트리사이클로헥실포스핀

Tricyclohexylphosphine

HCID 75806CAS 2622-14-2

기본 정보

표준 SMILES
C1CCC(P(C2CCCCC2)C2CCCCC2)CC1
InChIKey
WLPUWLXVBWGYMZ-UHFFFAOYSA-N
분자식
C18H33P
평균 분자량
280.4 g/mol
단동위원소 질량
280.23198769

이름 및 식별자

우선 이름
Tricyclohexylphosphine
IUPAC
tricyclohexylphosphane
현지명
트리사이클로헥실포스핀
영어명
Tricyclohexyl phosphine
분자식
C18H33P
분자량
280.43

이름 및 동의어

TricyclohexylphosphinePhosphine, tricyclohexyl-EINECS 220-069-2NSC 158657DTXSID9062562Phosphine, tricyclohexylRefChem:191427DTXCID8037469220-069-2WLPUWLXVBWGYMZ-UHFFFAOYSA-N2622-14-2TRICYCLOHEXYL PHOSPHINE
이름 더 보기
트리사이클로헥실포스핀TCHPP(4-MeOC6H4)3TricycLProtein TCHPtricyclohexylphospine
TricyclohexylphosphanePCy3Tricyclohexyl-phosphaneMFCD00003853tris(cyclohexyl)phosphineP(Cy)3Cy3PP(cHex)3

데이터베이스 식별자

CAS
2622-14-2
PubChem CID
75806
DTXSID
DTXSID9062562
UNII
34HJS55VCG
EC Number
220-069-2
Nikkaji
J87.295D

물성

구조 계산 물성

XLogP
5.4
극성 표면적
0 Ų
수소 결합 공여자 수
0
수소 결합 수용자 수
0
회전 가능 결합 수
3
무거운 원자 수
19

실험 및 물리화학적 성질

Chemical ClassesOther Classes -> Phosphorus Compounds
Physical DescriptionCrystalline powder or chunks; [Sigma-Aldrich MSDS]

물리화학적 성질

녹는점
81 · 81-83 °C (lit.)
끓는 점
383.4 · 383.4±9.0 °C | Condition: Press: 760 Torr
밀도
0.909 g/mL · 0.909 g/mL at 25 °C
인화점
48 °F · 48 °F
저장 조건
2 · Inert atmosphere,2-8°C
용해도
Chloroform (Slightly), DMSO (Slightly, Heated, Sonicaetd), Ethyl Acetate (Slightly)

화학적 성질

clear colorless to pale yellow solution

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H251 (18.7%): Self-heating; may catch fire [Danger Self-heating substances and mixtures]

P235, P261, P264, P264+P265, P270, P271, P273, P280, P301+P316, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, P407, P410, P413, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 91 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Hazards SummaryA skin and strong eye irritant; [Sigma-Aldrich MSDS] See Triphenylphosphine.
Hazard Classes and CategoriesSelf-heat. 1 (18.7%)

안전 데이터

wgk
3
tsca
TSCA listed
ridadr
UN 2056 3/PG 2
HS 번호
29319090
risk_code
36/37/38-22-37/38-36-19-11-67-65-63-48/20-40
hazard_code
Xi,Xn,F

화학 및 산업

용도 및 제조

General Manufacturing InformationPhosphine, tricyclohexyl-: ACTIVE
응용 분야 · 1건

용도Tricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry. Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides. suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides. This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds. As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations. Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions. Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.

공급사50 곳

国药集团化学试剂有限公司86-21-63210123 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]
科瑞迪化学400-821-5857 021-64326257 · [email protected]

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