4-Methylpiperidine (HCID 69381)

이름 및 식별자

우선 이름: 4-Methylpiperidine
IUPAC: 4-methylpiperidine
현지명: 4-피페콜린
영어명: 4-Methylpiperidine
분자식: C6H13N
분자량: 99.17

이름 및 동의어

4-Methylpiperidine626-58-44-PipecolinePiperidine, 4-methyl-gamma-PipecolineEV6HN6HDP8NSC-66495DTXSID8060820RefChem:99934DTXCID6043418210-954-1.gamma.-Pipecoline

이름 더 보기

4-메틸피페리딘4-피페콜린메틸피페리딘4PPC4-Methylpiperidine solution4Me-Pipg-PipecolineAKOS BBS-000036664-methyl-piperidin

4-Methyl-piperidine4-methylpiperidin4-Methylpiperidine--d4MFCD00006005?-Pipecoline4-methylpiperdine4-methylpyperidine4-Pipecoline; 4-Methylpiperidine; NSC 126910; NSC 66495; gamma-Pipecoline

데이터베이스 식별자

CAS: 626-58-4
PubChem CID: 69381
DTXSID: DTXSID8060820
ChEMBL: CHEMBL21533
UNII: EV6HN6HDP8
EC Number: 210-954-1
Nikkaji: J6.864K

물성

구조 계산 물성

XLogP: 1.1
극성 표면적: 12 Å²
수소 결합 공여자 수: 1
수소 결합 수용자 수: 1
회전 가능 결합 수: 0
무거운 원자 수: 7
형식 전하: 0
복잡도: 46

실험 및 물리화학적 성질

Physical DescriptionColorless liquid with an amine-like odor; [Alfa Aesar MSDS]

Kovats Retention Index · 2건

831；816；816

1077；1075

물리화학적 성질

녹는점: 4 · 4-5 °C
끓는 점: 124 °C · 124 °C(lit.)
밀도: 0.838 g/mL · 0.838 g/mL at 25 °C(lit.)
증기압: 16 hPa · 16 hPa (20 °C)
굴절률: 20 · n20/D 1.446(lit.)
인화점: 45 °F · 45 °F
저장 조건: Flammables area
용해도: 클로로포름에 용해됨
물리적 상태: 액체
산도 계수 (pKa): 1 · pK1:11.23(+1) (25°C,μ=0.5)
Specific Gravity: 0.838 · 0.838
색상: 약간 노란색으로 맑음
수소이온지수(pH): 13 · 13 (100g/l, H2O, 20℃)
수용성: 혼용 가능
BRN: 1083 · 1083
InChI: 1S/C6H13N/c1-6-2-4-7-5-3-6/h6-7H,2-5H2,1H3
InChIKey: UZOFELREXGAFOI-UHFFFAOYSA-N
SMILES: CC1CCNCC1
NIST: 4 · Piperidine, 4-methyl-(626-58-4)
EPA: 4 · Piperidine, 4-methyl- (626-58-4)

화학적 성질

clear slightly yellow liquid

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]；H302 (12.3%): Harmful if swallowed [Warning Acute toxicity, oral]；H314 (27.7%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H315 (70.8%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (70.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (70.8%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P330, P332+P317, P337+P317, P362+P364, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 65 reports by companies from 18 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory Information · 3건

Chemical: Piperidine, 4-methyl-

Status: Active Update: 13-05-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/19405

4-Methylpiperidine: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Alfa Aesar MSDS] See Piperidine.

Hazard Classes and CategoriesFlam. Liq. 2 (100%)；Acute Tox. 4 (12.3%)；Skin Corr. 1A (27.7%)；Skin Irrit. 2 (70.8%)；Eye Irrit. 2 (70.8%)；STOT SE 3 (70.8%)

독성 정보

Adverse EffectsDermatotoxin - Skin burns.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

규제 정보

Regulatory Information · 3건

Chemical: Piperidine, 4-methyl-

Status: Active Update: 13-05-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/19405

4-Methylpiperidine: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 2
HS 번호: 29333999
risk_code: 11-36/37/38-36-20/21-10-61
hazard_code: F,Xi,T
safety_code: 16-26-36-45-36/37-53
포장분류: II
위험 등급: 3
Hazard Classifications: Acute Tox. 4 OralEye Dam. 1Flam. Liq. 2Skin Corr. 1B
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

용도 및 제조

General Manufacturing InformationPiperidine, 4-methyl-: ACTIVE

응용 분야

용도4-Methylpiperidine is used as a catalyst in the synthesis of stilbene derivatives as anti-malarial agents. It also serves as an anti-corrosive compound for iron.

상·하류 제품 정보

하류 제품

2-(4-메틸-피페리딘-1-YL)-에틸아민 4-메틸렌피페리딘 4-메틸-1,2,3,6-테트라히드로피리딘 1-(클로로아세틸)-4-메틸피페리딘 1-Piperidineacetic acid, 4-methyl-, ethyl ester 4-메틸니트로소피페리딘 2-chloro-6-(4-methylpiperidine-1-carbonyl)pyridine 2,2-Dimethyl-3-(4-methyl-piperidin-1-yl)-propionaldehyde (4-아미노-페닐)-(4-메틸-피페리딘-1-일)-메타논 (4-(Chloromethyl)piperidin-1-yl)(phenyl)methanone 4-(4-메틸피페리딘-1-일)벤즈알데히드 (2R,4R)-1-[(2S)-2-[(tert-Butyloxycarbonyl)aMino]-5-[[iMino(nitroaMino)Methyl]aMino]-1-oxopentyl]-4-Methyl-2-piperidinecarboxylic Acid Benzyl Ester

공급사50 곳

山东玖玥生物科技有限公司15553333686

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

阿诺西（上海）生物技术有限公司400-1107768 15058188853 · [email protected]

Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]

연결된 노트

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4-피페콜린

기본 정보