기본 정보
- 표준 SMILES
[Ba+2].[S-2]- InChIKey
CJDPJFRMHVXWPT-UHFFFAOYSA-N- 분자식
- BaS
- 평균 분자량
- 169.39 g/mol
- 단동위원소 질량
- 169.8773182
개요
Barium sulfide is a sulfide salt and a barium salt.
이름 및 식별자
- 우선 이름
- Barium sulfide
- IUPAC
- barium(2+) sulfide
- 현지명
- 황화 바륨
- 영어명
- BARIUM SULFIDE
- 분자식
- BaHS
- 분자량
- 170.4
이름 및 동의어
이름 더 보기
데이터베이스 식별자
- CAS
21109-95-5、50864-67-0、8011-62-9- PubChem CID
- 6857597
- DTXSID
DTXSID30892157- ChEBI
CHEBI:32590- UNII
- TV3U2GEW4H
- EC Number
- 244-214-4
물성
구조 계산 물성
- 극성 표면적
- 1 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 1
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 2
- 형식 전하
- 0
- 복잡도
- 0
실험 및 물리화학적 성질
Physical Description
Dry Powder
Water-soluble, gray powder; [Hawley] Smells like rotten eggs; Hydrolyzes in water; [MSDSonline]
물리화학적 성질
- 녹는점
- 1200 °C · 1200°C
- 밀도
- 4.25 g/mL · 4.25 g/mL at 15 °C(lit.)
- 물리적 상태
- 가루
- Specific Gravity
- 4.25 · 4.25
- 색상
- 옅은 회색에서 노란색까지
- 수용성
- 물에는 용해되지만 알코올에는 용해되지 않습니다.
- 비열
- 0.29 J/ · Cp(crystal): 0.29 J/(g·K), at 25℃
- Merck
- 14 · 14,995
- 안정성
- 안정적이지만 가열하면 분해됩니다. 산, 산화제, 물과 호환되지 않습니다.
- 화장품 원료 기능
- 제모제
- InChI
- 1S/Ba.S
- InChIKey
- OTMNKCRTGBGNPN-UHFFFAOYSA-N
- SMILES
- S=[Ba]
- NIST
- Barium sulfide(21109-95-5)
- EPA
- Barium sulfide (21109-95-5)
화학적 성질
colourless crystals, or white to grey-brown powder,
안전 및 규제
GHS 분류
GHS Classification
Warning
H302: Harmful if swallowed [Warning Acute toxicity, oral]
P261, P264, P270, P271, P273, P301+P317, P304+P340, P317, P330, P391, and P501 (click each P-code to see the statement)
Danger
H290 (82.7%): May be corrosive to metals [Warning Corrosive to Metals]
P234, P260, P261, P264, P270, P271, P273, P280, P301+P316, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)
유해성 정보
Regulatory Information
Chemical: Barium sulfide (BaS)
Barium sulfide (BaS) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Barium sulfide (BaS) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 28-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13592
Hazard Classes and Categories
Met. Corr. 1 (82.7%)
Hazardous to the aquatic environment (acute) - category 1
Acute toxicity (Oral) - Category 4
Acute Tox. 4 *
안전 및 보호
독성 정보
Health Effects
The health effects of the different barium compounds depend on how well the compound dissolves in water or the stomach contents. At low doses, barium acts as a muscle stimulant, while higher doses affect the nervous system, causing cardiac irregularities, tremors, weakness, anxiety, dyspnea, paralysisand possibly death. Barium may also cause gastrointestinal disturbances, damage the kidneys and cause decreases in body weight. (L214)
Toxicity Summary
Barium is a competitive potassium channel antagonist that blocks the passive efflux of intracellular potassium, resulting in a shift of potassium from extracellular to intracellular compartments. The intracellular translocation of potassium results in a decreased resting membrane potential, making the muscle fibers electrically unexcitable and causing paralysis. Some of these barium's effects may also be due to barium induced neuromuscular blockade and membrane depolarization. (L214)
Signs and Symptoms
Ingesting excess barium may cause vomiting, abdominal cramps, diarrhea, difficulties in breathing, increased or decreased blood pressure, numbness around the face, and muscle weakness. High levels may result in changes in heart rhythm or paralysis and possibly death. (L214)
안전 데이터
- wgk
- 2
- tsca
- TSCA listed
- ridadr
- UN 2813 4.3/PG 2
- HS 번호
- 2830908500
- risk_code
- 20/22-31-50-36/37/38-41-35
- hazard_code
- Xn,N,Xi,C
- safety_code
- 28-61
- 포장분류
- III
- 위험 등급
- 4.3
- 기존화학 물질
- KE-02093
- Hazard Classifications
- Acute Tox. 3 OralAcute Tox. 4 InhalationAquatic Acute 1Met. Corr. 1Skin Corr. 1A
- 스토리지 클래스
- 4.3 - Hazardous materials which set free flammable gases upon contact with water
화학 및 산업
약리 정보
Metabolism/Metabolites
Barium compounds are absorbed via ingestion and inhalation, the extent of which depends on the individual compound. In the body, the majority of the barium is found in the bone, while small amounts exists in the muscle, adipose, skin, and connective tissue. Barium is not metabolized in the body, but it may be transported or incorporated into complexes or tissues. Barium is excreted in the urine and faeces. (L214)
용도 및 제조
Uses
Used to remove hair and to make luminous paints, lithopone, and vulcanized rubber; [Merck Index] Used for dehiding, flame retarding, and as a paint additive; [Hawley] Used in metallic patinas; [www.ci.tucson.az.us/arthazards/medium.html]
Painting (Pigments, Binders, and Biocides) [Category: Paint]
Applying metallic patinas [Category: Hobbies]
Barium sulfide is the precursor to barium carbonate and the pigment lithopone. (L211)
General Manufacturing Information
All Other Basic Inorganic Chemical Manufacturing
Barium sulfide (BaS): ACTIVE
응용 분야
출처Barium sulfide occurs in the form of black ash, which is a gray to black impure product obtained from high temperature carbonaceous reduction of barite. It is the starting material in the manufacture of most barium compounds including barium chloride and barium carbonate. It is used in luminous paints; for dehairing hides; as a flame retardant; and for generating H2S.
용도Barium sulfide has different characters, so it is used in a variety of ways, such as in electronics, paint pigments, dehairing hides, flame retardant, luminous paints, and generating pure hydrogen sulfide. Barium sulfide can deviate X-rays and helps to give clearly image of the soft tissue. Barium sulfide is a precursor to other barium compounds and also used as a short wavelength emitters for electronic displays.
일반 설명Barium sulfide (BaS) is an inorganic compound that is used as a precursor in the production of barium compounds. These compounds can be used in a variety of applications, such as ceramics, luminous paints, additives, and flame retardants.
제조 방법
생산 방법Barium sulfide is grayish-white solid, formed by heating barium sulfate and carbon, reactive with H2O to form barium hydrosulfide, Ba(SH)2, solution. The latter is also made by saturation of barium hydroxide solution with H2S. Barium polysulfides are formed by boiling barium hydrosulfide with sulfur.
Barium sulfide can be prepared by the direct reaction of the elements, calcined in an inert atmosphere, at a 1:1.05 molecular ratio: Ba+S+heat→BaS Barium sulfide is prepared commercially by heating barite (BaO) with coal or petroleum coke in a rotary kiln at 1000°C to 1250°C in an oxygen-free atmosphere. The product, black ash, is a gray or black powder containing carbonaceous impurities and unreacted barite. Barium sulfide is separated from impurities by extraction with hot water and filtration. Barium sulfide may also be made by high temperature reduction of barium sulfate with methane.
상·하류 제품 정보
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