1-Vinylimidazole (HCID 66171)

개요

structure in first source

이름 및 식별자

우선 이름: 1-Vinylimidazole
IUPAC: 1-ethenylimidazole
현지명: 1-비닐이미다졸
영어명: 1-Vinylimidazole
분자식: C5H6N2
분자량: 94.11

이름 및 동의어

1-Vinylimidazole1072-63-5N-Vinylimidazole1-ethenyl-1H-imidazole1H-Imidazole, 1-ethenyl-ODY9ION63ADTXSID0061458N-VI cpdRefChem:7907DTXCID8033061214-012-01-Vinyl-1H-imidazole

이름 더 보기

1-비닐이미다졸비닐이미다졸VINYL IMIDAZOLEN-VINYL IMIDAZOLESKL15551-VinylimidazolVinylimidazole VImVinyliMidazole,99+%1-ethenyl-1h-imidazol

Vinylimidazole1-ethenylimidazole1H-Imidazole, ethenyl-MFCD0000529729383-23-1LufixanEINECS 214-012-0UNII-ODY9ION63A

데이터베이스 식별자

CAS: 1072-63-5、25232-42-2、29383-23-1
PubChem CID: 66171
DTXSID: DTXSID0061458
ChEMBL: CHEMBL3929571
UNII: ODY9ION63A
EC Number: 214-012-0、608-353-8
Nikkaji: J26.587J

물성

구조 계산 물성

XLogP: 0.5
극성 표면적: 17.8 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 1
무거운 원자 수: 7
형식 전하: 0
복잡도: 70.5

실험 및 물리화학적 성질

Chemical ClassesNitrogen Compounds -> Imidazoles

Vapor Pressure0.38 [mmHg]

Physical Description · 2건

Liquid

Yellow liquid with an odor like amines; [BASF MSDS]

물리화학적 성질

녹는점: 78 · 78-79°C
끓는 점: 192 · 192-194 °C (lit.) 78-79 °C/13 mmHg (lit.)
밀도: 1.039 g/mL · 1.039 g/mL at 25 °C (lit.)
증기압: 38 Pa · 38Pa at 20℃
굴절률: 20 · n20/D 1.533(lit.)
인화점: 178 °F · 178 °F
저장 조건: 2 · under inert gas (nitrogen or Argon) at 2-8°C
용해도: 아세토니트릴(약간 용해됨), 클로로포름(약간 용해됨)
물리적 상태: 기름
산도 계수 (pKa): 6.07 · 6.07±0.10(Predicted)
색상: 무색
냄새: Amines-like odor
수용성: 물과 섞일 수 있습니다.
BRN: 105321 · 105321
안정성: 안정적인. 흡습성. 강한 산화제와 호환되지 않습니다.
InChI: 1S/C5H6N2/c1-2-7-4-3-6-5-7/h2-5H,1H2
InChIKey: OSSNTDFYBPYIEC-UHFFFAOYSA-N
SMILES: C=Cn1ccnc1
LogP: 0.54 at · 0.54 at 25℃
NIST: N-vinylimidazole(1072-63-5)
EPA: 1 H-Imidazole, · 1H-Imidazole, 1-ethenyl- (1072-63-5)

화학적 성질

Brown liquid

안전 및 규제

GHS 분류

GHS Classification · 6건

Danger

H360D: May damage the unborn child [Danger Reproductive toxicity]

P203, P280, P318, P405, and P501 (click each P-code to see the statement)

Danger

H302 (99.8%): Harmful if swallowed [Warning Acute toxicity, oral]

P203, P260, P264, P264+P265, P270, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P318, P321, P330, P363, P405, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 6건

Chemical: 1H-Imidazole, 1-ethenyl-

Hazard Traits - Reproductive Toxicity

1H-Imidazole, 1-ethenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1H-Imidazole, 1-ethenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 17-01-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/12790

Substance: 1-vinylimidazole

1-Vinylimidazole: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - 1H-Imidazole, 1-ethenyl- (N-vinyl imidazole)

Hazards SummaryNot a skin irritant; May cause serious eye injury; Chronic exposure may cause liver injury; [BASF MSDS]

Hazard Classes and Categories · 3건

Acute Tox. 4 (99.8%)

Reproductive toxicity - category 1B

Repr. 1B

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: UN 3267 8/PG 2
HS 번호: 29339900
risk_code: 22-34-41
hazard_code: C,F
safety_code: 26-36/37/39-45
포장분류: III
위험 등급: 8
기존화학 물질: 97-3-70
F 고인화성물질: 10
위험 참고 사항: Flammable/Light Sensitive
Hazard Classifications: Acute Tox. 4 OralEye Dam. 1Repr. 1B
스토리지 클래스: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects

화학 및 산업

용도 및 제조

UsesA monomer; [ExPub: EPA - TSCATS] Used to make and/or formulate industrial products; [BASF MSDS]

U.S. Production2023: <75,000 lb

Consumer UsesEmulsifier

Industry UsesNot Known or Reasonably Ascertainable

General Manufacturing Information · 2건

All Other Basic Organic Chemical Manufacturing

1H-Imidazole, 1-ethenyl-: ACTIVE

응용 분야 · 1건

용도1-Vinylimidazole is used as a monomer in the synthesis of molecularly imprinted polymers. It is involved in the removal of vinyl protecting groups with an isoprene-catalyzed lithiation process. Also, it is involved in the preparation of magnetic-poly(divinylbenzene-1-vinylimidazole) microbeads. Further, it is used to prepare ion imprinted polyvinylimidazole-silica hybrid copolymer.