1,3-BIS(3-아미노펜옥시)벤젠
1,3-BIS(3-아미노펜옥시)벤젠 · RESORCINOL BIS(3-AMINOPHENYL) ETHER · TPE-M · 1,3,3-APB · 3-[3-(3-AMINOPHENOXY)PHENOXY]ANILINE · APB-133 · TIMTEC-BB SBB008356 · 1,3-BIS(3-AMINOPHENO
식별자 및 물리적 특성
| CAS No. | 10526-07-5 |
|---|---|
| 분자식 | C18H16N2O2 |
| 평균 분자량 | 292.3 g/mol |
| 단동위원소 질량 | 292.12117775 g/mol |
| SMILES | Nc1cccc(Oc2cccc(Oc3cccc(N)c3)c2)c1 |
| InChIKey | DKKYOQYISDAQER-UHFFFAOYSA-N |
| PubChem CID | 66342 |
| EC No. | 234-082-6 |
| DTXSID | DTXSID4065109 |
| 현지명 | 1,3-BIS(3-아미노펜옥시)벤젠 |
화학 및 물리적 성질
| XLogP | 3.6 |
|---|---|
| 극성 표면적 | 70.5 |
| 수소 결합 공여자 수 | 2 |
| 수소 결합 수용자 수 | 4 |
| 회전 가능 결합 수 | 4 |
| 무거운 원자 수 | 22 |
| 형식 전하 | 0 |
| 복잡도 | 309 |
| 녹는점 | 108°C |
| 끓는 점 | 479.9±30.0 °C(Predicted) |
| 밀도 | 1.243 |
| 저장 조건 | Keep in dark place,Inert atmosphere,Room temperature |
| 용해도 | 물에 불용성 |
| 용해도 | Slightly soluble in methanol |
| 물리적 상태 | powder to crystal |
| pKa(산도 계수) | 4.29±0.10(Predicted) |
| 색상 | White to Light yellow to Light orange |
| InChI | InChI=1S/C18H16N2O2/c19-13-4-1-6-15(10-13)21-17-8-3-9-18(12-17)22-16-7-2-5-14(20)11-16/h1-12H,19-20H2 |
| InChIKey | DKKYOQYISDAQER-UHFFFAOYSA-N |
| SMILES | C1(OC2C=CC=C(N)C=2)=CC=CC(OC2C=CC=C(N)C=2)=C1 |
| EPA | Benzenamine, 3,3'-[1,3-phenylenebis(oxy)]bis- (10526-07-5) |
화학적 성질
1,3-Bis(3-aminophenoxy)benzene, also known as TIMTEC-BB SBB008356, is a Light yellow to yellow solid. It has slight solubility in methanol but is insoluble in water. To maintain its stability, it is recommended to store it in a cool and dark place. However, it is incompatible with oxidizing agents and should not be stored or handled near them to avoid any hazardous reactions.
안전 및 규제
| GHS 분류 | WarningH302 (50%): Harmful if swallowed [Warning Acute toxicity, oral]P261, P264, P270, P271, P272, P273, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P333+P317, P362+P364, P391, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 2 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Hazard Classes and Categories | Acute Tox. 4 (50%) |
| TSCA 등재 상태 | TSCA listed |
| 관세 코드 | 29222990 |
| 위험 문구(R) | 20/21/22 |
| 안전 문구(S) | 26-36/37/39 |
| 기존화학 물질 | 2009-3-3948 |
용도
용도
1,3-Bis(3-aminophenoxy)benzene is an intermediate compound used in the production of synthetic materials, such as PI (polyimide) films and polyimide materials.
제조 및 합성 방법
제조 방법
1,3-Bis(3-aminophenoxy)benzene is a reactive monomer commonly utilized in the synthesis of polyurethane coatings. This compound is processed at 200 degrees Celsius and has a viscosity of 1.5-2.0 centipoise at 25 degrees Celsius. Its chemical structure consists of three amine groups that are ether linked to a benzene ring with one hydroxyl group on the phenoxy side chain. The monomer can be synthesized via acylation reaction or polymerization process, typically through heating with a catalyst. The resulting product is thermally stable and resistant to heat up to 250 degrees Celsius.