디보란

Diboron

HCID 6328200CAS 14452-61-0

기본 정보

표준 SMILES
B#B
InChIKey
ZOCHARZZJNPSEU-UHFFFAOYSA-N
분자식
B2
평균 분자량
21.63 g/mol
단동위원소 질량
22.0186108

개요

Diboron is a diatomic boron.

이름 및 식별자

우선 이름
Diboron
IUPAC
boranylidyneborane
현지명
디보란
영어명
Diborane
분자식
B2H6
분자량
27.67

이름 및 동의어

diborynediboronBoron, mol. (B2)CHEBI:51707DTXSID50131666514452-61-0Diatomic boronBoron dimerRefChem:53365DiboranCCRIS 4780DIBORANE [HSDB]
이름 더 보기
디보란보로에탄,디보란다이보레인다이보레인 (B2H6)다이보레인과 혼합물보레인 (B2H6)보로에테인붕소화 수소 (H6B2)수소화 붕소수소화 붕소 (B2H6)육수소화 이붕소B2H6boroneBoron hydride (B2H6)borinedlboraneDIBORANEBoroethaneChebi:33590Diborane(6)
SCHEMBL539DIBORANE(6) [MI]SCHEMBL3454712SCHEMBL12852195ZOCHARZZJNPSEU-UHFFFAOYSA-NDTXSID501335990AKOS015916125Diborane, compressed [UN1911] [Poison gas]

데이터베이스 식별자

CAS
14452-61-0、19287-45-7
PubChem CID
6328200
DTXSID
DTXSID501316665
ChEBI
CHEBI:51707
UNII
BS9K982N24
Nikkaji
J3.252.583K、J3.621.001J、J806.249H

물성

구조 계산 물성

극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
0
무거운 원자 수
2

물리화학적 성질

녹는점
-165 °C · -165°C
끓는 점
-93 °C · -93°C
밀도
0.477 · 0.477
인화점
-90 °C · -90°C
용해도
2 O · reacts with H2O
물리적 상태
무색 가스

화학적 성질

Diborane is a compressed, colorless, and flam- mable gas. It has a nauseating, sickly sweet odor.

안전 및 규제

안전 데이터

OEB
D
OEL
TWA: 0.1 ppm (0.1 mg/m3)
IDLA
15 ppm
tsca
TSCA listed
ridadr
UN 1911
독성
LC50 inhal (rat) 50 ppm (4 h)PEL (OSHA) 0.1 ppmTLV-TWA (ACGIH) 0.1 ppm

화학 및 산업

응용 분야 · 3건

용도디보란은 보란류의 하나로 고급 수소화붕소의 출발 물질로 중요한 화합물입니다.

개요Diborane is a colorless gas at room temperature and atmospheric pressure. It has an unpleasant, distinctive, sickly sweet odor. Diborane is a highly flammable gas that forms a flammable mixture with air over a range of 0.9 percent to 98 percent diborane (at 1 atm). Diborane bums in air (or oxygen) with a blue to green flame. Diborane is considered pyrophoric at room temperature. The gas is easily ignited by a spark or the heat of reaction with moisture in air. Pure diborane is insensitive to mechanical shock; however, shock and thermally sensitive mixtures may be formed in the presence of impurities such as oxygen, water, halogenated hydrocarbons, and so on. Thermal decomposition of diborane to hydrogen can result in excessive pressure buildup. Vessels for containment of diborane should be designed to contain such resultant decomposition pressure.

용도Diborane is used as a rocket propellant, in thevulcanization of rubber, as a polymerizationcatalyst, as a reducing agent, in the synthesisof trialkyl boranes, and as a doping agent(Merck 1996).

제조 방법

생산 방법Diborane now can be produced more easily and in larger quantities by the reaction of LiH, NaH or alkali borohydrides with BF3 diethyl etherate, To obtain good yields, the alkali hydrides must be very finely powdered.

관련 반응

279건

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