메틸포스포로디클로다이트

Phosphorodichloridous acid, methyl ester

HCID 76768

노트 반응

부분 구조 검색 유사 구조 찾기

기본 정보

CAS: 3279-26-3
표준 SMILES: COP(Cl)Cl
InChIKey: HCSDJECSMANTCX-UHFFFAOYSA-N
분자식: CH3Cl2OP
평균 분자량: 132.91 g/mol
단동위원소 질량: 131.9298571

이름 및 식별자

우선 이름: Phosphorodichloridous acid, methyl ester
IUPAC: dichloro(methoxy)phosphane
현지명: 메틸포스포로디클로다이트
영어명: Methyl phosphorodichloridite
분자식: CH3Cl2OP
분자량: 132.91

이름 및 동의어

Methyl phosphorodichloridite3279-26-3Phosphorodichloridous acid, methyl esterDTXSID20186451RefChem:158001DTXCID30108942221-915-3Methyl dichlorophosphitedichloro(methoxy)phosphaneDichloro Methyl PhosphiteMFCD00000524methyldichlorophosphite

이름 더 보기

메틸포스포로디클로다이트메틸 다이클로로포스파이트[Phosphitylating Agent]DICHLOROMETHOXY PHOSPHINEichloro(methoxy)phosphaneMethyl dichloridophosphiteMethyl dichlorophosphite,98%

Methyl phosphorodichloridoitemethyl dichlorophosphiniteCH3Cl2OPMethoxydichlorophosphineMethoxyphosphonous DichlorideO-Methyl PhosphorodichloriditeEINECS 221-915-3Phosphorodichloridous acid methyl ester

데이터베이스 식별자

CAS: 3279-26-3
PubChem CID: 76768
DTXSID: DTXSID20186451
EC Number: 221-915-3
Nikkaji: J208.737E

물성

구조 계산 물성

XLogP: 1.6
극성 표면적: 9.2 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 1
회전 가능 결합 수: 0
무거운 원자 수: 5
형식 전하: 0
복잡도: 23

물리화학적 성질

녹는점: -91 °C · -91 °C (lit.)
끓는 점: 93 · 93-95 °C (lit.)
밀도: 1.376 g/mL · 1.376 g/mL at 20 °C (lit.)
굴절률: 20 · n20/D 1.474(lit.)
인화점: 104 °F · 104 °F
저장 조건: 20 °C · −20°C
용해도: 클로로포름, 디클로로메탄, 에틸 아세테이트에 용해됨
물리적 상태: 액체
색상: 무색 내지 거의 무색
수용성: 물과 반응합니다. 클로로포름, 디클로로메탄 및 에틸 아세테이트에 용해됩니다.
BRN: 1697452 · 1697452
안정성: 가연성.
InChI: 1S/CH3Cl2OP/c1-4-5(2)3/h1H3
InChIKey: HCSDJECSMANTCX-UHFFFAOYSA-N
SMILES: COP(Cl)Cl

화학적 성질

Colourless Liquid

안전 및 규제

GHS 분류

GHS Classification · 5건

Danger

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]；H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H335 (88.6%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P210, P233, P240, P241, P242, P243, P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P319, P321, P363, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 44 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

유해성 정보

Regulatory InformationPhosphorodichloridous acid, methyl ester: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 3 (100%)；Skin Corr. 1B (100%)；STOT SE 3 (88.6%)

규제 정보

Regulatory InformationPhosphorodichloridous acid, methyl ester: Does not have an individual approval but may be used under an appropriate group standard

안전 데이터

wgk: 3
ridadr: UN 2920 8/PG 2
HS 번호: 29209090
risk_code: 10-14-34-37
hazard_code: C
safety_code: 26-36/37/39-45
포장분류: II
위험 등급: 8
F 고인화성물질: 10-13-23
Hazard Classifications: Flam. Liq. 3Skin Corr. 1BSTOT SE 3
스토리지 클래스: 3 - Flammable liquids

화학 및 산업

응용 분야

용도Employed in the synthesis of phosphorodichloridothioates1 and oxazaphosphorinanes2 from sulfenyl chlorides and a chiral amino alcohol, respectively.