디아잘

Diazald

HCID 6628CAS 60858-95-9
부분 구조 검색유사 구조 찾기

기본 정보

표준 SMILES
Cc1ccc(S(=O)(=O)N(C)N=O)cc1
InChIKey
FFKZOUIEAHOBHW-UHFFFAOYSA-N
분자식
C8H10N2O3S
평균 분자량
214.24 g/mol
단동위원소 질량
214.04121336

이름 및 식별자

우선 이름
Diazald
IUPAC
N,4-dimethyl-N-nitrosobenzenesulfonamide
현지명
디아잘
영어명
N-Methyl-N-nitrosotoluene-4-sulphonamide
분자식
C8H10N2O3S
분자량
214.24

이름 및 동의어

DiazaldDiazaloN-nitroso-N-methyl-4-toluenesulfonamideRefChem:85825380-11-5N-Methyl-N-nitroso-p-toluenesulfonamideN-Methyl-N-nitrosotoluene-4-sulphonamideN,4-dimethyl-N-nitrosobenzenesulfonamideDiazaleP-TOLYLSULFONYLMETHYLNITROSAMIDEBenzenesulfonamide, N,4-dimethyl-N-nitroso-p-Toluenesulfonamide, N-methyl-N-nitroso-
이름 더 보기
디아잘N,4-dimethyl-N-nitroso-BenzenesulfonamideDIAZOGENN-Methyl-N-nitroso-4-toluenesulfonamideDIAZALD(R)Diazogen,99%Diazogen,95%
p-TolylsulfonylmethylnitrosamineMethylnitroso-p-toluenesulfonamideToluene-p-sulfonylmethylnitrosamideN-Nitroso-N-methyl-p-toluenesulfamideN-Nitroso-N-methyl-4-tolylsulfonamideN-Methyl-N-nitroso-p-tolylsulfonylamidep-Tolylsulfonyl-methyl-nitrosamidNSC 313

데이터베이스 식별자

CAS
60858-95-9、80-11-5
PubChem CID
6628
DTXSID
DTXSID8058827
ChEMBL
CHEMBL1606452
ChEBI
CHEBI:143725
UNII
K3089966LA
EC Number
201-252-6、693-083-3
Nikkaji
J3.851B

물성

구조 계산 물성

XLogP
0.6
극성 표면적
75.2 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
5
회전 가능 결합 수
2
무거운 원자 수
14

실험 및 물리화학적 성질

Color/FormYELLOW CRYSTALS FROM BENZENE + PETROLEUM ETHER
Solubility · 4건

INSOL IN WATER; SOL IN ETHER, PETROLEUM ETHER, BENZENE

SOL IN CHLOROFORM, CARBON TETRACHLORIDE

VERY SOL IN HOT ALC

SOL IN MOST ORGANIC SOLVENTS

Melting Point62 °C
Vapor Pressure0.00000479 [mmHg]
Physical DescriptionYellow solid; [Merck Index] Fine light yellow crystals; [MSDSonline]
Stability/Shelf LifeSTABLE IN ORDINARY BROWN BOTTLE FOR SEVERAL YR; WHITE COATING (FORMED OF P-TOLYLSULFONYLMETHYLAMIDE) DOES NO HARM

물리화학적 성질

녹는점
58 °C · ~58 °C
끓는 점
320.5 · 320.5±35.0 °C(Predicted)
밀도
1.3844 · 1.3844 (rough estimate)
굴절률
1.569 · 1.5690 (estimate)
저장 조건
2 · 2-8°C
용해도
Chloroform (Slightly), Dichloromethane (Sparingly), DMSO (Slightly), Ethyl Acetate

화학적 성질

pale yellow crystalline powder

안전 및 규제

GHS 분류

GHS Classification · 6건

Danger

H242 (90.9%): Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]；H315 (97.7%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (88.6%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (97.7%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (88.6%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P234, P235, P240, P261, P264, P264+P265, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P370+P378, P403, P403+P233, P405, P410, P411, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 44 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory InformationBenzenesulfonamide, N,4-dimethyl-N-nitroso-: Does not have an individual approval but may be used under an appropriate group standard
Hazards SummaryA mutagen and tumorigen; [RTECS] May explode from shock or friction; May polymerize; An irritant; May cause skin sensitization; [MSDSonline]
Hazard Classes and Categories · 2건

Self-react. C (90.9%)；Skin Irrit. 2 (97.7%)；Skin Sens. 1 (88.6%)；Eye Irrit. 2 (97.7%)；STOT SE 3 (88.6%)

Skin Irrit. 2 (100%)；Skin Sens. 1 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (100%)

규제 정보

Regulatory InformationBenzenesulfonamide, N,4-dimethyl-N-nitroso-: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk
2
tsca
TSCA listed
rtecs
XT5950000
ridadr
UN 3234 4.1/PG 2
HS 번호
29350090
risk_code
2-36/37/38-43-20/21/22

화학 및 산업

용도 및 제조

Uses · 2건

Used to make diazomethane in the laboratory; [Merck Index]

IN LAB PREPN OF DIAZOMETHANE

Methods of ManufacturingPREPD BY ACTION OF NITROUS ACID ON P-TOLYLSULFONYLMETHYLAMIDE: GERMAN PATENT 224,388 (1910 TO BAYER)...
Formulations/PreparationsDIAZALD. TRADEMARK FOR N-METHYL-N-NITROSOPARATOLUENESULFONAMIDE.
General Manufacturing InformationBenzenesulfonamide, N,4-dimethyl-N-nitroso-: ACTIVE

응용 분야

용도N-Methyl-N-nitroso-p-toluenesulfonamide is Diazomethane precursor.

상·하류 제품 정보

공급사50 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
爱斯特（成都）生物制药股份有限公司+86-28-85122536 85324413 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
南京兰亚化工贸易有限公司+86-25-8331-5620 · [email protected]
衢州明锋化工有限公司0570-3062502 13819002126;13819008176 · [email protected]

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