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황산제일철7수화물

Ferrous sulfate heptahydrate

HCID 62662
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
15491-23-3
표준 SMILES
O.O.O.O.O.O.O.O=S(=O)([O-])[O-].[Fe+2]
InChIKey
SURQXAFEQWPFPV-UHFFFAOYSA-L
분자식
FeH14O11S
평균 분자량
278.02 g/mol
단동위원소 질량
277.96061977

개요

Iron(2+) sulfate heptahydrate is a hydrate that is the heptahydrate form of iron(2+) sulfate. It is used as a source of iron in the treatment of iron-deficiency anaemia (generally in liquid-dosage treatments; for solid-dosage treatments, the monohydrate is normally used). It has a role as a nutraceutical, a reducing agent and an anti-anaemic agent. It is an iron molecular entity and a hydrate. It contains an iron(2+) sulfate (anhydrous).

이름 및 식별자

우선 이름
Ferrous sulfate heptahydrate
IUPAC
iron(2+);sulfate;heptahydrate
현지명
황산제일철7수화물
영어명
Ferrous sulfate heptahydrate
분자식
FeH14O11S
분자량
278.01

이름 및 동의어

7782-63-0Iron(II) sulfate heptahydrateFERROUS SULFATE HEPTAHYDRATEIron(2+) sulfate heptahydrateIron sulfate heptahydrateMelanterite mineralFesotymeIrosulSiderotil mineralTauriscite mineralSzomolnikite mineralFerrous sulfate, heptahydrate
이름 더 보기
황산,철(2+)염(1:1),헵타수화물(SULFURICACID,IRON그린비트리올녹반철(2+)황산염헵타수화물철(II)황산염(1:1),헵타수화물(IRON코퍼라스황산제1철철(II)황산염황산제1철헵타수화물황산제1철,칠수화물황산철황산제일철황산제일철7수화물황산철(Ⅱ)황산제일철칠수화물황산철(Ⅱ)칠수화물황산제1철,칠수화물(FERROUSSULFATE,HEPTAHYDRATE)황산제1철7수화물페러스설페이트FERROINsulfate heptahydrateFERROIN INDICATOR SOLUTIONIron(Ⅱ) sulfate heptahydrateFERROIN INDICATORFerrous sulfate hept

물성

구조 계산 물성

극성 표면적
95.6 Ų
수소 결합 공여자 수
7
수소 결합 수용자 수
11
회전 가능 결합 수
0
무거운 원자 수
13
형식 전하
0
복잡도
62.2

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Inorganic Compounds
Density1.895 @25 °C
Physical Description · 2건

CBI

Blue-green odorless solid; Efflorescent in dry air; Soluble in water; [Merck Index] Green crystalline solid; [Alfa Aesar MSDS]

물리화학적 성질

녹는점
64 °C · 64 °C
밀도
1.898 g/mL · 1.898 g/mL at 25 °C (lit.)
증기압
14.6 mm · 14.6 mm Hg ( 25 °C)
저장 조건
15 °C · Store at +15°C to +25°C.
용해도
25.6 g/100mL · 25.6g/100mL(20°C)
물리적 상태
액체
Specific Gravity
1.898 · 1.898
색상
약간 녹색을 띤 파란색
냄새
연한 파란색에서 녹색까지의 크리스탈. 냄새 없음
수소이온지수(pH)
3 · 3.0-4.0 (25℃, 50mg/mL in H2O)
수용성
25.6 g/100mL · 25.6g/100mL(20℃)
Merck
14 · 14,4057
안정성
안정적인. 피해야 할 물질에는 강한 산화제가 포함됩니다. 공기와 습기에 민감합니다.

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 6건

Warning

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P264, P264+P265, P270, P280, P301+P317, P302+P352, P305+P351+P338, P321, P330, P332+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for < 0.1% (2 of 2619) of reports.

Warning

H302 (> 99.9%): Harmful if swallowed [Warning Acute toxicity, oral]

유해성 정보

Regulatory Information · 4건

Chemical: Sulfuric acid, iron(2+) salt (1:1), heptahydrate

Regulation (EC) No 1831/2003 (amended)

Sulfuric acid, iron(2+) salt (1:1), heptahydrate is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, iron(2+) salt (1:1), heptahydrate are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Ferrous sulphate, heptahydrate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Sulfuric acid, iron(2+) salt (1:1), heptahydrate: Human health tier I assessment
Hazards Summary · 1건

A skin, eye, and mucous membrane irritant; May cause gastrointestinal disturbances, shock, cyanosis, coma, and liver damage; [Merck Index] A skin and strong eye irritant; Harmful by ingestion; [Alfa Aesar MSDS] See Ferrous sulfate. See Iron salts, soluble.

Hazard Classes and Categories · 4건

Acute Tox. 4 (> 99.9%)

Acute toxicity - category 4

Acute toxicity (Oral) - Category 4

Acute Tox. 4 *

안전 및 보호

화학 및 산업

용도 및 제조

Uses · 3건

Used in iron electroplating baths, fertilizers, pesticides, radiation dosimeters, writing ink, process engraving, lithography, dyeing leather, etching aluminum, water treatment, brown ring test for nitrates, and food and feed supplements; Also used as a reducing agent, wood preservative, weed killer, polymerization catalyst, plant food, and hematinic; [Merck Index] Formerly registered in the US as a moss killer/fertilizer for lawns; [NPIRS] Used as a nutritional supplement, processing aid, and stabilizer or thickener for foods; [FDA]

Aluminum Producing [Category: Industry]

Lithography printing [Category: Hobbies]

U.S. Production2023: 75,000 - <500,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesSoil amendments (fertilizers)
Household ProductsInformation on 27 consumer products that contain Ferrous sulfate heptahydrate in the following categories is provided:
General Manufacturing InformationPesticide, Fertilizer, and Other Agricultural Chemical Manufacturing
응용 분야 · 3건

개요§184.1315(a) Ferrous sulfate heptahydrate (iron (II) sulfate heptahydrate, FeS04-7H2O) is prepared by the action of sulfuric acid on iron. It occurs as pale, blueish-green crystals or granules. Progressive heating of ferrous sulfate heptahydrate produces ferrous sulfate (dried). Ferrous sulfate (dried) consists primarily of ferrous sulfate monohydrate (CAS No. 17375-41-6) with varying amounts of ferrous sulfate tetrahydrate (CAS No. 20908-72-9) and occurs as a grayish-white to buff-colored powder.

용도Used in quantitative analysis of nitrates .

일반 설명A greenish or yellow-brown crystalline solid. Density 15.0 lb /gal. Melts at 64°C and loses the seven waters of hydration at 90°C. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Used for water or sewage treatment, as a fertilizer ingredient.

관련 반응

91건
반응 기록 만들기
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HRID 53900 반응식
HRID 53900촉매로uspto-grants-1997_04
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HRID 61433 반응식
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HRID 65439 반응식
HRID 65439촉매로uspto-grants-1986_09
HRID 129525 반응식
HRID 129525촉매로uspto-grants-1995_11
HRID 133630 반응식
HRID 133630촉매로uspto-grants-2008_06
1 / 12 페이지

화합물 노트

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이 페이지에서기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
더보기
새 노트새 반응견적 요청하기
ferrous sulfate granular
FerrousSulphateMonohydrate
Iron(II)sulphateheptahydrate,98%
Iron(II) sulfate (1:1), heptahydrateTetucur-SDTXSID9040344CHEBI:75836RefChem:921576DTXCID7020344616-510-7Melanterite

데이터베이스 식별자

CAS
15491-23-3、7782-63-0
PubChem CID
62662
DTXSID
DTXSID9040344
ChEBI
CHEBI:75836
UNII
39R4TAN1VT
EC Number
616-510-7
InChI
1S/Fe.H2O4S.7H2O/c;1-5(2,3)4;;;;;;;/h;(H2,1,2,3,4);7*1H2/q+2;;;;;;;;/p-2
InChIKey
SURQXAFEQWPFPV-UHFFFAOYSA-L
SMILES
[Fe+2].[S](=O)(=O)([O-])[O-].O.O.O.O.O.O.O
LogP
-1.031 · -1.031 (est)
EPA
Ferrous sulfate heptahydrate (7782-63-0)

화학적 성질

light blue or light blue-green solid

Threshold Limit Values (TLV)1.0 [mg/m3], as Fe (soluble iron salts)
Protective Action Criteria (PAC) · 3건

2.5 [mg/m3]

27 [mg/m3]

160 [mg/m3]

독성 정보

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.

안전 데이터

wgk
1
tsca
Yes
rtecs
NO8510000
ridadr
UN3077
독성
LD50 in mice: 65 mg/kg i.v.; 1.52 g/kg orally (Hoppe)
HS 번호
28332950
risk_code
22-36/38
hazard_code
Xn
safety_code
36/37/39-46
위험 등급
9
F 고인화성물질
10-23
Hazard Classifications
Acute Tox. 4 OralEye Irrit. 2Skin Irrit. 2
스토리지 클래스
11 - Combustible Solids

상·하류 제품 정보

상류 원료

Sulfuric acid iron(2+) salt monohydrateIron filingsIronmetal,wire0.075mm(0.003in)diaspectro99.9,metalsbasis금홍석철분ILMENITE황산

하류 제품

Iron Oxide Green메틸6-퀴놀린아세테이트시트로넬롤유산철8-Chloroquinoline6-클로로인돌-2-카르복실산Naphthenate drier6-퀴놀리닐메탄올5-Chloroindoleferrous pyrophosphate for foodPOTASSIUM FERRATE(VI)페로스 푸마레이트산화 철FERROUS GLUCONATE DIHYDRATEFoliar-fertilizer헥사시아노철(II)산칼륨4-Amino-3-fluoropyridineMetatitanic acid페로시안화 제2철제스토덴ethybenzene dehydrogenation catayst NCY4-Fluoroindole아나타제medium temperature Shift catalysts황산 암모늄 제1철망간 설페이트 모노하이드레이트FE2O3 AS BROWN PIGMENT염료 청색 27황혈소다Polyferric sulfate산화제1철-제1철Ferric phosphate페로사이안화칼륨Iron naphthenateIron oxide brownCI 77492산화 철, 황medium(high)temperature Shift catalysts구연산철 암모늄산화제1철-제1철
추가 설명 · 1건

정의ChEBI: A hydrate that is the heptahydrate form of iron(2+) sulfate. It is used as a source of iron in the treatment of iron-deficiency anaemia (generally in liquid-dosage treatments; for solid-dosage treatments, the monohydrate is normally used).