Diethyl (trichloromethyl)phosphonate

HCID 70085CAS 866-23-9
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기본 정보

표준 SMILES
CCOP(=O)(OCC)C(Cl)(Cl)Cl
InChIKey
RVAQSYWDOSHWGP-UHFFFAOYSA-N
분자식
C5.H10.Cl3.O3.P
평균 분자량
255.5 g/mol
단동위원소 질량
253.94331385

이름 및 식별자

우선 이름
Diethyl (trichloromethyl)phosphonate
IUPAC
1-[ethoxy(trichloromethyl)phosphoryl]oxyethane
영어명
Diethyl (trichloromethyl)phosphonate
분자식
C5H10Cl3O3P
분자량
255.46

이름 및 동의어

Diethyl (trichloromethyl)phosphonateRefChem:587041622-785-4866-23-9Diethyl trichloromethylphosphonateDiethyltrichloromethylphosphonate1-[ethoxy(trichloromethyl)phosphoryl]oxyethaneRo 3-0658MFCD00013666Phosphonic acid, trichloromethyl-, diethyl esterPhosphonic acid, (trichloromethyl)-, diethyl esterAI3-18556
이름 더 보기
Ro-30658TIMTEC-BB SBB008195diethyl trichloromethanephosphonateTrichloromethylphosphonic acid diethylDiethyl (trichloromethyl)phosphonate 97%(Trichloromethyl)phosphonic acid diethylDiethyl (Trichloromethyl)phosphonate >trichloromethyl-phosphonicacidiethylesterDIETHYL (TRICHLOROMETHYL)PHOSPHONATE, 97 %
WLN: GXGGPO&O2&O2(Trichloromethyl)phosphonic Acid Diethyl EsterNSC-46567CS-0151420EN300-7867510NSC 46567BRN 1210640C5H10Cl3O3P

데이터베이스 식별자

CAS
866-23-9
PubChem CID
70085
DTXSID
DTXSID50235688
UNII
LKC8DWP2F4
EC Number
622-785-4
Nikkaji
J7.147A

물성

구조 계산 물성

XLogP
2.2
극성 표면적
35.5 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
3
회전 가능 결합 수
4
무거운 원자 수
12

실험 및 물리화학적 성질

SpringerMaterials PropertiesViscosity
Density1.362 @25 °C

물리화학적 성질

끓는 점
130 · 130-131 °C/14 mmHg (lit.)
밀도
1.362 g/mL · 1.362 g/mL at 25 °C (lit.)
굴절률
20 · n20/D 1.463(lit.)
인화점
230 °F · >230 °F
저장 조건
2 · 2-8°C
물리적 상태
액체

화학적 성질

Colorless to Almost colorless clear liquid.

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H302 (11.1%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazard Classes and CategoriesAcute Tox. 4 (11.1%)

안전 및 보호

Protective Action Criteria (PAC) · 3건

2.4 [mg/m3]

26 [mg/m3]

160 [mg/m3]

안전 데이터

wgk
3
rtecs
TA0988000
ridadr
UN3278
HS 번호
29319000
risk_code
36/37/38-22
hazard_code
Xi

화학 및 산업

응용 분야 · 2건

용도Diethyl (trichloromethyl)phosphonate may be used in the synthesis of chlorovinyl phosphonates via reaction with aldehydes and ketones.

일반 설명Addition reaction of diethyl (trichloromethyl)phosphonate to olefins by non-chain catalytic reactions catalyzed by copper amine complexes has been reported. Irradiation of diethyl (trichloromethyl)phosphonate in MeCN is reported to afford corresponding monoesters and olefins, via photochemical type II elimination reaction.

제조 방법 · 1건

Diethyl trichloromethylphosphonate was also obtained from diethyltrimethylsilyl phosphite in 60 % yield, and from benzyldiethyl phosphite in the presence of dibenzoyl peroxide and an ultraviolet source in a radical induced reaction in 87 % yield (compared to 26 % without the dibenzoyl peroxide).

상·하류 제품 정보

공급사48 곳

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
南京世洲生物科技有限公司025-85560043 15850508050 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]

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