Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
사이클로헥사논 퍼옥사이드
과산화사이클로헥사논 · 사이클로헥사논퍼옥사이드 · 사이클로헥사논디퍼옥사이드 · 과산화사이클로헥사논(CYCLOHEXANONEPEROXIDE) · 1-하이드로퍼옥시사이클로헥실-1-하이드록시사이클로헥실퍼옥사이드 · Cyclohexanone peroxi · CYCLOHEXANONE PEROXIDE · Cyclohexanone peroxide solution
식별자 및 물리적 특성
| CAS No. | 12262-58-7 |
|---|---|
| 분자식 | C12H22O5 |
| 평균 분자량 | 246.3 g/mol |
| 단동위원소 질량 | 246.1467238 g/mol |
| SMILES | OOC1(OOC2(O)CCCCC2)CCCCC1 |
| InChIKey | UICXTANXZJJIBC-UHFFFAOYSA-N |
| PubChem CID | 6521 |
| EC No. | 201-091-1 |
| DTXSID | DTXSID9058812 |
| 현지명 | 사이클로헥사논 퍼옥사이드 |
화학 및 물리적 성질
| XLogP | 2.3 |
|---|---|
| 극성 표면적 | 68.2 |
| 수소 결합 공여자 수 | 2 |
| 수소 결합 수용자 수 | 5 |
| 회전 가능 결합 수 | 4 |
| 무거운 원자 수 | 17 |
| 형식 전하 | 0 |
| 복잡도 | 231 |
| 물질 분류 | Other Classes -> Peroxides, Organic |
| 밀도 | 1.05 at 68 °F (USCG, 1999) - Denser than waterwill sink1.15[at 20℃] |
| Color/Form | Grayish paste |
| 용해도 | OFF-WHITE THICK PASTEINSOL IN WATERSOL IN COMMON ORG SOLVENTS /PASTE WITH DIBUTYL PHTHALATE/Insoluble in watersoluble in most organic solvents |
| 인화점 | 315 °F Combustible solution) (dibutyl phthalate) (USCG, 1999) |
| 녹는점 | 76-77 °C65-70 °C |
| 증기압 | 0.00000071 [mmHg]2.16Pa at 25℃ |
| Physical Description | Cyclohexanone peroxide, not more than 72% in solution is a white solid dissolved in some unkown organic solvent. Responders should try to identify the solvent being used. Solvent is added to lessen explosion hazard.1-hydroxy-1'-hydroperoxy dicyclohexyl peroxide is an odorless thick white liquid. Sinks in water. (USCG, 1999)Odorless thick white liquid or paste[CAMEO] Moist white solid[MSDSonline] |
| 자연 발화 온도 | 757 °F (USCG, 1999) |
| 용해도 | 9.3g/L at 25℃ |
| LogP(분배 계수) | 1.2 at 29℃ |
| EPA | Cyclohexanone, peroxide (12262-58-7) |
안전 및 규제
| GHS 분류 | DangerH240: Heating may cause an explosion [Danger Self-reactive substances and mixturesOrganic peroxides]P210, P234, P235, P240, P260, P264, P270, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P363, P370+P372+P380+P373, P403, P405, P410, P411, P420, and P501 (click each P-code to see the statement) |
|---|---|
| 규제 정보 | Chemical: Cyclohexanol, 1-[(1-hydroperoxycyclohexyl)dioxy]-Chemical: Cyclohexanone, peroxideCyclohexanone, peroxide is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cyclohexanone, peroxide are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)REACH registered substance: Cyclohexanone, peroxide (EC: 235-527-7)Cyclohexanone peroxide, 30-60%, 30-60% dibutyl phthalate, 10-30% ethyl acetate: Does not have an individual approval but may be used under an appropriate group standardCyclohexanone peroxide, >25% in a non hazardous diluent: Does not have an individual approval but may be used under an appropriate group standard |
| 운송 라벨(DOT) | Organic Peroxide |
| 화재 위험 | Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Behavior in Fire: May explode (USCG, 1999) |
| 화재 가능성 | DANGEROUS /FIRE HAZARD/ BY CHEM REACTION WITH REDUCING AGENTS OR EXPOSURE TO HEAT. THEY ARE POWERFUL OXIDIZERS. /PEROXIDES, ORG/ALTHOUGH FLASHPOINTS OF MOST ORG PEROXIDES ARE NOT EXCEPTIONALLY LOW, WHEN IGNITED THEY BURN MORE FURIOUSLY THAN CORRESPONDING FLAMMABLE LIQ NOT CONTAINING THE PEROXY LINKAGE. ORG PEROXIDES CONTAIN SUFFICIENT AVAILABLE OXYGEN TO SUPPORT THEIR OWN COMBUSTION IN...ABSENCE OF ATMOSPHERIC OXYGEN. /PEROXIDES, ORG/ |
| 건강 유해성 | Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Irritates eyes and skin on contact. Ingestion causes irritation of mouth and stomach. (USCG, 1999) |
| 유해성 요약 | Water is added to paste to decrease explosion hazard[CAMEO] A skin sensitizerBlistering of the skin from prolonged contact |
용도
일반 설명
White solid dissolved in some unkown organic solvent. Responders should try to identify the solvent being used. Solvent is added to lessen explosion hazard.