Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
트리클로로이소시아눌산
트라이클로로아이소시아누르산 · 심클로센 · 트라이클로로아이소사이아누린산 · 트리클로로이소시아눌산 · TCCA · TCICA · BLEACH · 1,3,5-Trichloro-1,3,5-triazinane-2,4,6-trione
식별자 및 물리적 특성
| CAS No. | 87-90-1 |
|---|---|
| 분자식 | C3Cl3N3O3 |
| 평균 분자량 | 232.41 g/mol |
| 단동위원소 질량 | 230.9005239 g/mol |
| SMILES | O=c1n(Cl)c(=O)n(Cl)c(=O)n1Cl |
| InChIKey | YRIZYWQGELRKNT-UHFFFAOYSA-N |
| PubChem CID | 6909 |
| ChEMBL | CHEMBL1698868 |
| ChEBI | CHEBI:33015 |
| EC No. | 201-782-8 |
| DTXSID | DTXSID2026523 |
| 현지명 | 트리클로로이소시아눌산 |
화학 및 물리적 성질
| XLogP | 1.2 |
|---|---|
| 극성 표면적 | 60.9 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 3 |
| 회전 가능 결합 수 | 0 |
| 무거운 원자 수 | 12 |
| 형식 전하 | 0 |
| 복잡도 | 202 |
| 물질 분류 | Other Uses -> Biocides/DisinfectantsReactive agents - 2nd degree |
| pH | pH = 4.42.0-2.7 (10g/l, H2O, 20℃) |
| SpringerMaterials Properties | Nuclear quadrupole resonance spectroscopy |
| LogP(분배 계수) | 0.26 |
| 냄새 | Chlorine odor염소 냄새 |
| 밀도 | greater than 1 at 68 °F (est) (USCG, 1999)Greater than 1 at 20 °C (solid)2.07 g/cm³> 1 |
| Color/Form | Needles from ethylene chlorideWhite crystalline powder or granulesWhite crystals |
| 용해도 | Soluble in chlorinated and highly polar solventsSolubility in water at 25 °C = 1 g/100 gSolubility in acetone at 30 °C = 35.0 g/100 gWater solubility = 1.2% = 1.20X10+4 mg/L at 25 °CSolubility in water, g/100ml at 25 °C: 1.2클로로포름(아주 적은 양으로 녹여라, 가열), DMSO(약간 용해됨) |
| 인화점 | > 250 °C (482 °F ) open cup121°C |
| Decomposition | When heated to decomposition it emits very toxic fumes of /chlorine and nitrogen oxides/.>225 °C |
| 녹는점 | 246.7 °C (decomposes)235 °C249-251 °C (lit.) |
| 증기압 | 0.00000012 [mmHg]negligible0.001-0.002Pa at 20-25℃ |
| 끓는 점 | 272.3±23.0 °C(Predicted) |
| 저장 조건 | Store below +30°C. |
| pKa(산도 계수) | -4.49±0.20(Predicted) |
| 물리적 상태 | 분말 또는 과립 |
| 색상 | 흰색에서 거의 흰색 |
| 용해도 | 1.2g/100mL(25℃) |
| Merck | 14,9641 |
| BRN | 202022 |
| 헨리 상수 | 1.6×105 mol/(m3Pa) at 25℃, HSDB (2015) |
| 안정성 | 안정적인. 흡습성이 있으며 습기와 접촉하면 분해될 수 있습니다. 가연성 물질과 접촉하면 화재가 발생할 수 있습니다. 산, 환원제, 물, 강산화제와 호환되지 않습니다. |
| InChI | 1S/C3Cl3N3O3/c4-7-1(10)8(5)3(12)9(6)2(7)11 |
| InChIKey | YRIZYWQGELRKNT-UHFFFAOYSA-N |
| SMILES | ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O |
| LogP(분배 계수) | -1.31-0.94 at 25℃ |
| NIST | Trichlorocyanuric acid(87-90-1) |
| EPA | Trichloro-s-triazinetrione (87-90-1) |
화학적 성질
white to light yellow crystal powde
안전 및 규제
| GHS 분류 | DangerH272: May intensify fireoxidizer [Danger Oxidizing liquidsOxidizing solids]P210, P220, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P304+P340, P305+P351+P338, P319, P330, P337+P317, P370+P378, P391, P403+P233, P405, and P501 (click each P-code to see the statement)H272 (100%): May intensify fireP210, P220, P260, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P330, P337+P317, P363, P370+P378, P391, P403+P233, P405, and P501 (click each P-code to see the statement) |
|---|---|
| 규제 정보 | Chemical: 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro-1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 15-08-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/245021,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro-: HSNO Approval: HSR001359 Approved with controlsThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| 기타 안전 정보 | IMAP assessments - 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro-: Human health tier II assessment |
| 운송 라벨(DOT) | Oxidizer |
| 화재 위험 | Special Hazards of Combustion Products: Toxic chlorine or nitrogen trichloride may be formed in fires.CAUTION: Ammonium nitrate products may explode if involved in fire or contaminated with hydrocarbons (fuels), organic matter, other contaminants or when hot molten and contained. Treat as an explosive (GUIDE 112).Not combustible but enhances combustion of other substances. Gives off irritating or toxic fumes (or gases) in a fire. Risk of explosion on heating. Risk of explosion on contact with combustible substances or incompatible substances. See Chemical Dangers. |
| 화재 가능성 | Noncombustible, but due to high reactivity (chlorination, oxidation), may cause ignition by contact with many substances, organic substances easily chlorinated or oxidizeD.Not combustible. Reacts with combustible materials, ammonium salts, or foreign substances, resulting in fire. |
| 건강 유해성 | Inhalation causes sneezing and coughing. Contact with dust causes moderate irritation of eyes and itching and redness of skin. Ingestion causes burns of mouth and stomach. (USCG, 1999)· Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. |
| 유해성 요약 | Forms hypochlorous acid on contact with waterA moderate skin, eye, and mucous membrane irritant[Merck Index] A strong oxidant that reacts violently with combustible substancesDecomposed by water forming hypochloric acid and cyanuric acidA mild skin irritantA severe eye and respiratory tract irritantInhalation of dust or decomposition products may cause pulmonary edema[ICSC] Irritating to skin, eyes, and respiratory tractEstimated lethal oral dose = 1 ounce to 1 pint for a 150 lb. personOral LD50 (rat) = 406 mg/kgSkin LD50 (rabbit) = 20,000 mg/kg[HSDB] A strong oxidizing agentMay react with water producing chlorine gasMay cause skin and eye irritation[CAMEO] A skin, eye, and respiratory tract irritantMay cause corrosive injuries on prolonged contact with skin and eyes[CHEMINFO] A skin irritantCorrosive to eyes[eChemPortal: ERMA] An eye and respiratory tract irritant[eChemPortal: ESIS] An oxidizing agentMay cause fire on contact with combustible materialAn irritantMay cause corrosive injuries[MSDSonline] See Sodium cyanurate and Sodium dichloroisocyanurate. |
| 운송 번호 및 가이드(DOT) | 2468 140 |
| 반응성 그룹 | Salts, Acidic |
| EC 분류 | Symbol: O, Xn, NR: 8-22-36/37-31-50/53S: (2)-8-26-41-60-61 |
| UN 분류 | UN Hazard Class: 5.1UN Pack Group: II |
| Special Reports | European Commission, ESISIUCLID Dataset, Symclosene (87-90-1) (2000 CD-ROM edition) contains information on use, toxicology, and environmental effects of this chemical as supplied to the European Union by industry..[Available from, as of September 25, 2009: http://esis.jrc.ec.europa.eu/]USEPA/Office of Pesticide ProgramsReregistration Eligibility Decision Document - Chlorinated Isocyanurates (September 1992). The RED summarizes the risk assessment conclusions and outlines any risk reduction measures necessary for the pesticide to continue to be registered in the U.S.[Available from, as of October 7, 2009: http://www.epa.gov/pesticides/reregistration/status.htm] |
| 소화 | Fire Extinguishing Agents: Water in large amounts (USCG, 1999)Use water in large amounts, foam, dry powder. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water. |
| 응급 조치 | Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again.Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer immediately for medical attention.Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention . |
| 누출 비상 조치 | · CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.· Keep combustibles (wood, paper, oil, etc.) away from spilled material. |
| 응급 처치 | INHALATION: remove victim to fresh air.General First Aid: |
| 안전 보관 | Dry. Well closed. Separated from amines, combustible substances and reducing agents. See Chemical Dangers. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing. |
| Firefighting Hazards | Closed containers may rupture violently when heated. Thermally unstable. Decomposes at 437 °F (225 °C). |
| 노출 관리 및 개인 보호 | · Wear positive pressure self-contained breathing apparatus (SCBA). |
| 소화 절차 | Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Fight fire from protected location or maximum possible distance. Use flooding quantities of water on fire-involved containers. If necessary use water spray to keep fire-exposed containers cool. Avoid use of water on non-involved material wherever possible.If material involved in fire: Cool all affected containers with flooding quantities of water. Use water in flooding quantities as fog. Apply water from as far a distance as possible. Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) |
| 보관 조건 | Store in a cool, dry, well-ventilated location. Outside or detached storage is preferred. Must be stored in a dry location on pallets arranged according to NFPA 430, Code for Storage of Liquids and Solid Oxidizers. Separate from combustibles, oxidizables, ammonia, sodium carbonate (soda ash), calcium hypochlorite, hydrogen peroxide.Protect container against physical damage. Store in a cool, dark room well-ventilated, and keep away from flammable and oxidizable substances. Drums may explode by heating or contact with water. Therefore, place drums on a palette to protect from washing water, drainage, etc. on the floor. Should not be kept long under insufficient ventilation in summer.Sources of ignition, such as smoking and open flames, are prohibited where trichloroisocyanuric acid is used, handled, or stored in a manner that could create a potential fire or explosion hazard.Safe Storage of Pesticides. Always store pesticides in their original containers, complete with labels that list ingredients, directions for use, and first aid steps in case of accidental poisoning. Never store pesticides in cabinets with or near food, animal feed, or medical supplies. Do not store pesticides in places where flooding is possible or in places where they might spill or leak into wells, drains, ground water, or surface water. |
| 정리 방법 | SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a permitted wastewater treatment facility is acceptable only after review by the governing authority and assurance that "pass through" violations will not occur. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must be evaluated in accordance with EPA 40 CFR Part 261, specifically Subpart B, in order to determine the appropriate local, state and federal requirements for disposal.Keep water away from release. Approach release from upwind. Isolate leaking containers, if this can be done without undue risk. Prompt cleanup and removal is necessary. Shovel into suitable dry container. control runoff and isolate discharged material for proper disposal.Cover with weak reducing agent such as hypo, bisulfites or ferrous salts. Bisulfites or ferrous salts need additional promoter of some 3M-H2SO4 for rapid reaction. Transfer the slurry (or sludge) into a large container of water and neutralize with soda ash. Drain into the sewer with abundant water.If a spill occurs, clean it up promptly. Don't wash it away. Instead, sprinkle the spill with sawdust, vermiculite, or kitty litter. Sweep it into a plastic garbage bag, and dispose of it as directed on the pesticide product label.After Applying a Pesticide, Indoors or Outdoors. To remove pesticide residues, use a bucket to rinse tools or equipment three times, including any containers or utensils that you used when mixing the pesticide. Then pour the rinsewater into the pesticide sprayer and reuse the solution by applying it according to the pesticide product label directions. After applying any pesticide wash your hands and any other parts of your body that may have come in contact with the pesticide..To prevent tracking pesticides inside, remove or rinse your boots or shoes before entering your home. Wash any clothes that have been exposed to a lot of pesticide separately from your regular wash. |
| 비화재 누출 대응 | Excerpt from ERG Guide 140 [Oxidizers]: |
| 처리 방법 | SRP: Criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.Add substance into dilute solution of sodium hydroxide or soda ash with stirring gradualy and neutralize that solution with reducing agents such as sodium sulfite and sodium thiosulfate. Adjust pH with sulfuric acid or hydrogen chloride to make neutral solution and dispose.Evacuate persons not wearing protective equipment from area of spill or leak until clean-up is complete. Remove all ignition sources. Collect powdered material in the most convenient and safe manner and deposit in sealed containers. Ventilate area after clean-up is complete. It may be necessary to contain and dispose of this chemical as a hazardous waste. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters.Use vast volume of concentrated solution of reducing agent (bisulfites or ferrous salts with 3M-H2SO4 or hypo). Neutralize with soda ash or dilute hydrochloric acid. Drain into the sewer with abundant water.For more Disposal Methods (Complete) data for Trichloroisocyanuric acid (6 total), please visit the HSDB record page. |
| 상호 작용 | Halogenated isocyanurates exhibit biocidal synergism when used with 3-isothiazolone derivatives. |
| 생태독성 수치 | LC50Species: Anas platyrhynchos (Mallard duck, age 14 days) diet >10000 ppm for 8 daysSpecies: Anas platyrhynchos (Mallard duck) diet >5000 ppm for 8 daysSpecies: Anas platyrhynchos (Mallard duck, age 9 days) diet >5620 ppm for 8 daysLD50Species: Anas platyrhynchos (Mallard duck, age 14 days) oral via capsule 1890 mg/kgFor more Ecotoxicity Values (Complete) data for Trichloroisocyanuric acid (21 total), please visit the HSDB record page. |
| 환경 거동 | TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 25(SRC), determined from a water solubility of 1.2X10+4 mg/L(2) and a regression-derived equation(3), indicates that trichloroisocyanuric acid is expected to have very high mobility in soil(SRC). Volatilization of trichloroisocyanuric acid from moist soil surfaces is not expected to be an important fate process(SRC) given an estimated Henry's Law constant of 6.2X10-11 atm-cu m/mole(SRC), using a fragment constant estimation method(4). Trichloroisocyanuric acid is not expected to volatilize from dry soil surfaces(SRC) based upon an estimated vapor pressure of 1.6X10-8 mm Hg at 25 °C(SRC), determined from a fragment constant method(5). Biodegradation data for trichloroisocyanuric acid in the terrestrial environment were not available(SRC,2009). However, in the Japanese MITI test, trichloroisocyanuric acid reacted with water to form isocyanuric acid, which is confirmed to be biodegradable(6).AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 25(SRC), determined from a water solubility of 1.2X10+4 mg/L(2) and a regression-derived equation(3), indicates that trichloroisocyanuric acid is not expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is not expected(4) based upon an estimated Henry's Law constant of 6.2X10-11 atm-cu m/mole(SRC), developed using a fragment constant estimation method(5). According to a classification scheme(6), an estimated BCF of 3.1(SRC), from its water solublity(2) and a regression-derived equation(7), suggests the potential for bioconcentration in aquatic organisms is low(SRC). Trichloroisocyanuric acid is expected to undergo hydrolysis in the environment since this compound contains functional groups that hydrolyze under environmental conditions(4). Biodegradation data for trichloroisocyanuric acid in the aquatic environment were not available(SRC,2009). However, in the Japanese MITI test, trichloroisocyanuric acid reacted with water to form isocyanuric acid, which is confirmed to be biodegradable(8).ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), trichloroisocyanuric acid, which has an estimated vapor pressure of 1.6X10-8 mm Hg at 25 °C(SRC), determined from a fragment constant method(2), is expected to exist solely in the particulate phase in the ambient atmosphere. Particulate-phase trichloroisocyanuric acid may be removed from the air by wet or dry deposition(SRC). Trichloroisocyanuric acid does not contain chromophores that absorb at wavelengths >290 nm(3) and therefore is not expected to be susceptible to direct photolysis by sunlight(SRC). |
| 유해 작용 | Dermatotoxin - Skin burns. |
| 노출 경로 | The substance can be absorbed into the body in hazardous amounts by inhalation and by ingestion. |
| 생태독성 발췌 | /AQUATIC SPECIES/ The effects of trichloroisocyanuric acid (TCCA) ... on the freshwater alga Chlorella vulgaris were assessed by toxicity bioassays and by the values of biomarkers in phase I and phase II. The biomarkers included growth rate, concentration of chlorophyll a, activities of 7-ethoxyresorufin-O-dealkylases (EROD), glutathione S-transferase (GST), catalase (CAT), and total glutathione (GSH) ... Trichloroisocyanuric acid was a strong growth inhibitor and, at concentrations of greater than 0.80 mg/L, caused 100% inhibition on 24-hr exposure. The 96-hr EC50 of TCCA was 0.313 mg/L ... In TCCA exposure, GST activity was significantly stimulated, and GSH concentration was increased. Catalase activity increased only at TCCA concentrations of greater than 0.12 mg/L, and no change in EROD activity was observed./AQUATIC SPECIES/ This paper reports the acute toxicity of three biocides used in the disinfection of cooling towers, tetrakis(hydroxymethyl) phosphonium chloride (THPC), trichloroisocyanuric acid (TCIC), and sodium bromide (NaBr), on Artemia larvae, their effect on the phototactic response of this organism, and the potential of bioaccumulation in this species. The 24-hr median lethal concentration (LC50) values for these biocides with respect to 24-, 48-, and 72-hr-old Artemia, determined by static bioassays, showed the following rank order of toxicity: THPC < TCIC < NaBr. An age-dependent increase in sensitivity was seen for each compound. All three biocides reduced the phototactic response of 24-hr-old Artemia larvae in 24-hr static bioassaysthe median inhibitory concentration ratios obtained were 30 to 40 times lower than their respective 24-hr LC50 values. The results suggest that phototaxis bioassays could provide the speed and simplicity required for screening many potential pollutants for harmful effects. The bioconcentration factors obtained for Artemia larvae exposed to 10% LC50 for 168 hr in renewal assays were 93.75, 1.67, and 0.23 for THPC, TCIC, and NaBr, respectively. This shows these biocides pose no bioaccumulation risk in this organism, although the value of 93.75 obtained for THPC is close to the threshold above which such a risk is considered to exist. |
| Signs and Symptoms | Cough. Sore throat. Laboured breathing.Redness.Redness. Pain. Burns.Abdominal pain. Burning sensation. Shock or collapse. |
| ICSC Environmental Data | The substance is very toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment. |
| Soil Adsorption/Mobility | The Koc of trichloroisocyanuric acid is estimated as 25(SRC), using a water solubility of 1.20X10+4 mg/L(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that trichloroisocyanuric acid is expected to have very high mobility in soil. |
| Human Toxicity Excerpts | /HUMAN EXPOSURE STUDIES/ Trichloroisocyanuric acid solution (neutralized, 100 mg/L as available chlorine) was tested on 10 individuals by immersion of the entire forearms eight times a day for 7 days and after a 2 wk rest repeated for 7 days. No skin irritation or sensitization was observed./SIGNS AND SYMPTOMS/ Human systemic effects by ingestion: ulceration or bleeding from stomach. Toxicity symptoms include emaciation, lethargy, weakness, and delayed death./CASE REPORTS/ Two patients were admitted to the hospital emergency room in respiratory distress after an accidental explosion involving chlorinating agents for the swimming pool. The two primary agents involved were calcium hypochlorite and trichloro-s-triazinetrioneboth are commonly used chlorinating agents ...The amount of calcium hypochlorite primarily determines the rate of reaction and heat generation. Appropriate emergency action and treatment for chlorine gas is discussed./SURVEILLANCE/ Possible health hazards due to worker exposure to chlorinated isocyanurates at Olin Chemical, Lake Charles, Louisiana, were investigated. At the time of the survey about 90 workers were employed in production activities associated with packaging trichloroisocyanuric acid and sodium dichloroisocyanurate. Personal breathing zone sampling and medical interviews were performed. Particulate concentrations ranged from 0.11 to 38 mg/cu m. About 60% of the dust near the packaging areas was within the respirable size range. No OSHA standards for exposure to any chlorinated isocyanurates have been developed. Workers used respirator facepieces with high efficiency particulate filters. All production workers reported one or more work related symptoms. The most common symptoms were eye irritation and cough. 78% of the women interviewed reported problems or changes in their menstrual cycle since beginning work in the packaging area. |
| Artificial Pollution Sources | Trichloroisocyanuric acid's production and use as an active ingredient in household dry bleaches, dishwashing compounds, scouring powders, detergent sanitizers, commercial laundry bleaches, swimming-pool disinfectant, bactericide, algicide, bleach, and deodorant(1) may result in its release to the environment through various waste streams(SRC). |
| Environmental Biodegradation | AEROBIC: Cyanuric acid is ultimately the end product of use of chloroisocyanurates in bleaching, sanitizing, and disinfection applications. Since the N-chloro derivatives are biocidal, biodegradation studies have centered on the residual cyanuric acid, which has been shown to undergo biodegradation under environmental conditions(1). In the Japanese MITI test, trichloroisocyanuric acid reacted with water to form isocyanuric acid, which is confirmed to be biodegradable(2). |
| FIFRA 요건 | Residues of the following chemical substances are exempted from the requirement of a tolerance when used in accordance with good manufacturing practice as ingredients in an antimicrobial pesticide formulation, provided that the substance is applied on a semi-permanent or permanent food-contact surface (other than being applied on food packaging) with adequate draining before contact with food. ... (c) The following chemical substances when used as ingredients in an antimicrobial pesticide formulation may be applied to: Food-processing equipment and utensils. 1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-trichloro- is included on this list. Limit: When ready for use, the end-use concentration of all di- or trichloroisocyanuric acid chemicals in the solution is not to exceed 100 ppm determined as total available chlorine.The Agency has sufficient information on the health effects of the chlorinated isocyanurates and on their potential for causing adverse effects in fish and wildlife and the environment for all uses registered for these chemicals. The Agency therefore concludes that products containing the chlorinated isocyanurates for these uses are eligible for reregistration. Only product chemistry data on certain manufacturing use products are still needed. The Agency has determined that the chlorinated isocyanurate products, labeled and used as specified in this Reregistration Eligibility Document, will not pose unreasonable risks or adverse effects to humans or the environment.As the federal pesticide law FIFRA directs, EPA is conducting a comprehensive review of older pesticides to consider their health and environmental effects and make decisions about their continued use. Under this pesticide reregistration program, EPA examines newer health and safety data for pesticide active ingredients initially registered before November 1, 1984, and determines whether the use of the pesticide does not pose unreasonable risk in accordance to newer saftey standards, such as those described in the Food Quality Protection Act of 1996. Sodium dichloroisocyanurate is found on List A, which contains most pesticides that are used on foods and, hence, have a high potential for human exposure. List A consists of the 194 chemical cases (or 350 individual active ingredients) for which EPA issued registration standards prior to FIFRA '88. Case No: 0569Pesticide type: antimicrobialRegistration Standard Date: 5/20/88 PB88-220660Case Status: RED Approved 09/02OPP has made a decision that some/all uses of the pesticide are eligible for reregistration, as reflected in a Reregistration Eligibility Decision (RED) document .Active ingredient (AI): trichloroisocyanuric acidAI Status: OPP has completed a Reregistration Eligibility Decision (RED) for the case/AI. |
| 수질 위해 등급(WGK) | 2 |
| TSCA 등재 상태 | TSCA listed |
| RTECS 번호 | XZ1925000 |
| 운송 번호(UN) | UN 2468 (TRICHLOROISOCYANURIC ACID, DRY) |
| 독성 | LD50 orally in Rabbit: 406 mg/kg LD50 dermal Rabbit > 2000 mg/kg |
| 관세 코드 | 29336980 |
| 위험 문구(R) | 8-22-31-36/37-50/53-36/37/38 |
| 위험 표시 | O,Xn,N |
| 안전 문구(S) | 8-26-41-60-61 |
| 포장분류 | II |
| 위험 등급 | 5.1Acute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Eye Irrit. 2Ox. Sol. 2STOT SE 3 |
| 기존화학 물질 | KE-34101 |
| 저장 분류 | 5.1B - Oxidizing hazardous materials |
| 유해 물질 데이터 | 87-90-1(Hazardous Substances Data) |
| 함량 및 규제정보 | 물질구분: 유독물질혼합물(제품)함량정보: 심클로센 및 이를 1% 이상 함유한 혼합물 |
| 유해화학물질 필터링 | 2014-1-685 |
용도
용도
Trichloroisocyanuric Acid is a disinfectant and anti-bacterial. It can also be used in the synthesis of napthols.
일반 설명
A white slightly hygroscopic crystalline powder or lump solid with a mild chlorine-like odor. Said to have 85 percent available chlorine. Decomposes at 225°C. Moderately toxic by ingestion. May irritate skin and eyes. Active ingredient in household dry bleaches. Used in swimming pools as a disinfectant .