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단사

Cinnabar

HCID 62402
노트반응
기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
부분 구조 검색유사 구조 찾기

기본 정보

CAS
1344-48-5
표준 SMILES
[S]=[Hg]
InChIKey
QXKXDIKCIPXUPL-UHFFFAOYSA-N
분자식
HgS
평균 분자량
232.66 g/mol
단동위원소 질량
233.942714

개요

Cinnabar is a mineral with formula of HgS. The IMA symbol is Cin.

이름 및 식별자

우선 이름
Cinnabar
IUPAC
sulfanylidenemercury
현지명
단사
영어명
cinnabar
분자식
HgS
분자량
232.67

이름 및 동의어

CinnabarZinnoberCinabreRefChem:918654Mercury(II) sulfide1344-48-5SulfanylidenemercuryMercury sulfide (HgS)Cinnabarite19122-79-3Mercuric Sulfide RedAlmaden
이름 더 보기
단사ParagiteMercurius 6aCinnabar (hgs)Mercury ores, cinnabar
Ethiops mineralRed cinnabarOrange vermilionChinese vermilionScarlet vermilionVermilion (HgS)Mercury monosulfideMonomercury sulfide

데이터베이스 식별자

CAS
1344-48-5、19122-79-3、23333-45-1
PubChem CID
62402
DTXSID
DTXSID301318265
EC Number
215-696-3
Nikkaji
J43.911H

물성

구조 계산 물성

극성 표면적
32.1 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
1
회전 가능 결합 수
0
무거운 원자 수
2
형식 전하
0
복잡도
2

실험 및 물리화학적 성질

Chemical ClassesMetals -> Mercury Compounds, Inorganic
SpringerMaterials Propertiesphonon wavenumber
Physical Description · 2건

Dry Powder

Black or red solid; [2 entries in Merck Index] Mercuric sulfide, black is insoluble; Mercuric sulfide, red is soluble in aqua regia (separation of S) and hydriodic acid (H2S formation); [ATSDR ToxProfiles]

물리화학적 성질

녹는점
850 °C · 850 °C (sublm)

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

This chemical does not meet GHS hazard criteria for 1.5% (1 of 66) of reports.

Warning

H317 (59.1%): May cause an allergic skin reaction [Warning Sensitization, Skin]

P261, P272, P273, P280, P302+P352, P321, P333+P317, P362+P364, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 66 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

유해성 정보

Regulatory Information · 4건

Chemical: Mercury sulfide (HgS)

Mercury sulfide (HgS) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Mercury sulfide (HgS) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

12C - indicates a substance that is prohibited to be exported from the Unites States under TSCA section 12(c).

Mercury sulphide: HSNO Approval: HSR007214 Approved with controls

Hazards SummaryHighly toxic after ingestion, inhalation, or skin absorption; [Hawley] See Mercury, inorganic compounds and the linked occupational disease.
Hazard Classes and Categories · 2건

Skin Sens. 1 (59.1%)

Skin sensitization - Category 1A

안전 및 보호

Exposure Control and Personal Protection0.02 [mg/m3], as Hg, inhalable fraction[German Research Foundation (DFG)]
Minimum Risk LevelChronic Inhalation: 0.0002 mg/m3 (L134)

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Mercury is absorbed mainly via ingestion and inhalation, then distributed throughout the body via the bloodstream, where a portion binds to sulfhydryl groups on haemoglobin. Mercury can undergo oxidation to mercuric mercury, which takes place via the catalase-hydrogen peroxide pathway. The mercury atom is able to diffuse down the cleft in the catalase enzyme to reach the active site where the heme ring is located. Oxidation most likely occurs in all tissue, as the catalase hydrogen peroxide pathway is ubiquitous. Following oxidation, mercury tends to accumulate in the kidneys. Mercury is excreted mainly by exhalation and in the faeces. (A6, L7)

용도 및 제조

Uses · 3건

Red form used to color plastics, sealing wax, marking linen, manufacturing of fancy colored paper, and as antibacterial; Black form used as pigment for rubber, etc. [Merck Index]

Pulp and Paper Processing [Category: Industry]

Mercury(II) sulfide is used as a semiconductor and as a red pigment, vermillion. (L426)

U.S. Production2023: 108,675 lb
Consumer UsesOther
Industry UsesOther
General Manufacturing Information · 2건

All Other Basic Inorganic Chemical Manufacturing

Mercury sulfide (HgS): ACTIVE

공급사1 곳

WATERSTONE[email protected]

관련 반응

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화합물 노트

불러오는 중…

이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
Threshold Limit Values (TLV)0.02 [mg/m3], as Hg
Permissible Exposure Limit (PEL)0.1 [mg/m3], as Hg
Immediately Dangerous to Life or Health (IDLH)10.0 [mg/m3], as Hg

독성 정보

TreatmentMercury poisoning is treated by immediate decontamination and chelation therapy using DMSA, DMPS, DPCN, or dimercaprol. (A7)
Health Effects · 1건

Mercury mainly affects the nervous system. Exposure to high levels of metallic, inorganic, or organic mercury can permanently damage the brain, kidneys, and developing fetus. Effects on brain functioning may result in irritability, shyness, tremors, changes in vision or hearing, and memory problems. Acrodynia, a type of mercury poisoning in children, is characterized by pain and pink discoloration of the hands and feet. Mercury poisoning can also cause Hunter-Russell syndrome and Minamata disease. (L7)

Adverse EffectsNeurotoxin - Sensorimotor
Exposure RoutesOral (L136) ; inhalation (L136); dermal (L136)
Toxicity Summary · 1건

High-affinity binding of the divalent mercuric ion to thiol or sulfhydryl groups of proteins is believed to be the major mechanism for the activity of mercury. Through alterations in intracellular thiol status, mercury can promote oxidative stress, lipid peroxidation, mitochondrial dysfunction, and changes in heme metabolism. Mercury is known to bind to microsomal and mitochondrial enzymes, resulting in cell injury and death. For example, mercury is known to inhibit aquaporins, halting water flow across the cell membrane. It also inhibits the protein LCK, which causes decreased T-cell signalling and immune system depression. Mercury is also believed to inhibit neuronal excitability by acting on the postsynaptic neuronal membrane. It also affects the nervous system by inhibiting protein kinase C and alkaline phosphatase, which impairs brain microvascular formation and function, as well as alters the blood-brain barrier. Mercury also produces an autoimmune response, likely by modification of major histocompatibility complex (MHC) class II molecules, self peptides, T-cell receptors, or cell-surface adhesion molecules. (L7, A8, A25, A26)

Signs and SymptomsCommon symptoms include peripheral neuropathy (presenting as paresthesia or itching, burning or pain), skin discoloration (pink cheeks, fingertips and toes), edema (swelling), and desquamation (dead skin peels off in layers). (A5)
Carcinogen Classification3, not classifiable as to its carcinogenicity to humans. (L135)