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2.5-디메틸-2.5-비스(벤조일퍼옥시)헥산

2,5-Dimethyl-2,5-DI-(benzoylperoxy)hexane

HCID 75796
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기본 정보개요이름 및 식별자물성안전 및 규제화학 및 산업관련 반응화합물 노트
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기본 정보

CAS
2618-77-1
표준 SMILES
CC(C)(CCC(C)(C)OOC(=O)c1ccccc1)OOC(=O)c1ccccc1
InChIKey
RIPYNJLMMFGZSX-UHFFFAOYSA-N
분자식
C22H26O6
평균 분자량
386.4 g/mol
단동위원소 질량
386.17293855

개요

This solid peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. It is generally stored or transported as a mixture, with an inert solid.

이름 및 식별자

우선 이름
2,5-Dimethyl-2,5-DI-(benzoylperoxy)hexane
IUPAC
(5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate
현지명
2.5-디메틸-2.5-비스(벤조일퍼옥시)헥산
영어명
2,5-Dimethyl-2,5-di(benzoylperoxy)hexane
분자식
C22H26O6
분자량
386.44

이름 및 동의어

2,5-dimethyl-2,5-di(benzoylperoxy)hexaneEINECS 220-050-9Benzenecarboperoxoic acid, 1,1'-(1,1,4,4-tetramethyl-1,4-butanediyl) esterDTXSID5062556Benzenecarboperoxoic acid, 1,1,4,4-tetramethyl-1,4-butanediyl ester2,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY)HEXANE, (TECHNICALLY PURE)2,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY)HEXANE, [TECHNICALLY PURE]KAYAESTER AB2,5-dimethyl-2,5-di-(benzoylperoxy)hexaneRefChem:444518PERHEXA 25ZLUPERSOL 118
이름 더 보기
2,5-디메틸-2,5-비스(벤조일페녹시)헥산2,5-디메틸헥산-2,5-디퍼벤조에이트2.5-디메틸-2.5-비스(벤조일퍼옥시)헥산2,5-다이메틸-2,5-다이-(벤조일퍼옥시)헥세인2,5-디메틸-2,5-DI(벤조일페록시)헥산L-118VAROX 118VAROX 230-XLVAROX DCP-40CVAROX DCP-40KE2,5-Dimethylhexane-2,5-diperbenzoate2,5-Dimethylhexan-2,5-diyldiperbenzoat2,5-dimethylhexane-2,5-diyl diperbenzoate2,5-DIMETHYLHEXANE-2,5-DI(BENZOYLPEROXY)HEXANE
LUPEROX 118DTXCID9037458USP 711Peroxybenzoic acid, 1,1,4,4-tetramethyltetramethylene esterL 1182,5-DIBENZOYLPEROXY-2,5-DIMETHYLHEXANE2,5-DIMETHYLHEXANE-2,5-DIPEROXYBENZOATE2,5-BIS(BENZOYLDIOXY)-2,5-DIMETHYLHEXANE

물성

구조 계산 물성

XLogP
5.4
극성 표면적
71.1 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
6
회전 가능 결합 수
11
무거운 원자 수
28
형식 전하
0
복잡도
455

실험 및 물리화학적 성질

Physical DescriptionThis solid peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. It is generally stored or transported as a mixture, with an inert solid.

물리화학적 성질

끓는 점
529.9 · 529.9±33.0 °C(Predicted)
밀도
1.143 · 1.143±0.06 g/cm3(Predicted)
EPA
1 · Benzenecarboperoxoic acid, 1,1'-(1,1,4,4-tetramethyl-1,4-butanediyl) ester (2618-77-1)

안전 및 규제

안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.

GHS 분류

GHS Classification · 3건

Danger

H241: Heating may cause a fire or explosion [Danger Self-reactive substances and mixtures; Organic peroxides]

P210, P234, P235, P240, P280, P370+P380+P375[+P378], P403, P410, P411, P420, and P501 (click each P-code to see the statement)

유해성 정보

Regulatory InformationChemical: Benzenecarboperoxoic acid, 1,1,4,4-tetramethyl-1,4-butanediyl ester
DOT LabelOrganic Peroxide Explosive
Fire HazardsExcerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Health HazardsExcerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Reactive GroupPeroxides, Organic
Reactivity AlertsExplosive
Reactivity Profile · 1건

Peroxides, such as 2,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY)HEXANE, are good oxidizing agents. Organic compounds can ignite on contact with concentrated peroxides. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with peroxides. There are few chemical classes that do not at least produce heat when mixed with peroxides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions of peroxides (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion. Solutions of peroxides often become explosive when evaporated to dryness or near-dryness. Danger of explosion when dry. May explode from heat or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). May be ignited by heat, sparks or flames.

화학 및 산업

용도 및 제조

General Manufacturing InformationBenzenecarboperoxoic acid, 1,1'-(1,1,4,4-tetramethyl-1,4-butanediyl) ester: ACTIVE
응용 분야 · 1건

일반 설명2,5-DIMETHYL-2,5-DI(BENZOYLPEROXY)HEXANE is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. 2,5-DIMETHYL-2,5-DI(BENZOYLPEROXY)HEXANE is generally stored or transported as a mixture, with an inert solid.

관련 반응

5건
반응 기록 만들기
HRID 46462 반응식
HRID 46462촉매로uspto-grants-1979_11
HRID 127048 반응식
HRID 127048촉매로uspto-grants-1981_03
HRID 372563 반응식
HRID 372563촉매로uspto-grants-1978_05
HRID 971501 반응식
HRID 971501촉매로uspto-grants-1979_07
HRID 1654593 반응식
HRID 1654593반응물로uspto-grants-1995_04

화합물 노트

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데이터베이스 식별자

CAS
2618-77-1
PubChem CID
75796
DTXSID
DTXSID5062556
UNII
A5SRX84PEA
EC Number
220-050-9
Nikkaji
J5.176D
Air and Water ReactionsNo rapid reaction with air. No rapid reaction with water.
Hazard Classes and CategoriesOrganic peroxides - Type B

안전 및 보호

Fire FightingExcerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
First AidExcerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Nonfire Spill ResponseExcerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Isolation and EvacuationExcerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

안전 데이터

tsca
TSCA listed
ridadr
3102
포장분류
II
위험 등급
5.2