디페닐포시닉클로라이드

Diphenylphosphinic chloride

HCID 73910CAS 1499-21-4

부분 구조 검색 유사 구조 찾기

기본 정보

표준 SMILES: O=P(Cl)(c1ccccc1)c1ccccc1
InChIKey: QPQGTZMAQRXCJW-UHFFFAOYSA-N
분자식: C12H10ClOP
평균 분자량: 236.63 g/mol
단동위원소 질량: 236.01577925

이름 및 식별자

우선 이름: Diphenylphosphinic chloride
IUPAC: [chloro(phenyl)phosphoryl]benzene
현지명: 디페닐포시닉클로라이드
영어명: Diphenylphosphinic Chloride
분자식: C12H10ClOP
분자량: 236.63

이름 및 동의어

Diphenylphosphinic chloride1499-21-4Diphenylphosphinyl chlorideChlorodiphenylphosphine oxidePhosphinic chloride, diphenyl-diphenylphosphinoyl chloridePhosphinic chloride, P,P-diphenyl-Diphenylchlorophosphine oxideDiphenylphosphorus oxychloridediphenylphosphinic acid chloride5GP30GY04VEINECS 216-107-2

이름 더 보기

디페닐포시닉클로라이드다이페닐포스피닉 클로라이드DPPCDPP-CLPh2POClphosphinic chLDiphenylphoshinic

NSC-175848DIPHENYLPHOSPHONIC CHLORIDEDTXSID50164424NSC 175848RefChem:588942DTXCID6086915216-107-2[chloro(phenyl)phosphoryl]benzene

데이터베이스 식별자

CAS: 1499-21-4
PubChem CID: 73910
DTXSID: DTXSID50164424
UNII: 5GP30GY04V
EC Number: 216-107-2
Nikkaji: J150.122D

물성

구조 계산 물성

XLogP: 2.1
극성 표면적: 17.1 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 2
무거운 원자 수: 15
형식 전하: 0
복잡도: 220

실험 및 물리화학적 성질

SpringerMaterials PropertiesNuclear quadrupole resonance spectroscopy

물리화학적 성질

녹는점: 20 °C · 20°C
끓는 점: 222 °C/16 · 222 °C/16 mmHg (lit.)
밀도: 1.24 g/mL · 1.24 g/mL at 25 °C (lit.)
굴절률: 20 · n20/D 1.609(lit.)
인화점: 79 °F · 79 °F
저장 조건: 2 · 2-8°C
용해도: 클로로포름, 메탄올에 용해됨
물리적 상태: 액체
Specific Gravity: 1.24 · 1.24
색상: 무색~황색으로 투명함
수용성: 물에서 분해되다
BRN: 975191 · 975191
InChI: 1S/C12H10ClOP/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChIKey: QPQGTZMAQRXCJW-UHFFFAOYSA-N
SMILES: ClP(=O)(c1ccccc1)c2ccccc2
NIST: Diphenylphosphinic chloride(1499-21-4)

화학적 성질

clear colorless to yellow liquid

안전 및 규제

GHS 분류

GHS Classification · 5건

This chemical does not meet GHS hazard criteria for 1.4% (1 of 71) of reports.

Danger

H226 (71.8%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P319, P321, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 71 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 2건

Status: Active Update: 31-01-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/27651

Diphenylphosphinic chloride: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 3 (71.8%)

안전 데이터

wgk: 3
ridadr: UN 2920 8/PG 2
HS 번호: 29310095
risk_code: 10-34
hazard_code: C,F
safety_code: 16-26-36/37/39-45
포장분류: II
위험 등급: 8
기존화학 물질: KE-12096
F 고인화성물질: 10-21
위험 참고 사항: Flammable/Corrosive
Hazard Classifications: Eye Dam. 1Flam. Liq. 3Skin Corr. 1BSkin Sens. 1A
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

응용 분야

용도Diphenylphosphinic chloride (Ph2POCl) is widely used as a precursor to synthesize various chiral phosphine bidentate ligands for asymmetric synthesis, in addition to several peptide coupling agents.