Dicyclopentadiene dioxide

HCID 6673CAS 81-21-0

기본 정보

표준 SMILES
C1C2OC2C2C1C1CC2C2OC12
InChIKey
BQQUFAMSJAKLNB-UHFFFAOYSA-N
분자식
C10H12O2
평균 분자량
164.2 g/mol
단동위원소 질량
164.08372962

이름 및 식별자

우선 이름
Dicyclopentadiene dioxide
IUPAC
4,10-dioxapentacyclo[6.3.1.02,7.03,5.09,11]dodecane
영어명
Dicyclopentadiene diepoxide
분자식
C10H12O2
분자량
164.2

이름 및 동의어

Dicyclopentadiene diepoxideDICYCLOPENTADIENE DIOXIDEHSDB 5240Dicyclopentadiene dioxide (VAN)DTXSID4020452EINECS 201-334-11,2:5,6-Diepoxyhexahydro-4,7-methanoindanAI3-260462,4-Methano-2H-indeno(1,2-b:5,6-b')bisoxirene, octahydro-2,4-Methano-2H-indeno[1,2-b:5,6-b']bisoxirene, octahydro-Dicyclopentadiene dioxide, 70% exo isomers, 30% endo isomersDTXCID00452
이름 더 보기
BICYCLOPENTADIENE DIEPOXIDE2,4-Methano-2H-indeno1,2-b:5,6-bbisoxirene, octahydro-ep207unox207unox207xepoxide207unoxepoxide207bicyclopentadienedioxideBicyelopentadiene dioxide
NSC-24262NSC-30544NSC-34460NSC-54738NSC-56357UNII-4UQK50194RRefChem:1332582,4-METHANO-2H-INDENO(1,2-B:5,6-B')BISOXIRENE, OCTAHYDRO-, (1A.ALPHA.,1B.BETA.,2.BETA.,2A.ALPHA.,3A.ALPHA.,4.BETA.,4A.BETA.,5A.ALPHA.)-

데이터베이스 식별자

CAS
81-21-0
PubChem CID
6673
DTXSID
DTXSID4020452
ChEMBL
CHEMBL3184982
EC Number
201-334-1
Nikkaji
J192.584I

물성

구조 계산 물성

XLogP
0.8
극성 표면적
25.1 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
2
회전 가능 결합 수
0
무거운 원자 수
12

실험 및 물리화학적 성질

PolymersPlastics & Rubber -> Epoxides
OdorMILD TERPENE LIKE ODOR MAY BE MASKED BY MORE POWERFUL & DISTINCTIVE HYDROCARBON ODOR OF DICYCLOPENTADIENE.
Density1.331 @ 25 °C
Color/FormWHITE CRYSTALLINE POWDER
Solubility · 5건

SOL IN BENZENE

1.4% IN WATER

18.6% IN METHANOL

44.7% IN ACETONE

18.7% IN ETHER

Melting Point180-184 °C

물리화학적 성질

녹는점
185 · 185-189 °C(lit.)
끓는 점
120 °C · 120°C 10mm
밀도
1 · 1,331 g/cm3
굴절률
1.546 · 1.5460 (estimate)
인화점
120 °C/10mm · 120°C/10mm subl.
저장 조건
2 · 2-8°C

화학적 성질

white to yellow-beige crystals or

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P264, P264+P265, P270, P280, P301+P316, P305+P351+P338, P321, P330, P337+P317, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 2건

Chemical: 2,4-Methano-2H-indeno[1,2-b:5,6-b']bisoxirene, octahydro-

2,4-Methano-2H-indeno[1,2-b:5,6-b']bisoxirene, octahydro-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazards SummaryMild irritant on rabbit skin; Methemoglobinemia, CNS effects, and proteinuria reported in inhalation studies of rats; [RTECS] Emergency treatment: irritants; [HSDB] An eye irritant; [MSDSonline]
TSCA RequirementsSection 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble of the 51 FR 41329.
Hazard Classes and CategoriesAcute Tox. 3 (100%)

독성 정보

Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect
Human Toxicity ExcerptsNo cases of dermatitis or sensitization have been reported /in man/.
Non-Human Toxicity Excerpts · 2건

CMPD IS MODERATELY TOXIC FOLLOWING ORAL OR IP ENTRY INTO BODY & PRACTICALLY NONTOXIC ON PERCUTANEOUS ABSORPTION. ... THE LETHAL RANGE WHEN GIVEN ORALLY TO RATS AS 50 TO 140 MG/KG, AND 11 TO 53 MG/KG INTRAPERITONEALLY. ... RABBITS TOLERATED 1 G/KG PERCUTANEOUSLY WITHOUT EFFECT. IN INHALATION EXPERIMENTS A DOSE OF 1 G/CU M FOR 1 HR WAS MODERATELY TOXIC, AND 10 G/CU M FOR 1 HR WAS LETHAL TO 5 OF 6 TEST ANIMALS. SATURATED VAPORS WERE NONLETHAL TO RATS IN 8 HR EXPOSURE. ... MILDLY IRRITATING BUT NO CORNEAL INJURY IN RABBITS WITH TEST QUANT OF 0.05 G. 40% SOLN WAS LEAST CONCN TO CAUSE BARELY DETECTABLE INJURY. ... SKIN IRRITATION. UNDIL MATERIAL CAUSED REDNESS OF SHORT DURATION.

DICYCLOPENTADIENE DIOXIDE DID NOT SHOW ANY ALLERGENIC PROPERTIES WHEN APPLIED IN 10-50% SOLN TO SKIN OF GUINEA PIGS FOR 5-15 DAYS.

규제 정보

TSCA RequirementsSection 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble of the 51 FR 41329.

안전 데이터

wgk
3
tsca
TSCA listed
rtecs
PB9625200
ridadr
UN 2811 6.1/PG 3
독성
LD50 orl-rat: 210 mg/kg UCDS** 10/5/61
HS 번호
29109000

화학 및 산업

용도 및 제조

Uses · 5건

Used as an intermediate for epoxy resins, plasticizers, and protective coatings; as a rubber additive; and for high temperature and high performance adhesives; [HSDB]

Working with Glues and Adhesives [Category: Other]

INTERMEDIATE FOR EPOXY RESINS, PLASTICIZERS, PROTECTIVE COATINGS

RUBBER ADDITIVE, EG, FOR CRACK PREVENTION & ADHESION

For high temp & high performance system, adhesives

U.S. Production · 2건

(1979) PROBABLY GREATER THAN 2.72X10+6 G

(1980) PROBABLY GREATER THAN 2.72X10+6 G

Methods of ManufacturingPROBABLY BY DIELS-ALDER CONDENSATION OF CYCLOPENTADIENE FOLLOWED BY EPOXIDATION.
General Manufacturing Information · 2건

2,4-Methano-2H-indeno[1,2-b:5,6-b']bisoxirene, octahydro-: ACTIVE

AVAIL IN EXPTL QUANT, THIS DIFUNCTIONAL EPOXIDE IS SUGGESTED FOR USE AS PRIMARY BUILDING BLOCK FOR EPOXY RESIN SYSTEM. IT HAS ALSO BEEN SUGGESTED IN MODIFICATION OF ALKYD RESINS, AS PLASTICIZER, & AS CHEMICAL INTERMEDIATE.

응용 분야 · 1건

용도Dicyclopentadiene diepoxide acts as an intermediate for epoxy resins, plasticizers and protective coatings. It finds application as a rubber additive and adhesives, which is used at high temperature. Further, it is used in the preparation of endo-3-hydroxy-exo-9-oxa-exo-tetracyclo[5.3.1.02,6.08,10]undecane using lithium aluminum hydride as a reagent.

공급사50 곳

郑州阿尔法化工有限公司+86-18530059196 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]

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3건

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