Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,1-디-(3차부틸퍼옥시)사이클로헥산
1,1-디-(3차부틸퍼옥시)사이클로헥산 · 1,1-디-(터셔리-부틸퍼옥시)-싸이클로헥산 · 1,1-디-(터셔리-부틸퍼옥시)-싸이클로헥산(57%이상) · 1,1-bis(T-butylperoxy)cyclohexane · DP275B · Perhexa-C · Chaloxyd P · Trigonox 22
식별자 및 물리적 특성
| CAS No. | 3006-86-8 |
|---|---|
| 분자식 | C14H28O4 |
| 평균 분자량 | 260.37 g/mol |
| 단동위원소 질량 | 260.19875938 g/mol |
| SMILES | CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 |
| InChIKey | HSLFISVKRDQEBY-UHFFFAOYSA-N |
| PubChem CID | 76359 |
| EC No. | 221-111-2 |
| DTXSID | DTXSID4044907 |
| 현지명 | 1,1-디-(3차부틸퍼옥시)사이클로헥산 |
화학 및 물리적 성질
| XLogP | 3.7 |
|---|---|
| 극성 표면적 | 36.9 |
| 수소 결합 공여자 수 | 0 |
| 수소 결합 수용자 수 | 4 |
| 회전 가능 결합 수 | 6 |
| 무거운 원자 수 | 18 |
| 형식 전하 | 0 |
| 복잡도 | 224 |
| Physical Description | Organic solvent solution, added to lessen explosion hazard.Particularly heat and contamination sensitive.CBILiquid |
| 녹는점 | 65 °C (SADT) |
| 끓는 점 | 52-54 °C (0.1 mmHg) |
| 밀도 | 0.891 g/mL at 25 °C |
| 증기압 | 4.88hPa at 25℃ |
| 굴절률 | n20/D 1.435 |
| 인화점 | 155 °F |
| 저장 조건 | 2-8°C |
| 물리적 상태 | 액체 |
| 색상 | 투명한 |
| 용해도 | 혼용 가능 |
| InChI | InChI=1S/C14H28O4/c1-12(2,3)15-17-14(10-8-7-9-11-14)18-16-13(4,5)6/h7-11H2,1-6H3 |
| InChIKey | HSLFISVKRDQEBY-UHFFFAOYSA-N |
| SMILES | C1(CCCCC1)(OOC(C)(C)C)OOC(C)(C)C |
| LogP(분배 계수) | 7.2 at 25℃ |
| EPA | Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) (3006-86-8) |
화학적 성질
clear liquid
안전 및 규제
| GHS 분류 | This chemical does not meet GHS hazard criteria for 1.8% (3 of 170) of reports.DangerH242 (74.7%): Heating may cause a fire [Danger Self-reactive substances and mixturesOrganic peroxides]P210, P234, P235, P240, P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403, P403+P233, P405, P410, P411, P420, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 170 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 규제 정보 | Chemical: Peroxide, cyclohexylidenebis[(1,1-dimethylethyl)Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Peroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 15-05-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/5875Peroxide, cyclohexylidenebis(1,1-dimethylethyl): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| 운송 라벨(DOT) | Organic PeroxideOrganic Peroxide Explosive |
| 화재 위험 | Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]: |
| 건강 유해성 | Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]: |
| 반응성 그룹 | Peroxides, Organic |
| Reactivity Alerts | Strong Oxidizing AgentExplosive |
| Reactivity Profile | The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]The explosive instability of the lower dialkyl peroxides (e.g.,. dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.]The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the mono functional peroxides. It is unlikely that this derivative would be particularly unstable compared to other peroxides in its class. [Bretherick 2nd ed., p 44 1979.] |
| Air and Water Reactions | No rapid reaction with air. No rapid reaction with water. |
| Hazard Classes and Categories | Org. Perox. C (74.7%)Flammable liquids - Category 4 |
| 소화 | Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]: |
| 응급 처치 | Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]: |
| 비화재 누출 대응 | Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]: |
| Isolation and Evacuation | Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]: |
| Personal Protective Equipment (PPE) | Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]: |
| 수질 위해 등급(WGK) | 2 |
| TSCA 등재 상태 | TSCA listed |
| 운송 번호(UN) | UN 3103 5.2 |
| 관세 코드 | 29096000 |
| 위험 문구(R) | 7-62-50/53-36/37/38-61-65-45-51/53 |
| 위험 표시 | O,N,T |
| 안전 문구(S) | 17-36/37/39-3/7-14A-61-60-45-26-14-53-62 |
| 포장분류 | II |
| 위험 등급 | 5.2Asp. Tox. 1Carc. 1BEye Irrit. 2Muta. 1BOrg. Perox. CSkin Irrit. 2STOT SE 3 |
| 기존화학 물질 | 2004-3-2858 |
| 저장 분류 | 4.1A - Other explosive hazardous materials |
용도
용도
Polymerization initiator.