황화바륨(BaS),검정색

Barium sulfide

HCID 6857597CAS 21109-95-5

기본 정보

표준 SMILES
[Ba+2].[S-2]
InChIKey
CJDPJFRMHVXWPT-UHFFFAOYSA-N
분자식
BaS
평균 분자량
169.39 g/mol
단동위원소 질량
169.8773182

개요

Barium sulfide is a sulfide salt and a barium salt.

이름 및 식별자

우선 이름
Barium sulfide
IUPAC
barium(2+) sulfide
현지명
황화 바륨
영어명
BARIUM SULFIDE
분자식
BaHS
분자량
170.4

이름 및 동의어

Barium sulfideBarium sulphideBariumsulfidBARIUM MONOSULFIDETV3U2GEW4HCHEBI:32590DTXSID30892157RefChem:916717barium(2+) ion sulfanediideDTXCID701324628244-214-421109-95-5
이름 더 보기
황화바륨황화바륨바륨설파이드BaSBlack ashyellowpowderEinecs 244-214-4Sulfurated barytabariumsulfide(bas)
Barium sulfide (bas)barium(2+);sulfideBarium sulfide, blackEINECS 256-814-3EINECS 232-376-9barium hydrogen sulfideUNII-PET6ZVZ3MK[BaS]

데이터베이스 식별자

CAS
21109-95-5、50864-67-0、8011-62-9
PubChem CID
6857597
DTXSID
DTXSID30892157
ChEBI
CHEBI:32590
UNII
TV3U2GEW4H
EC Number
244-214-4

물성

구조 계산 물성

극성 표면적
1 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
1
회전 가능 결합 수
0
무거운 원자 수
2

실험 및 물리화학적 성질

Chemical ClassesMetals -> Metals, Inorganic Compounds
CosmeticsDepilatory
SpringerMaterials Propertiesphonon wavenumber
Physical Description · 2건

Dry Powder

Water-soluble, gray powder; [Hawley] Smells like rotten eggs; Hydrolyzes in water; [MSDSonline]

물리화학적 성질

녹는점
1200 °C · 1200°C
밀도
4.25 g/mL · 4.25 g/mL at 15 °C(lit.)
물리적 상태
가루
Specific Gravity
4.25 · 4.25
색상
옅은 회색에서 노란색까지
수용성
물에는 용해되지만 알코올에는 용해되지 않습니다.

화학적 성질

colourless crystals, or white to grey-brown powder,

안전 및 규제

GHS 분류

GHS Classification · 6건

Warning

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P270, P271, P273, P301+P317, P304+P340, P317, P330, P391, and P501 (click each P-code to see the statement)

Danger

H290 (82.7%): May be corrosive to metals [Warning Corrosive to Metals]

P234, P260, P261, P264, P270, P271, P273, P280, P301+P316, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory Information · 3건

Chemical: Barium sulfide (BaS)

Barium sulfide (BaS) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Barium sulfide (BaS) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 28-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13592

Other Safety InformationIMAP assessments - Soluble Sulfide Salts: Human health tier II assessment
Hazards SummaryHarmful by ingestion and inhalation; [ESIS] Reacts with acid to form hydrogen sulfide; [www.ci.tucson.az.us/arthazards/medium.html] Contact with acid liberates toxic gas; [MSDSonline] SeeBarium.
Hazard Classes and Categories · 4건

Met. Corr. 1 (82.7%)

Hazardous to the aquatic environment (acute) - category 1

Acute toxicity (Oral) - Category 4

Acute Tox. 4 *

안전 및 보호

Exposure Control and Personal Protection0.5 [mg/m3], as Ba, inhalable fraction (soluble compds)[German Research Foundation (DFG)]
Minimum Risk LevelIntermediate Oral: 0.2 mg/kg/day (L134) Chronic Oral: 0.2 mg/kg/day (L134)
Threshold Limit Values (TLV)0.5 [mg/m3], as Ba
Permissible Exposure Limit (PEL)0.5 [mg/m3], as Ba
Immediately Dangerous to Life or Health (IDLH)50.0 [mg/m3], as Ba

독성 정보

TreatmentIntravenous infusion of potassium often relieves many of the symptoms of barium toxicity. (L214)
Health Effects · 1건

The health effects of the different barium compounds depend on how well the compound dissolves in water or the stomach contents. At low doses, barium acts as a muscle stimulant, while higher doses affect the nervous system, causing cardiac irregularities, tremors, weakness, anxiety, dyspnea, paralysisand possibly death. Barium may also cause gastrointestinal disturbances, damage the kidneys and cause decreases in body weight. (L214)

Adverse EffectsNephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
Exposure RoutesOral (L214) ; inhalation (L214)
Toxicity Summary · 1건

Barium is a competitive potassium channel antagonist that blocks the passive efflux of intracellular potassium, resulting in a shift of potassium from extracellular to intracellular compartments. The intracellular translocation of potassium results in a decreased resting membrane potential, making the muscle fibers electrically unexcitable and causing paralysis. Some of these barium's effects may also be due to barium induced neuromuscular blockade and membrane depolarization. (L214)

Signs and Symptoms · 1건

Ingesting excess barium may cause vomiting, abdominal cramps, diarrhea, difficulties in breathing, increased or decreased blood pressure, numbness around the face, and muscle weakness. High levels may result in changes in heart rhythm or paralysis and possibly death. (L214)

안전 데이터

wgk
2
tsca
TSCA listed
ridadr
UN 2813 4.3/PG 2
HS 번호
2830908500
risk_code
20/22-31-50-36/37/38-41-35
hazard_code
Xn,N,Xi,C

화학 및 산업

약리 정보

Metabolism/Metabolites · 1건

Barium compounds are absorbed via ingestion and inhalation, the extent of which depends on the individual compound. In the body, the majority of the barium is found in the bone, while small amounts exists in the muscle, adipose, skin, and connective tissue. Barium is not metabolized in the body, but it may be transported or incorporated into complexes or tissues. Barium is excreted in the urine and faeces. (L214)

용도 및 제조

Uses · 4건

Used to remove hair and to make luminous paints, lithopone, and vulcanized rubber; [Merck Index] Used for dehiding, flame retarding, and as a paint additive; [Hawley] Used in metallic patinas; [www.ci.tucson.az.us/arthazards/medium.html]

Painting (Pigments, Binders, and Biocides) [Category: Paint]

Applying metallic patinas [Category: Hobbies]

Barium sulfide is the precursor to barium carbonate and the pigment lithopone. (L211)

U.S. Production2023: 35,380,000 lb
Industry UsesIntermediate
Use ClassificationCosmetics -> Depilatory
General Manufacturing Information · 2건

All Other Basic Inorganic Chemical Manufacturing

Barium sulfide (BaS): ACTIVE

응용 분야 · 3건

출처Barium sulfide occurs in the form of black ash, which is a gray to black impure product obtained from high temperature carbonaceous reduction of barite. It is the starting material in the manufacture of most barium compounds including barium chloride and barium carbonate. It is used in luminous paints; for dehairing hides; as a flame retardant; and for generating H2S.

용도Barium sulfide has different characters, so it is used in a variety of ways, such as in electronics, paint pigments, dehairing hides, flame retardant, luminous paints, and generating pure hydrogen sulfide. Barium sulfide can deviate X-rays and helps to give clearly image of the soft tissue. Barium sulfide is a precursor to other barium compounds and also used as a short wavelength emitters for electronic displays.

일반 설명Barium sulfide (BaS) is an inorganic compound that is used as a precursor in the production of barium compounds. These compounds can be used in a variety of applications, such as ceramics, luminous paints, additives, and flame retardants.

제조 방법 · 2건

생산 방법Barium sulfide is grayish-white solid, formed by heating barium sulfate and carbon, reactive with H2O to form barium hydrosulfide, Ba(SH)2, solution. The latter is also made by saturation of barium hydroxide solution with H2S. Barium polysulfides are formed by boiling barium hydrosulfide with sulfur.

Barium sulfide can be prepared by the direct reaction of the elements, calcined in an inert atmosphere, at a 1:1.05 molecular ratio: Ba+S+heat→BaS Barium sulfide is prepared commercially by heating barite (BaO) with coal or petroleum coke in a rotary kiln at 1000°C to 1250°C in an oxygen-free atmosphere. The product, black ash, is a gray or black powder containing carbonaceous impurities and unreacted barite. Barium sulfide is separated from impurities by extraction with hot water and filtration. Barium sulfide may also be made by high temperature reduction of barium sulfate with methane.

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
阿诺西(上海)生物技术有限公司400-1107768 15058188853 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
山东瑞博恩新材料科技有限公司15064961989 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]

관련 반응

1건

연결된 노트

불러오는 중…