Allyl methacrylate

식별자 및 물리적 특성

CAS No.	96-05-9
분자식	C7H10O2
평균 분자량	126.15 g/mol
단동위원소 질량	126.06807956 g/mol
SMILES	C=CCOC(=O)C(=C)C
InChIKey	FBCQUCJYYPMKRO-UHFFFAOYSA-N
PubChem CID	7274
ChEMBL	CHEMBL1889548
EC No.	202-473-0
DTXSID	DTXSID2021816

화학 및 물리적 성질

XLogP	1.7
극성 표면적	26.3
수소 결합 공여자 수	0
수소 결합 수용자 수	2
회전 가능 결합 수	4
무거운 원자 수	9
형식 전하	0
복잡도	136
밀도	0.9335 g/cu cm at 20 °C0.927 g/cm3
Viscosity	12 mPa-s at 20 °C
Color/Form	Colorless liquid
인화점	33.9 °C
끓는 점	150 °C302 °F30-50 °C(Press: 23 Torr)
Decomposition	When heated to decomposition it emits acrid smoke and irritating fumes.
Polymerization	Methyl methacrylate, and in general the methacrylic esters, polymerize much less readily than the corresponding ordinary acrylates. None the less, they are stabilized by adding hydroquinone or pyrogallol, particularly in the presence of metallic copper. /Methacrylates/
증기압	5.77 [mmHg]5.77 mm Hg at 25 °C5.77 mmHg
굴절률	Index of refraction: 1.4360 at 20 °CIndex of refraction: 1.4328 at 25 °C/D
Physical Description	LiquidClear colorless liquid with a pungent odor[ACGIH]Colorless liquid.
Kovats Retention Index	8491188
Other Experimental Properties	67 °C at 50 mm Hg55 °C at 30 mm Hg

안전 및 규제

GHS 분류	DangerH226: Flammable liquid and vapor [Warning Flammable liquids]H302: Harmful if swallowed [Warning Acute toxicity, oral]H311: Toxic in contact with skin [Danger Acute toxicity, dermal]H330: Fatal if inhaled [Danger Acute toxicity, inhalation]H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]P210, P233, P240, P241, P242, P243, P260, P262, P264, P270, P271, P273, P280, P284, P301+P317, P302+P352, P303+P361+P353, P304+P340, P316, P320, P321, P330, P361+P364, P370+P378, P391, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
규제 정보	Chemical: 2-Propenoic acid, 2-methyl-, 2-propenyl ester2-Propenoic acid, 2-methyl-, 2-propen-1-yl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 2-methyl-, 2-propen-1-yl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 17-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/144012-Propenoic acid, 2-methyl-, 2-propenyl ester: HSNO Approval: HSR001394 Approved with controls
유해성 요약	TLV Basis: liver damageCauses liver damage in rats fed 60/mg/kg/day but not at 15 mg/kg/dayThree individuals reported skin irritation after exposure to 3% allyl methacrylate in olive oilNo reports of skin sensitization in humans or after animal testing[ACGIH] See ACRYLIC RESINS (MONOMERS).
Hazard Classes and Categories	Flam. Liq. 3 (99.7%)Acute Tox. 4 (99.7%)Acute Tox. 3 (34.5%)Acute Tox. 4 (65.5%)Acute Tox. 2 (34.5%)Acute Tox. 3 (62.5%)STOT RE 2 (34.5%)Aquatic Acute 1 (99.7%)Aquatic Chronic 3 (33.4%)Flammable liquid - category 3Hazardous to the aquatic environment (acute) - category 1Acute toxicity (inhalation) - category 3Acute toxicity (dermal) - category 4