TITANIUM CHLORIDE (TiCl3) (HCID 62646)

이름 및 식별자

우선 이름: TITANIUM CHLORIDE (TiCl3)
IUPAC: trichlorotitanium
현지명: 티타늄 트리염화물
영어명: Titanous chloride
분자식: TiCl3
분자량: 154.22

이름 및 동의어

TITANIUM TRICHLORIDETrichlorotitanium7705-07-9Titanium chloride (TiCl3)TiCl3TAC 121TAC 131Lynx 900GVD566MM7KTEN 12TGY 24TOS 17

이름 더 보기

삼염화티타늄티타늄트리염화물삼염화티타늄삼염화 타이타늄티타늄(III)염화물TITANIUM(III) CHLORIDETitanium (III) chloride (solid)Titanium(iii) chloride, 20% w/w solution in 2n hydrochloric acidtac121tac131

RefChem:190167TAC 140TAC 144TAS 101231-728-9LYNX-900TAC-121TAS-101

데이터베이스 식별자

CAS: 7705-07-9
PubChem CID: 62646
DTXSID: DTXSID1052870
EC Number: 231-728-9

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 0
무거운 원자 수: 4
형식 전하: 0
복잡도: 8

실험 및 물리화학적 성질

Chemical Classes · 2건

Metals -> Metals, Inorganic Compounds

Flammable agents - 3rd degree

SpringerMaterials Propertiescrystal structure

Density1.772 @25 °C

Boiling Point136.4 °C @760 [mm Hg]

Melting Point-30 °C

Vapor Pressure10 [mm Hg] @21.3 °C

물리화학적 성질

녹는점: 440 °C · 440 °C (dec.)(lit.)
끓는 점: 100 °C · 100 °C
밀도: 1.192 g/mL · 1.192 g/mL at 25 °C
용해도: 2 O · reacts with H2O
물리적 상태: 가루
색상: 보라
수용성: 녹는
비열: 0.63 J/ · Cp(crystal): 0.63 J/(g·K), at 25℃
Merck: 14 · 14,9481
안정성: 안정적이지만 물과 격렬하게 반응하고 공기 중에서 자연적으로 가연성이 있습니다.
InChI: InChI=1S/2ClH.Ti/h2*1H;/q;;+2/p-2
InChIKey: ZWYDDDAMNQQZHD-UHFFFAOYSA-L
SMILES: Cl[Ti](Cl)Cl
NIST: Titanium(iii) chloride(7705-07-9)
EPA: Titanium chloride (TiCl3) (7705-07-9)

화학적 성질

purple crystalline solid

안전 및 규제

GHS 분류

GHS Classification · 6건

Danger

H250 (96.6%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

P210, P222, P231, P233, P260, P261, P264, P264+P265, P271, P272, P280, P284, P301+P330+P331, P302+P335+P334, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P333+P317, P362+P364, P363, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 236 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H250: Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

유해성 정보

Regulatory Information · 4건

Chemical: Titanium chloride (TiCl3)

REACH registered substance: Titanium trichloride (EC: 231-728-9)

Titanium (III) chloride: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Fire Hazards· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

Hazards Summary · 1건

Unstable and highly reactive; Powder is pyrophoric; Dissociates rapidly from moisture in air; A powerful reducing agent; [Merck Index] A strong reducing agent; Decomposed by moisture evolving hydrochloric acid; Dry powder is pyrophoric; Corrosive to skin and mucous membranes; [CAMEO] Pyrophoric; Reacts violently with water evolving hydrogen chloride gas; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract; [Sigma-Aldrich MSDS]

DOT ID and Guide2869 157

DOT Hazard Classification · 5건

Titanium trichloride, pyrophoric or Titanium trichloride mixtures, pyrophoric

UN2441

Div 4.2 Spontaneously combustible material (49 eCFR § 173.124)

PG I: the degree of danger presented by the material is great

안전 및 보호

Accidental Release Measures · 2건

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First AidGeneral First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).

Isolation and EvacuationImmediate precautionary measure

Protective Action Criteria (PAC) · 3건

1.2 [mg/m3]

13 [mg/m3]

79 [mg/m3]

Emergency Response Planning Guidelines· Note: Some foams will react with the material and release corrosive/toxic gases.

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

안전 데이터

wgk: 3
tsca: TSCA listed
rtecs: XR1924000
ridadr: UN 2441
HS 번호: 28273990
risk_code: 34-37-35-17-14
hazard_code: C,F
safety_code: 6-26-30-36/37/39-43-45
포장분류: I
위험 등급: 4.2
기존화학 물질: KE-33927
F 고인화성물질: 10-23
Hazard Classifications: Eye Dam. 1Met. Corr. 1Skin Corr. 1BSTOT SE 3
스토리지 클래스: 8B - Non-combustible corrosive hazardous materials

화학 및 산업

용도 및 제조

UsesUsed as a reducing agent (nitrate to ammonia), laundry stain remover, and analytical reagent; [Merck Index]

General Manufacturing InformationTitanium chloride (TiCl3): ACTIVE

응용 분야 · 2건

용도As powerful reducing agent, Titanous chlorideb can reduces nitrate to ammonia; when boiled with aqueous SO2, sulfur is separated; hence is used as an aqueous solution for estimation of nitro groups, ferric ions, per-salts, etc. Removes stains, etc. (stripper) in laundering.

일반 설명A dark violet crystalline solid. Denser than water. Contact may burn skin, eyes, and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.

제조 방법

Titanium trichloride may be prepared by reducing titanium tetrachloride with hydrogen at 600°C. The tetrachloride may alternatively be reduced with aluminum, zinc, magnesium, tin, or by electrolysis.