1,1',1''-(Chlorosilylidyne)tris(benzene) (HCID 6458)

이름 및 식별자

우선 이름: 1,1',1''-(Chlorosilylidyne)tris(benzene)
IUPAC: chloro(triphenyl)silane
영어명: Triphenylsilyl chloride
분자식: C18H15ClSi
분자량: 294.85

이름 및 동의어

Chlorotriphenylsilane76-86-8TriphenylchlorosilaneTriphenylsilyl chlorideDTXSID70870398Benzene, 1,1',1''-(chlorosilylidyne)tris-RefChem:575984DTXCID608181231,1',1''-(Chlorosilylidyne)tris(benzene)200-989-0CTPSSILANE, CHLOROTRIPHENYL-

이름 더 보기

P3TPCSMyD10ICAM-1/CDTRIPHENLCHLOROSILANEchlorotriphenyl-silanTriphenylchlorsoilane

chloro(triphenyl)silaneTriphenylsilicon chlorideMFCD00000496S20525triphenylsilylchloridechloro-tri(phenyl)silaneC18H15ClSiChlorotriphenylsilane.

데이터베이스 식별자

CAS: 76-86-8
PubChem CID: 6458
DTXSID: DTXSID70870398
EC Number: 200-989-0
Nikkaji: J54.324A

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 3
무거운 원자 수: 20
형식 전하: 0
복잡도: 240

실험 및 물리화학적 성질

Kovats Retention Index2191

물리화학적 성질

녹는점: 91 · 91-94 °C(lit.)
끓는 점: 378 °C · 378 °C
밀도: 1.14 · 1.14
인화점: 200 °C · >200°C
저장 조건: Refrigerator
용해도: 0.1 g/mL, · 에 용해됨 아세톤: 0.1 g/mL, 투명
물리적 상태: 수정 같은
색상: 하얀색
Specific Gravity: 1.16 · 1.16
수용성: 물과 반응합니다.
BRN: 1820487 · 1820487
InChI: 1S/C18H15ClSi/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChIKey: MNKYQPOFRKPUAE-UHFFFAOYSA-N
SMILES: Cl[Si](c1ccccc1)(c2ccccc2)c3ccccc3
NIST: Triphenylchlorosilane(76-86-8)
EPA: Silane, chlorotriphenyl- (76-86-8)

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H335 (80%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P319, P321, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 50 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 2건

Chemical: Silane, chlorotriphenyl-

Chlorotriphenylsilane: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesSkin Corr. 1B (100%)；STOT SE 3 (80%)

규제 정보

Regulatory Information · 2건

Chemical: Silane, chlorotriphenyl-

Chlorotriphenylsilane: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk: 1
tsca: TSCA listed
rtecs: VV2720000
ridadr: UN 3261 8/PG 2
HS 번호: 29310095
risk_code: 34-37
hazard_code: C
safety_code: 26-36/37/39-45-24/25
포장분류: II
위험 등급: 8
F 고인화성물질: 10-21
Hazard Classifications: Skin Corr. 1B
스토리지 클래스: 8A - Combustible corrosive hazardous materials

화학 및 산업

용도 및 제조

General Manufacturing InformationBenzene, 1,1',1''-(chlorosilylidyne)tris-: ACTIVE

응용 분야 · 2건

개요Triphenylsilyl chloride is a white to off-white crystal or powder with acrid ordor of hydrogen chloride, used for synthesis of pharmaceutical intermediates.

용도A wide variety of Grignard reagents and organolithium complexes participate in reactions with Ph3SiCl to afford organosilanes. Thus the reaction of allylmagnesium chloride with Ph3SiCl gives the allylsilane in high yield (eq 3).However, when hydrosilyl Grignard reagents are employed, reduction to the silane occurs (eq 4).Azaallyl anion6 and diazolithium salts can each be silylated to give the anticipated silane adducts (eqs 5 and 6). Similarly, arylsilanes8 and alkynylsilanes are produced upon silylation of the appropriate metalated13 carbanions with Ph3SiCl (eqs 7–11).