이소부티릴 퍼옥사이드

디아이소부티릴퍼옥시드 · 디이소부티릴퍼옥사이드 · 디이소부틸퍼옥사이드(50%이상) · 이소부티릴퍼옥사이드 · 다이아이소뷰티릴 퍼옥사이드, 33-52 % · Isobutyryl peroxide · Diisobutyryl peroxide · bisisobutyryl peroxide

https://huagongshe.com/ko/chemical/76969

식별자 및 물리적 특성

CAS No.	3437-84-1
분자식	C8H14O4
평균 분자량	174.19 g/mol
단동위원소 질량	174.08920893 g/mol
SMILES	CC(C)C(=O)OOC(=O)C(C)C
InChIKey	RPBWMJBZQXCSFW-UHFFFAOYSA-N
PubChem CID	76969
EC No.	222-340-0
DTXSID	DTXSID0063024
현지명	이소부티릴 퍼옥사이드

화학 및 물리적 성질

XLogP	2.3
극성 표면적	52.6
수소 결합 공여자 수	0
수소 결합 수용자 수	4
회전 가능 결합 수	5
무거운 원자 수	12
형식 전하	0
복잡도	152
Physical Description	This liquid peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently.
끓는 점	225.17°C (rough estimate)
밀도	1.0817 (rough estimate)
증기압	1.2-2.41hPa at 20-25℃
굴절률	1.4220 (estimate)
용해도	49.1g/L at 25℃
InChI	InChI=1S/C8H14O4/c1-5(2)7(9)11-12-8(10)6(3)4/h5-6H,1-4H3
InChIKey	RPBWMJBZQXCSFW-UHFFFAOYSA-N
SMILES	O(C(=O)C(C)C)OC(=O)C(C)C
LogP(분배 계수)	0.94-2.6 at 20-25℃
EPA	Peroxide, bis(2-methyl-1-oxopropyl) (3437-84-1)

안전 및 규제

GHS 분류	DangerH241 (100%): Heating may cause a fire or explosion [Danger Self-reactive substances and mixturesOrganic peroxides]P210, P234, P235, P240, P260, P261, P264, P264+P265, P272, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P321, P331, P333+P317, P337+P317, P362+P364, P363, P370+P380+P375[+P378], P403, P405, P410, P411, P420, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 5 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
규제 정보	Status: Active Update: 12-06-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/11632
운송 라벨(DOT)	Organic Peroxide
화재 위험	Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
건강 유해성	Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
반응성 그룹	Peroxides, Organic
Reactivity Alerts	Explosive
Reactivity Profile	Most of the isolated diacyl peroxides are solids with relatively low decomposition temperatures, and are explosive, and sensitive to shock, heat, or friction. Several, particularly the lower members, will detonate on the slightest disturbance. Autocatalytic, self-accelerating decomposition, which is promoted by tertiary amines, is involved. A sample of DIISOBUTYRYL PEROXIDE in ether was being evaporated to dryness with a stream of air when it exploded violently, [MCA Case History No. 579]. Can generate electrostatic charges. REF [Handling Chemicals Safely, 1980. p. 250].
Air and Water Reactions	No rapid reaction with air. No rapid reaction with water.
Hazard Classes and Categories	Org. Perox. B (100%)
소화	Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
응급 처치	Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:

용도

일반 설명

Diisobutyryl peroxide(in solution,content≤52%) is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently.