기본 정보
- CAS
3536-96-7- 표준 SMILES
[CH-]=C.[Cl-].[Mg+2]- InChIKey
NAFZXKWEUWVSAW-UHFFFAOYSA-M- 분자식
- C2H3ClMg
- 평균 분자량
- 86.8 g/mol
- 단동위원소 질량
- 85.9773695
개요
See also: Magnesium, chloroethenyl (annotation moved to).
이름 및 식별자
- 우선 이름
- Magnesium, chloroethenyl-
- IUPAC
- magnesium;ethene;chloride
- 영어명
- Vinylmagnesium chloride
- 분자식
- C2H3ClMg
- 분자량
- 86.8
이름 및 동의어
Vinylmagnesium chlorideChlorovinylmagnesiumMagnesium, chloroethenyl-EINECS 222-575-9DTXSID80883919EC 222-575-9RefChem:800679DTXCID601023401Vinylmagnesium chloride, 15 wt% solution in tetrahydrofuran222-575-93536-96-7magnesium;ethene;chloride
이름 더 보기
VinylmagnesiumChlorvinylmagnesiumVinylchloromagnesiumMagnesium,chloroethenyl-Magnesium vinyl chlorideAlkenylmagnesiumchloride
chloro(ethenyl)magnesiumVinyl magnesium chloridemagnesium,ethene,chloridevinyl magnesium-chloridevinyl-magnesium chlorideSCHEMBL356372AR-1K5632MFCD00013594
데이터베이스 식별자
- CAS
3536-96-7- PubChem CID
- 77075
- DTXSID
DTXSID80883919- EC Number
- 222-575-9
물성
구조 계산 물성
- 극성 표면적
- 0 Ų
- 수소 결합 공여자 수
- 0
- 수소 결합 수용자 수
- 2
- 회전 가능 결합 수
- 0
- 무거운 원자 수
- 4
- 형식 전하
- 0
- 복잡도
- 6
실험 및 물리화학적 성질
Chemical ClassesMetals -> Metals, Organic Compounds
Physical Description
Liquid
15% solution in tetrahydrofuran: Brown liquid; [Acros Organics MSDS]
물리화학적 성질
- 끓는 점
- 66 °C · 66 °C
- 밀도
- 0.98 g/mL · 0.980 g/mL at 20 °C
- 인화점
- 1 °F · −1 °F
- 저장 조건
- 0 · 0-6°C
- 물리적 상태
- 결정성 분말
- 색상
- 흰색에서 베이지색
- 수용성
- 격렬한 반응
- BRN
- 3535268 · 3535268
- InChI
- InChI=1S/C2H3.ClH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1
- InChIKey
- NAFZXKWEUWVSAW-UHFFFAOYSA-M
- SMILES
- C(=C)[Mg]Cl
- EPA
- Magnesium, chloroethenyl- (3536-96-7)
화학적 성질
dark brown solution
안전 및 규제
안전 정보는 참고용이며, 공급업체의 물질안전보건자료(SDS), 관련 법규 및 전문가 평가를 대체하지 않습니다.
GHS 분류
GHS Classification
This chemical does not meet GHS hazard criteria for 3.3% (11 of 333) of reports.
Danger
H225 (50.2%): Highly Flammable liquid and vapor [Danger Flammable liquids]
P210, P223, P231+P232, P233, P240, P241, P242, P243, P260, P264, P264+P265, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 333 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
유해성 정보
Regulatory Information
Magnesium, chloroethenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Magnesium, chloroethenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.
REACH registered substance: Chlorovinylmagnesium (EC: 222-575-9)
Hazards Summary
Corrosive to skin; [Quick CPC] 15% solution in tetrahydrofuran: Reacts violently and/or explosively with water and moisture in the air; May ignite or explode on contact with moisture; Causes burns; Inhalation may cause chemical burns to respiratory tract and CNS depression; May cause liver and kidney injury; [Acros Organics MSDS]
Hazard Classes and CategoriesFlam. Liq. 2 (50.2%)
독성 정보
Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
화학 및 산업
용도 및 제조
UsesUsed as an intermediate; [ExPub: ECHA REACH Registrations]
U.S. Production2023: 69,446 lb
Industry UsesIntermediate
General Manufacturing Information
All Other Basic Organic Chemical Manufacturing
Magnesium, chloroethenyl-: ACTIVE
응용 분야
용도Vinylmagnesium chloride (Grignard reagent) can be prepared from vinyl chloride and then used to make a variety of useful end products or intermediates by adding a vinyl anion to organic functional groups. For instance, the vinylmagnesium compounds can be coupled with cuprous chloride, CuCl, at 60 °C (76 °F) to give 1,3-butadiene, while vinyl ketones and alcohols can be prepared by the addition of vinylmagnesium chloride to organic acids.
상·하류 제품 정보
하류 제품
관련 반응
0건
현재 필터 조건에 해당하는 반응 기록이 없습니다.
화합물 노트
불러오는 중…