Hexaethylphosphorous triamide (HCID 75292)

개요

structure given in first source

이름 및 식별자

우선 이름: Hexaethylphosphorous triamide
IUPAC: N-[bis(diethylamino)phosphanyl]-N-ethylethanamine
영어명: Tris(diethylamino)phosphine
분자식: C12H30N3P
분자량: 247.36

이름 및 동의어

Tris(diethylamino)phosphine2283-11-6Hexaethylphosphorous triamidePhosphorous triamide, hexaethyl-WPC83R9HNCDTXSID4062305Phosphorous triamide, N,N,N',N',N'',N''-hexaethyl-RefChem:900283DTXCID0036760218-920-8Hexaethyl phosphorous triamideN,N,N',N',N'',N''-Hexaethylphosphinetriamine

이름 더 보기

P(N(C2H5)2)3HexaethyLphosphorous triamideHexaethylphosphinetriamineHEXAETHYLPHOSPHORUS TRIAMIDEAURORA KA-1249

N-[bis(diethylamino)phosphanyl]-N-ethylethanamineMFCD00009041Tris(N,N-diethylamino)phosphineN,N,N',N',N'',N''-hexaethylphosphorous triamideHexaethyltriamidophosphiteHexaethyltriaminophosphineTris(diethylamido)phosphinePhosphorous acid tris(diethylamide)

데이터베이스 식별자

CAS: 2283-11-6
PubChem CID: 75292
DTXSID: DTXSID4062305
UNII: WPC83R9HNC
EC Number: 218-920-8
Nikkaji: J21.143E

물성

구조 계산 물성

XLogP: 2.8
극성 표면적: 9.7 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 3
회전 가능 결합 수: 9
무거운 원자 수: 16
형식 전하: 0
복잡도: 126

실험 및 물리화학적 성질

SpringerMaterials Properties15N nuclear magnetic resonance spectrum

물리화학적 성질

녹는점: 230 · 230-232 °C
끓는 점: 80 · 80-90 °C10 mm Hg(lit.)
밀도: 0.903 g/mL · 0.903 g/mL at 25 °C(lit.)
굴절률: 20 · n20/D 1.475(lit.)
인화점: 58 °C · 58 °C
저장 조건: 30 °C · Store below +30°C.
산도 계수 (pKa): 9.74 · 9.74±0.70(Predicted)
물리적 상태: 액체
Specific Gravity: 0.903 · 0.903
색상: 투명한 무색~황색-주황색
수용성: 물에 불용성.
BRN: 636187 · 636187
InChI: 1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3
InChIKey: FDIOSTIIZGWENY-UHFFFAOYSA-N
SMILES: CCN(CC)P(N(CC)CC)N(CC)CC
EPA: Phosphorous triamide, hexaethyl- (2283-11-6)

화학적 성질

clear colorless to yellow-orange liquid

안전 및 규제

GHS 분류

GHS Classification · 4건

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory InformationHexaethyltriaminophosphine: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 3 (100%)

안전 데이터

wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 3
HS 번호: 29319090
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36
포장분류: III
위험 등급: 3
F 고인화성물질: 10-23
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

용도 및 제조

General Manufacturing InformationPhosphorous triamide, N,N,N',N',N'',N''-hexaethyl-: ACTIVE

응용 분야 · 1건

용도Tris(diethylamino)phosphine [(Et2N)3P] can be used as a reagent to synthesize: 1,1′-Dialkylisoindigo derivatives by reacting with various 1-alkylisatins via deoxygenation reaction.1-Aminomethylisatins by treating with isatin and primary and secondary amines.It can also be used in the deoxygenation of some cyclic α-diketones using fullerene C60.