087
UNII
I3931J3ZJ2
EC Number
201-127-6
Nikkaji
J36.477K

물성

구조 계산 물성

극성 표면적
18.5 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
4
무거운 원자 수
9

실험 및 물리화학적 성질

Chemical ClassesFlammable agents - 3rd degree
SpringerMaterials Properties29Si nuclear magnetic resonance spectrum
Density0.86 @25 °C
Boiling Point114 °C @760 [mm Hg]
Vapor Pressure10 [mm Hg] @13.3 °C
Physical Description · 2건

Dimethyldiethoxysilane appears as a colorless liquid. Less dense than water and insoluble in water. Vapors heavier than air.

Liquid

물리화학적 성질

녹는점
-97 °C · -97°C
끓는 점
114 °C · 114 °C (lit.)
밀도
0.865 g/mL · 0.865 g/mL at 25 °C (lit.)
증기압
7 · 7-7910Pa at 20-25℃
굴절률
20 · n20/D 1.381(lit.)
인화점
53 °F · 53 °F

화학적 성질

Colorless clear liquid

안전 및 규제

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 2% (5 of 245) of reports.

Danger

H225 (98%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 245 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

유해성 정보

Regulatory Information · 5건

Chemical: Silane, diethoxydimethyl-

Silane, diethoxydimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silane, diethoxydimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 23-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/24954

Diethoxydimethylsilane: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Liquid
Fire Hazards · 2건

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Health Hazards · 2건

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

· Inhalation or contact with material may irritate or burn skin and eyes.

DOT ID and Guide2380 127
Reactive GroupSiloxanes

안전 및 보호

Fire FightingExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2건

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Isolation and Evacuation · 2건

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

Immediate precautionary measure

안전 데이터

wgk
2
tsca
TSCA listed
rtecs
VV3590000
ridadr
UN 2380
독성
LD50 oral in rat: 9280mg/kg
HS 번호
29319090

화학 및 산업

용도 및 제조

U.S. Production2023: 550,000 - <1,000,000 lb
Industry UsesIntermediate
General Manufacturing Information · 2건

All Other Basic Inorganic Chemical Manufacturing

Silane, diethoxydimethyl-: ACTIVE

응용 분야 · 2건

용도Diethoxydimethylsilane may be used to modify epoxy resin6 and the surfaces of pure silica and Pd/SiO2 hydrogen gas sensors. Surface modification results in enhanced gas sensing properties of the sensors. It may be used as a precursor for the synthesis of ultrafine SiC powder. Diethoxydimethylsilane is an intermediate silane useful for blocking hydroxyl and amino groups in organic synthesis reactions. This silylating step allows subsequent reactions to be carried out which would be adversely affected by the presence of active hydrogen in the hydroxyl or amine groups. Following the reaction step, hydroxyl or amine groups blocked with diethoxydimethylsilane may be recovered by a hydrolysis procedure. It is also used for preparing hydrophobic and release materials as well as enhancing flow of powders. Studies report its use as a precursor for ORMOSIL (Organically modified SILicates) and thin a-SiOxCyHz films.

일반 설명A colorless liquid. Flash point 75°F. Less dense than water and insoluble in water. Vapors heavier than air.

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北科孚乐材料科技有限公司027-84459282 13720265353 · [email protected]
南通润丰石油化工有限公司66017690 19952660367 · [email protected]

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