메틸시클로헥실아민

N-메틸사이클로헥실아민 · 메틸시클로헥실아민 · N-메틸시클로헥실아민 · N-Methylcyclohexanamine · Methylcyclohexylamine · Cyclohexylmethylamine · 1-Methylcyclohexylamine · AKOS BBS-00004304

https://huagongshe.com/ko/chemical/7514

식별자 및 물리적 특성

CAS No.	100-60-7
분자식	C7H15N
평균 분자량	113.2 g/mol
단동위원소 질량	113.12044948 g/mol
SMILES	CNC1CCCCC1
InChIKey	XTUVJUMINZSXGF-UHFFFAOYSA-N
PubChem CID	7514
ChEBI	CHEBI:59018
EC No.	202-869-3
DTXSID	DTXSID3059216
현지명	메틸시클로헥실아민

화학 및 물리적 성질

XLogP	1.6
극성 표면적	12
수소 결합 공여자 수	1
수소 결합 수용자 수	1
회전 가능 결합 수	1
무거운 원자 수	8
형식 전하	0
복잡도	55.4
SpringerMaterials Properties	Optical coefficient
Physical Description	Methyl cyclohexylamine appears as a water-white liquid. Slightly soluble in water and floats on water. A strong irritant to skin and eyes. Corrosive. Used as a solvent.
녹는점	-9--7 °C (lit.)
끓는 점	149 °C (lit.)
밀도	0.868 g/mL at 25 °C (lit.)
증기 밀도	4 (vs air)
증기압	11 mm Hg ( 40 °C)
굴절률	n20/D 1.456(lit.)
인화점	85 °F
저장 조건	Keep in dark place,Inert atmosphere,Room temperature
용해도	54g/L
물리적 상태	액체
pKa(산도 계수)	11.03±0.20(Predicted)
비중	0.855 (20/4℃)
색상	무색~황색으로 투명함
pH	12 (10g/l, H2O, 20℃)
폭발한계	2.2-10.5%(V)
용해도	5.4g/100mL(20℃)
BRN	1523664
유전율	3.6400000000000001
InChI	1S/C7H15N/c1-8-7-5-3-2-4-6-7/h7-8H,2-6H2,1H3
InChIKey	XTUVJUMINZSXGF-UHFFFAOYSA-N
SMILES	CNC1CCCCC1
NIST	Cyclohexanamine, N-methyl-(100-60-7)
EPA	Cyclohexanamine, N-methyl- (100-60-7)

화학적 성질

clear colourless to yellow liquid

안전 및 규제

GHS 분류	DangerH226 (99.5%): Flammable liquid and vapor [Warning Flammable liquids]P210, P233, P234, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P362+P364, P363, P370+P378, P390, P403+P233, P403+P235, P405, P406, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 218 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
규제 정보	Chemical: Cyclohexanamine, N-methyl-Status: Active Update: 13-01-2016 https://echa.europa.eu/registration-dossier/-/registered-dossier/17035Cyclohexyl(methyl)amine: Does not have an individual approval but may be used under an appropriate group standard
운송 라벨(DOT)	Flammable Liquid Corrosive
화재 위험	Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
건강 유해성	Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
반응성 그룹	Amines, Phosphines, and Pyridines
Reactivity Alerts	Highly Flammable
Reactivity Profile	METHYL CYCLOHEXYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Air and Water Reactions	Flammable. Slightly soluble in water.
Hazard Classes and Categories	Flam. Liq. 3 (99.5%)
소화	Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
응급 처치	Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
비화재 누출 대응	Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

용도

Intermediate, solvent, acid acceptor.

용도

N-Methylcyclohexylamine is used as a component of vulcanization accelerators, but the market size is relatively small.

일반 설명

A water-white liquid. Slightly soluble in water and floats on water. A strong irritant to skin and eyes. Corrosive. Used as a solvent.

제조 및 합성 방법

제조 방법

N-Methylcyclohexylamine can be prepared by a procedure similar to that used for cyclohexylamine, i.e., by hydrogenation of methylaniline over a supported nickel catalyst or from cyclohexanone and methylamine under hydrogenation conditions. Cyclohexylamine reacts with methanol over copper, zinc, or copper – calcium catalysts.