CAS 423-39-2 Perfluorobutyl iodide (HCID 67917)

개요

is a promising alternative to chlorofluorocarbon solvents used in aircraft ground maintenance operations

이름 및 식별자

우선 이름: Perfluorobutyl iodide
IUPAC: 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodobutane
영어명: Perfluorobutyl iodide
분자식: C4F9I
분자량: 345.93

이름 및 동의어

Perfluorobutyl iodide423-39-2Nonafluoro-1-iodobutaneNonafluorobutyl iodide1,1,1,2,2,3,3,4,4-Nonafluoro-4-iodobutaneperfluoro-n-butyl iodideButane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-N4357HS8BYDTXSID0047583n-nonafluorobutyliodidePFBI solvent4-iodoperfluorobutane

이름 더 보기

PerfluoroiodobutaneC1014NH3uorobutyLPERFLUOROBUTYL IODODE1-Iodoperfluorobutane

RefChem:171647DTXCID80275831,1,2,2,3,3,4,4,4-nonafluoro-1-iodobutane207-025-8perfluorobutyliodide1-Iodononafluorobutanen-Nonafluorobutyl iodideC4F9I

데이터베이스 식별자

CAS: 423-39-2
PubChem CID: 67917
DTXSID: DTXSID0047583
UNII: N4357HS8BY
EC Number: 207-025-8
Nikkaji: J97.534F

물성

구조 계산 물성

XLogP: 4.1
극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 9
회전 가능 결합 수: 2
무거운 원자 수: 14
형식 전하: 0
복잡도: 215

실험 및 물리화학적 성질

Chemical ClassesOther Classes -> Halogenated Aliphatics, Saturated

PFAS · 4건

PFAS -> Other/unspecified

PFAS -> OECD Category

SpringerMaterials PropertiesOptical coefficient

Physical Description · 2건

Liquid

Colorless to pinkish liquid with a pungent odor; [3M MSDS]

물리화학적 성질

녹는점: -88 °C · -88 °C
끓는 점: 66 · 66-67 °C
밀도: 2.01 g/mL · 2.01 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.3285(lit.)
인화점: None
저장 조건: Keep in dark place,Inert atmosphere,Room temperature
물리적 상태: 액체
Specific Gravity: 2.01 · 2.010
색상: 클리어 퍼플
수용성: 섞일 수 없음
BRN: 1777546 · 1777546
안정성: 안정적인. 알칼리성 용액과 호환되지 않습니다.
InChI: 1S/C4F9I/c5-1(6,3(9,10)11)2(7,8)4(12,13)14
InChIKey: PGRFXXCKHGIFSV-UHFFFAOYSA-N
SMILES: FC(F)(F)C(F)(F)C(F)(F)C(F)(F)I
NIST: 1 · 1-Iodononafluorobutane(423-39-2)
EPA: 1 · Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo- (423-39-2)

화학적 성질

clear colourless liquid with pungent odour

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H315 (85.7%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 56 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 2건

Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1건

Causes respiratory depression in acute inhalation studies of rats; Causes excitement and arrhythmias in acute inhalation studies of dogs; Causes somnolence and changes in liver weight in 4-week intermittent inhalation studies of rats; [RTECS] A mild skin and eye irritant; [3M MSDS] See 2,2,3-Trichloroheptafluorobutane and Perfluorobutane.

Hazard Classes and CategoriesSkin Irrit. 2 (85.7%)

독성 정보

Toxicity DataLC50 (rat) = 14,000 ppm/4hr

안전 데이터

wgk: 3
tsca: TSCA listed
rtecs: EK5360000
ridadr: 2810
HS 번호: 29034700
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36-37/39
포장분류: III
위험 등급: 6.1(b)
F 고인화성물질: 8
위험 참고 사항: Irritant/Light Sensitive
Hazard Classifications: Aquatic Chronic 2
스토리지 클래스: 10 - Combustible liquids

화학 및 산업

용도 및 제조

UsesUsed as a chemical intermediate; [3M MSDS]

U.S. Production2023: 1,000,000 - <5,000,000 lb

Industry UsesIntermediate

Use ClassificationPFAS (per- and polyfluoroalkyl substances) -> OECD Category

General Manufacturing Information · 2건

Plastics Material and Resin Manufacturing

Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-: ACTIVE

응용 분야 · 2건

개요Perfluorobutyl iodide (PFBI) is a promising alternative to chlorofluorocarbon solvents used in aircraft ground maintenance operations and other military and commercial operations because it cleans well, has zero ozone depletion potential, and has extremely low global warming properties. Perfluorobutyl iodides also could used as gain media for a solar-pumped laser amplifier. This compound is usually utilized as perfluoroalkyl radical precursors[1–3].

용도Perfluorobutyl Iodide is used as an organocatalyst in some polymerization reactions.