페닐트리클로로실란

페닐트리클로로실란 · TRICHLOROPHENYLSILANE · DK958 · CP0280 · KA 103 · NSC 77080 · Co-Formula CFS-135 · Trichloro(phenyl)sil

식별자 및 물리적 특성

CAS No.	98-13-5
분자식	C6H5Cl3Si
평균 분자량	211.5 g/mol
단동위원소 질량	209.92260973 g/mol
SMILES	Cl[Si](Cl)(Cl)c1ccccc1
InChIKey	ORVMIVQULIKXCP-UHFFFAOYSA-N
PubChem CID	7372
EC No.	202-640-8
DTXSID	DTXSID5026621
현지명	페닐트리클로로실란

화학 및 물리적 성질

극성 표면적	0
수소 결합 공여자 수	0
수소 결합 수용자 수	0
회전 가능 결합 수	0
무거운 원자 수	10
형식 전하	0
복잡도	104
물질 분류	Toxic Gases & Vapors -> ChlorosilanesCorrosives
SpringerMaterials Properties	13C nuclear magnetic resonance spectrum
밀도	1.326 at 64.4 °F (EPA, 1998) - Denser than waterwill sink1.321 g/cu cm at 20 °C1.321 @ 20°C1.321 g/mL at 25 °C(lit.)
Color/Form	Colorless liquid
용해도	Soluble in carbon tetrachloride, chloroform, carbon disulfideSoluble in benzene, ether, perchloroethylenesoluble in Chloroform,Benzene,Ether
Corrosivity	Corrosive
인화점	196 °F (EPA, 1998)196 °F (91 °C) (open cup)
끓는 점	395 °F at 760 mmHg (EPA, 1998)201 °C201 °C @760 [mm Hg]201 °C(lit.)
Decomposition	The silanes decomp at elevated temp to liberate hydrogen and deposit a high purity silicon, which leads to some of the principal uses of silanes. /Silanes/Hydrogen chloride and phosgene gases may formboth are toxic and irritating.When heated to decomposition, it emits toxic fumes of /hydrogen chloride/.
증기 밀도	7.36 (EPA, 1998) - Heavier than airwill sink (Relative to Air)7.36 (AIR= 1)
증기압	15.0 [mmHg]0.426 mm Hg at 25 °C44.3Pa at 20℃
굴절률	Index of refraction = 1.5230 at 20 °C/Dn20/D 1.523(lit.)
녹는점	-127°C
물리적 상태	액체
색상	무색의
비중	1.324
폭발한계	1.6-9.2%(V)
용해도	물과 반응
BRN	508730
InChI	1S/C6H5Cl3Si/c7-10(8,9)6-4-2-1-3-5-6/h1-5H
InChIKey	ORVMIVQULIKXCP-UHFFFAOYSA-N
SMILES	Cl[Si](Cl)(Cl)c1ccccc1
NIST	Phenyl trichlorosilane(98-13-5)
EPA	Trichlorophenylsilane (98-13-5)

안전 및 규제

건강 유해성
GHS 분류	This chemical does not meet GHS hazard criteria for 0.8% (1 of 119) of reports.DangerH312 (76.5%): Harmful in contact with skin [Warning Acute toxicity, dermal]P260, P261, P264, P264+P265, P271, P280, P284, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 119 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Hazards Identification	Water-reactive material (WR)
규제 정보	Chemical: Silane, trichlorophenyl-Benzene, (trichlorosilyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzene, (trichlorosilyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 16-09-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/14161The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)
운송 라벨(DOT)	Corrosive
화재 위험	Do not get water inside containers. Vapors may travel to ignition source and flash back. Runoff to sewer may create fire or explosion hazard. Flammable/combustible materialmay be ignited by heat, sparks or flames. Container may explode in heat of fire. Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Emits toxic chloride fumes when heated to decomposition. Do not mix with halogenated compounds, because a trace quantity of free halogen may cause violent explosion. May react violently with water. Readily hydrolyzed in water/moisture, producing hydrochloric acid. Avoid mixing with water or exposing to moisture. (EPA, 1998)· Combustible material: may burn but does not ignite readily.
화재 가능성	Self-ignites in air. With a little ammonia, it forms a self-igniting product.Trichlorosilane is highly flammable. /Trichlorosilane/

용도

Phenyltrichlorosilane can be used in the development of high-capacitance polymer dielectric for low-voltage organic transistors.

일반 설명

A colorless liquid with a pungent odor. Flash point 91°F. Decomposed by moisture or water to hydrochloric acid with evolution of heat. Corrosive to metals and tissue.