Silane, trimethyl((1-methylethenyl)oxy)- (HCID 74599)

이름 및 식별자

우선 이름: Silane, trimethyl((1-methylethenyl)oxy)-
IUPAC: trimethyl(prop-1-en-2-yloxy)silane
영어명: Isopropenyloxytrimethylsilane
분자식: C6H14OSi
분자량: 130.26

이름 및 동의어

IsopropenoxytrimethylsilaneSilane, trimethyl[(1-methylethenyl)oxy]-Trimethyl[(1-methylvinyl)oxy]silaneEINECS 217-393-1Trimethyl[(1-methylethenyl)oxy]silaneSilane, trimethyl((1-methylethenyl)oxy)-DTXSID4062014Trimethyl((1-methylvinyl)oxy)silaneTrimethyl((1-methylethenyl)oxy)silaneRefChem:885318DTXCID9035836217-393-1

이름 더 보기

DK177IPOTMS(CH3)3SiOC(CH3)=CH22-(TRIMETHYLSILOXY)PROPENETrimethyl IsopropenoxysilaneTrimethyl lsopropenoxysilaneTRIMETHYLISOPROPENYLOXYSILANE

1833-53-0trimethyl(prop-1-en-2-yloxy)silaneIsopropenyloxytrimethylsilane2-(trimethylsilyloxy)propene(Isopropenyloxy)trimethylsilaneisopropenyloxy(trimethyl)silaneMFCD00042845Isopropenyloxytrimethylsilane [Trimethylsilylating Agent]

데이터베이스 식별자

CAS: 1833-53-0
PubChem CID: 74599
DTXSID: DTXSID4062014
UNII: JHQ95GJ9U6
EC Number: 217-393-1
Nikkaji: J149.470H

물성

구조 계산 물성

극성 표면적: 9.2 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 2
무거운 원자 수: 8
형식 전하: 0
복잡도: 91

실험 및 물리화학적 성질

Kovats Retention Index675

물리화학적 성질

녹는점: 40 · 40-45 °C
끓는 점: 93 · 93-95 °C
밀도: 0.78 g/mL · 0.78 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.395(lit.)
인화점: 45 °F · 45 °F
저장 조건: -20 °C · -20°C
물리적 상태: 투명한 액체
색상: Colorless to Light orange to Yellow
Specific Gravity: 0.786 · 0.786
BRN: 1849023 · 1849023
InChI: 1S/C6H14OSi/c1-6(2)7-8(3,4)5/h1H2,2-5H3
InChIKey: UAIFZYSPVVBOPN-UHFFFAOYSA-N
SMILES: CC(=C)O[Si](C)(C)C
NIST: 2 · CH2=(CH3)OSi(CH3)3(1833-53-0)
EPA: Silane, trimethyl[(1-methylethenyl)oxy]- (1833-53-0)

화학적 성질

clear colorless liquid

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]；H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Hazard Classes and CategoriesFlam. Liq. 2 (100%)；Skin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.5%)

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 2
HS 번호: 2931900090
risk_code: 11-36/37/38
hazard_code: F,Xi
safety_code: 16-26-36-37/39
포장분류: II
위험 등급: 3.1
F 고인화성물질: 10-21
Hazard Classifications: Eye Irrit. 2Flam. Liq. 2Skin Irrit. 2STOT SE 3
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

용도 및 제조

General Manufacturing InformationSilane, trimethyl[(1-methylethenyl)oxy]-: ACTIVE

응용 분야 · 1건

일반 설명(Isopropenyloxy)trimethylsilane is an enol silyl ether. It participates as nucleophile in Lewis acid-promoted C3-nucleophile substitution of tetracyclic bromide. It is reported to participate in the total synthesis of (±)-powelline. It is reported to participate in dityltin bis(triflate) catalyzed Michael addition reaction of enol silyl ethers.