삼불화붕소테트라하이드로푸란착물
Boron, trifluoro(tetrahydrofuran)-, (T-4)-
기본 정보
- CAS
462-34-0- 표준 SMILES
C1CCOC1.FB(F)F- InChIKey
CHNLPLHJUPMEOI-UHFFFAOYSA-N- 분자식
- C4H8BF3O
- 평균 분자량
- 139.91 g/mol
이름 및 식별자
- 우선 이름
- Boron, trifluoro(tetrahydrofuran)-, (T-4)-
- IUPAC
- oxolane;trifluoroborane
- 현지명
- 삼불화붕소테트라하이드로푸란착물
- 영어명
- Boron trifluoride tetrahydrofuran complex
- 분자식
- C4H8BF3O
- 분자량
- 139.91
이름 및 동의어
Boron, trifluoro(tetrahydrofuran)-, (T-4)-EINECS 207-325-9EC 207-325-9RefChem:121043DTXCID9040477462-34-0DTXSID2060044Trifluoro(tetrahydrofuran)boron70157-12-9Boron,trifluoro(furan)-, (T-4)-oxolane;trifluoroboraneBF3 THF
이름 더 보기
삼불화붕소테트라하이드로푸란착물Boron trifluoride tetrahydrofuran complex,50%Boron trifLJACS-462-34-0Boron Trifluoride in THFTrifluor(tetrahydrofuran)borBorontrifluoride THF coMplexuoride tetrahydrofuran compLBORON TRIFLUORIDE TETRAHYDROFURANEtrifluoro(oxolan-1-ium-1-yl)boranuide
SCHEMBL47964borontrifluoride tetrahydrofuranAKOS015913932Trifluoroborane tetrahydrofuran complexBORON TRIFLUORIDE TETRAHYDROFURANtetrahydrofuran - trifluoroborane (1:1); Trifluoro(tetrahydrofuran)boron
데이터베이스 식별자
- CAS
462-34-0- PubChem CID
- 71088
- EC Number
- 207-325-9
물성
구조 계산 물성
- 극성 표면적
- 9.2 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 4
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 9
- 형식 전하
- 0
- 복잡도
- 30.8
실험 및 물리화학적 성질
Chemical ClassesMetals -> Metalloid Compounds (Boron)
Physical DescriptionYellow liquid; [Sigma-Aldrich MSDS]
물리화학적 성질
- 녹는점
- 11 · 11-13 °C (lit.)
- 끓는 점
- 180 °C · 180 °C (lit.)
- 밀도
- 1.268 g/mL · 1.268 g/mL at 25 °C (lit.)
- 증기압
- 11 Pa · 11Pa
- 인화점
- 198 °F · 198 °F
- 저장 조건
- 30 °C · Store below +30°C.
- 용해도
- 디메틸 포름아미드와 혼합 가능.
- 물리적 상태
- liquid
- 폭발한계
- 2.3 · 2.3-17.7%(V)
- 수용성
- 가수 분해
- InChI
- InChI=1S/C4H8BF3O/c6-5(7,8)9-3-1-2-4-9/h1-4H2
- InChIKey
- XYMZNNGTHKHCJH-UHFFFAOYSA-N
- SMILES
- [B+3](O1CCCC1)([F-])([F-])[F-]
- EPA
- Boron, trifluoro(tetrahydrofuran)-, (T-4)- (462-34-0)
화학적 성질
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
Danger
H302 (33.5%): Harmful if swallowed [Warning Acute toxicity, oral]
P260, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P363, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 224 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Regulatory Information
Status: Active Update: 05-04-2013 https://echa.europa.eu/registration-dossier/-/registered-dossier/11415
Boron, trifluoro(tetrahydrofuran)-, (T-4)-: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
Causes burns; Prolonged or repeated inhalation exposure may cause kidney injury; [ECHA REACH Registrations] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Targets the nerves, liver, and teeth; [Sigma-Aldrich MSDS] See Boron trifluoride dihydrate. See Tetrahydrofuran.
Hazard Classes and CategoriesAcute Tox. 4 (33.5%)
독성 정보
Adverse EffectsDermatotoxin - Skin burns.
안전 데이터
- wgk
- 1
- tsca
- TSCA listed
- ridadr
- UN 3265 8/PG 2
- HS 번호
- 29321900
화학 및 산업
용도 및 제조
Uses
Used as a polymerization catalyst and intermediate in the manufacture of large scale and fine chemicals and as a dopant in the semiconductor industry; [ECHA REACH Registrations]
Semiconductor Manufacturing [Category: Industry]
General Manufacturing InformationBoron, trifluoro(tetrahydrofuran)-, (T-4)-: ACTIVE
응용 분야
용도Reactant or reagent involved in:Deoxofluorination of alcohols and carbonylsSynthesis of methacrylate-PEG-methacrylate-boron trifluoride self-doped gel polymer electrolytesHydroboration-oxidation of divinylferroceneReagent involved in the synthesis of biologically active molecules such as: NK1 receptor antagonists Complex polyketide natural productsSelective serotonin reuptake inhibitors
관련 반응
3건
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