Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
스티프닉 산
스티프닉산 · 2,4,6-트리니트로레소르시놀 · STYPHNIC ACID · 2,4,6-Trinitrobenzene-1,3-diol · syphnic acid · Trinitroresorcine · SALOR-INT L495999-1EA · LABOTEST-BB LT00000292
식별자 및 물리적 특성
| CAS No. | 82-71-3 |
|---|---|
| 분자식 | C6H3N3O8 |
| 평균 분자량 | 245.1 g/mol |
| 단동위원소 질량 | 244.99201406 g/mol |
| SMILES | O=[N+]([O-])c1cc([N+](=O)[O-])c(O)c([N+](=O)[O-])c1O |
| InChIKey | IXHMHWIBCIYOAZ-UHFFFAOYSA-N |
| PubChem CID | 6721 |
| EC No. | 201-436-6 |
| DTXSID | DTXSID7058880 |
| 현지명 | 스티프닉 산 |
화학 및 물리적 성질
| XLogP | 1.1 |
|---|---|
| 극성 표면적 | 178 |
| 수소 결합 공여자 수 | 2 |
| 수소 결합 수용자 수 | 8 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 17 |
| 형식 전하 | 0 |
| 복잡도 | 317 |
| 물질 분류 | Other Uses -> ExplosivesFlammable agents - 4th degree |
| SpringerMaterials Properties | Boiling point |
| Physical Description | Trinitroresorcinol appears as a yellowish, crystalline solid. Used as a priming agent. Very sensitive to heat. Primary hazard is blast of an instantaneous explosion, not flying projectiles or fragments. Under prolonged exposure to fire or heat the containers may explode violently.CBIWet SolidYellow solid[Merck Index] Ellipsoid particles[Olin Winchester Ammunition MSDS] |
| Ionization Efficiency | Negative1.0710.5Agilent XCTElectrospray ionizationammonia (10nM) |
| 녹는점 | 175.5°mp 179-180° |
| 끓는 점 | 388.06°C (rough estimate) |
| 밀도 | 2.012±0.06 g/cm3(Predicted) |
| 굴절률 | 1.6910 (estimate) |
| pKa(산도 계수) | 1.20±0.10(Predicted) |
| 용해도 | 5.4g/L(25℃) |
| EPA | 1,3-Benzenediol, 2,4,6-trinitro- (82-71-3) |
화학적 성질
Yellow crystals; astringent taste. An initiating explosive. Forms addition compounds with many hydrocarbons; soluble in alcohol and ether; slightly soluble in water.
안전 및 규제
| GHS 분류 | DangerH201: (Deleted) Explosivemass explosion hazard [Danger Explosives]P210, P230, P240, P250, P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, P370+P380, P372, P373, P401, and P501 (click each P-code to see the statement)H201 (17%): (Deleted) Explosive |
|---|---|
| 규제 정보 | Chemical: 1,3-Benzenediol, 2,4,6-trinitro-1,3-Benzenediol, 2,4,6-trinitro- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1,3-Benzenediol, 2,4,6-trinitro- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 17-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/22338The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| 운송 라벨(DOT) | Explosive 1.1D |
| 화재 위험 | Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]: |
| 건강 유해성 | Excerpt from ERG Guide 112 [Explosives - Division 1.1, 1.2, 1.3 or 1.5]: |
| 유해성 요약 | A strong oxidizing agentHighly sensitive to heat and may explode[CAMEO] ExplosiveA skin and eye irritantMay cause CNS depression and methemoglobinemia followed by liver and kidney injuryToxic to the kidney, blood, and nervous systemHarmful by ingestion, inhalation, and skin absorption[Olin Winchester Ammunition MSDS] See Barium styphnate. See 1,3,5-Trinitrobenzene. |
| 반응성 그룹 | Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic |
| Reactivity Alerts | Explosive |
| Reactivity Profile | Aromatic nitro compounds, such as TRINITRORESORCINOL, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups. |
용도
용도
2,4,6-Trinitroresorcinol has been used in the manufacture of explosives.
일반 설명
A yellowish, crystalline solid. May explode under exposure to heat or fire. Primary hazard is blast of an instantaneous explosion, not flying projectiles or fragments. Used as a priming agent. Very sensitive to heat. Water is added to lessen the explosion hazard.