Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
트리스(4-클로로페닐)포스핀
트라이스(4-클로로페닐)수소화인 · 트리스(4-클로로페닐)포스핀 · tris(4-chlorophenyl)phosphane · TRIS(P-CHLOROPHENYL)PHOSPHINE · NSC 136459 · Tri(p-chlorophen · Tris(4-chlorophenyl) · TRI(4-CHLOROPHENYL)PHOSPHINE
식별자 및 물리적 특성
| CAS No. | 1159-54-2 |
|---|---|
| 분자식 | C18H12Cl3P |
| 평균 분자량 | 365.6 g/mol |
| 단동위원소 질량 | 363.97422 g/mol |
| SMILES | Clc1ccc(P(c2ccc(Cl)cc2)c2ccc(Cl)cc2)cc1 |
| InChIKey | IQKSLJOIKWOGIZ-UHFFFAOYSA-N |
| PubChem CID | 70874 |
| EC No. | 214-596-7 |
| DTXSID | DTXSID30151216 |
| 현지명 | 트리스(4-클로로페닐)포스핀 |
화학 및 물리적 성질
| XLogP | 6.5 |
|---|---|
| 극성 표면적 | 0 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 0 |
| 회전 가능 결합 수 | 3 |
| 무거운 원자 수 | 22 |
| 형식 전하 | 0 |
| 복잡도 | 275 |
| 녹는점 | 100-103 °C (lit.) |
| 끓는 점 | 427.6±40.0 °C(Predicted) |
| 저장 조건 | Inert atmosphere,Room Temperature |
| 물리적 상태 | 수정 같은 |
| 색상 | 하얀색 |
| BRN | 751458 |
| InChI | 1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H |
| InChIKey | IQKSLJOIKWOGIZ-UHFFFAOYSA-N |
| SMILES | Clc1ccc(cc1)P(c2ccc(Cl)cc2)c3ccc(Cl)cc3 |
화학적 성질
white to light yellow crystal powde
안전 및 규제
| GHS 분류 | WarningH315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]H335 (97.8%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposureRespiratory tract irritation]P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| Hazard Classes and Categories | Skin Irrit. 2 (100%)Eye Irrit. 2 (100%)STOT SE 3 (97.8%) |
| 수질 위해 등급(WGK) | 3 |
| TSCA 등재 상태 | No |
| 운송 번호(UN) | 3278 |
| 관세 코드 | 29310099 |
| 위험 문구(R) | 36/37/38 |
| 위험 표시 | Xi |
| 안전 문구(S) | 26-37/39 |
| 포장분류 | III |
| 위험 등급 | Eye Irrit. 2Skin Irrit. 2STOT SE 3 |
| 저장 분류 | 11 - Combustible Solids |
용도
용도
Catalyst for:Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydesSolvent-free Heck reactionsCocatalyst in:Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagentsRhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenesRhodium-catalyzed hydrogenation reactionsPlatinum-catalyzed allylation reactions